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A method and device for in-situ utilization of sewage to generate electricity to enhance denitrification efficiency of upward vertical flow constructed wetlands

A technology of artificial wetland and vertical flow, applied in chemical instruments and methods, biological water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of increasing system operating costs, improve the overall denitrification performance, improve Total nitrogen removal effect, effect of promoting ammonia oxidation process

Active Publication Date: 2020-03-20
INST OF AQUATIC LIFE ACAD SINICA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although some studies have reported that CW-MFC has a better effect on the treatment of high-nitrogen wastewater (Oon et al., Hybridsystem up-flow constructed wetland integrated with microbial fuel cell forsimultaneous wastewater treatment and electricity generation. BioresourceTechnology, 2015, 186: 270 -275.), but in the case of cathodic aeration, increased system operating costs

Method used

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  • A method and device for in-situ utilization of sewage to generate electricity to enhance denitrification efficiency of upward vertical flow constructed wetlands

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] An operation method for in-situ utilization of sewage to generate electricity to enhance the denitrification efficiency of an upward vertical flow constructed wetland, the steps of which are as follows:

[0046] A. Sewage enters continuously from the bottom of the system and distributes water evenly, and then rises in push flow along the non-conductive filler layer 1 at the bottom. Under the adsorption, interception and oxidation of fillers and microorganisms in this layer, part of the organic matter is effectively degraded, and at the same time Under the action of nitrifying bacteria, the ammonia nitrogen in the sewage is oxidized to nitrate nitrogen by the oxygen brought into the water, and the heterotrophic denitrifying bacteria use the organic carbon source as an electron donor to reduce a small part of the nitrate nitrogen to nitrogen;

[0047] B. The sewage after step A flows into the anode conductive filler layer 2. Part of the organic matter is used by the anode ...

Embodiment 2

[0058] A device for in-situ generating electricity from sewage to strengthen the denitrification performance of an upward vertical flow constructed wetland, the device is laid with bottom non-conductive filler layer 1, anode conductive filler layer 2; non-conductive filler isolation layer 3; cathode conductive Filling layer 4; It is characterized in that: the anode conductive filler layer 2 is connected to the bottom non-conductive filler layer 1 and the non-conductive filler isolation layer 3 respectively, the cathode conductive filler layer 4 is connected to the non-conductive filler isolation layer 3, and the non-conductive filler isolation layer Planting wetland plants 5 in 3, the anode collector 6 and the cathode collector 7 are short-circuited through the inner wire 8, and the anode collector 6 and the cathode collector 7 are respectively placed in the anode conductive filler layer 2 and the cathode conductive filler layer 4, and the inner wire 8 is buried in the anode co...

Embodiment 3

[0069] For influent water with ammonia nitrogen as the main form, the experiment compared the denitrification effect of the CW-MFC system under short-circuit (0 Ω) and closed-circuit (1000 Ω) conditions, as well as denitrification bacteria and electrogenic bacteria. The results showed that:

[0070] Compared with the external closed-circuit system, the COD removal efficiency of the short-circuit system is more than 10%, the total nitrogen removal efficiency is more than 25%, and the ammonia nitrogen removal rate is more than 60%. The proportion of nitrogen forms in the effluent of the short-circuit system to the total nitrogen is: ammonia nitrogen 34.9%, nitrite nitrogen 17.4%, nitrate nitrogen 39.7%, organic nitrogen 7.9%; the proportion of nitrogen forms in the effluent of the external closed circuit system to the total nitrogen is: ammonia nitrogen 87.1%, organic nitrogen 12.3%, nitrite nitrogen and nitrate nitrogen only accounted for 0.6%.

[0071] The microbial community ...

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Abstract

The invention discloses a method and a device for intensifying the denitrification efficiency of an upward vertical flow constructed wetland by utilizing sewage generated electricity in situ. The method comprises the following steps of A, enabling sewage to continuously enter from the bottom of the device; B, enabling the sewage to flow into an anode conductive filler layer, and enabling ammonia nitrogen in the sewage to produce an ammoxidation process under the action of a denitrifier in an anode area to be oxidized to form nitrate nitrogen; C, next, enabling the sewage to flow into a nonconductive filler isolation layer, and distributing a root system of a plant at the middle-upper part of the nonconductive filler isolation layer; D, subsequently, enabling the sewage to flow into a cathode conductive filler layer, and reducing the nitrate nitrogen to form nitrogen; E, finally, enabling the sewage to flow out through a water discharge pipe in the cathode conductive filler layer, wherein total nitrogen in yielding water is removed. The anode conductive filler layer is connected with a bottom nonconductive filler layer and the nonconductive filler isolation layer respectively; the cathode conductive filler layer is connected with the nonconductive filler isolation layer; an anode collector is connected with a cathode collector through an inner conducting wire. The method is simple, is convenient and quick to operate, is used for utilizing generated electric energy in situ, and is used for obviously improving the removal effect of the total nitrogen in low-carbon and high-ammonia-nitrogen sewage.

Description

technical field [0001] The invention belongs to the field of sewage treatment, and more specifically relates to a method for improving the removal of total nitrogen when a microbial fuel cell and vertical flow constructed wetland coupling system is used to treat low-carbon and high-ammonia-nitrogen sewage (domestic sewage, low-concentration landfill leachate, sludge digestate, etc.) Efficiency method. At the same time, it also relates to a device for in-situ using sewage to generate electricity to enhance the denitrification performance of the up-flowing vertical flow constructed wetland. Background technique [0002] Low carbon-to-nitrogen ratio (C / N ≤ 5) is a typical feature of sewage in southern my country. Traditional biochemical treatment processes (such as activated sludge process, biofilm process, etc.) have low denitrification efficiency due to insufficient carbon sources in the denitrification process. , the effluent water quality is difficult to meet the increasing...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/32C02F3/34C02F3/30C02F101/16
CPCC02F3/005C02F3/302C02F3/32C02F3/34C02F2101/16
Inventor 肖恩荣吴振斌许丹林莉莉张义徐栋贺锋
Owner INST OF AQUATIC LIFE ACAD SINICA