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Anion channel membrane

An anion, channel membrane technology, applied in membrane technology, semi-permeable membrane separation, water/sludge/sewage treatment, etc., can solve the problems of high operating pressure, membrane fouling, restricting the application of membrane technology, etc.

Inactive Publication Date: 2018-08-31
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Using membrane to treat dye wastewater has the advantages of high removal rate and energy saving, but serious membrane fouling and high operating pressure restrict the application of membrane technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 5-sulfosalicylic acid and ε-caprolactam were selected as monomers, and the monomers were weighed at a mass ratio of 3:100 for polymerization. Weigh the product sulfonic polyamide 6 (1) 3g and 7g of formic acid with a mass concentration of 80%, all add to a 100mL single-necked bottle, stir at room temperature until dissolved, leave to defoam, and prepare a film casting solution with a mass fraction of 30%. Drop the cast film liquid onto a clean glass plate, scrape it into a thin layer with a film scraper, let it stand in the air for 2 minutes, and immerse it in a coagulation bath composed of 130mL ethanol, 370mL water and 100mL80% formic acid until the film solidifies detached from the glass plate. Wash with deionized water until the pH is neutral, record as membrane 1, and set aside.

Embodiment 2

[0032] 2-amino-5-sulfo-benzoic acid and ε-caprolactam were selected as monomers, and the monomers were weighed at a mass ratio of 2.5:100 for polymerization. Take by weighing product sulfonic acid group polyamide 6 (II) 3g and the formic acid 7g of mass concentration 80%, 0.01g surfactant A, all add 100mL one-necked bottle, stir at room temperature until dissolving, leave standstill defoaming, be mixed with mass fraction: 30% casting solution. Drop the cast film liquid onto a clean glass plate, scrape it into a thin layer with a film scraper, let it stand in the air for 1.5min, and immerse it in a coagulation bath composed of 130mL ethanol and 370mL water until the film solidifies from the glass Board comes off. Wash with deionized water until the pH is neutral, record as membrane 2, and set aside.

Embodiment 3

[0034] 5-sulfosalicylic acid and ε-caprolactam were selected as monomers, and the monomers were weighed at a mass ratio of 2:100 for polymerization. Take by weighing 3.1g of the product sulfonic acid polyamide 6 (I) and 6.89g of formic acid with a mass concentration of 80%, and 0.01g of surfactant B, all add to a 100mL single-necked bottle, stir at room temperature until dissolved, let stand for defoaming, and prepare a mass Casting solution with a fraction of 31%. Drop the cast film liquid onto a clean glass plate, scrape it into a thin layer with a film scraper, let it stand in the air for 2.5 minutes, and immerse it in a coagulation bath composed of 130mL ethanol, 370mL water and 100mL formic acid until the film solidifies detached from the glass plate. Wash with deionized water until the pH is neutral, record as membrane 3, and set aside.

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Abstract

The invention relates to a polyamide membrane entrapping an anion dye dissolved in water and relates to preparation of a high polymer membrane material and an application of the membrane material in organic pollutant wastewater treatment. Polyamide 6 containing sulfonic groups is dissolved in a solvent and causes certain amphipathic self-assembly, so that nano / micro-size particles in certain sizesare formed in a solution. The membrane is prepared by an immersion-precipitation method; formulae of membrane casting liquid and a coagulating bath are adjusted; a high polymer coagulating process iscontrolled; the negatively charged sulfonic groups are distributed on the surface of the membrane and in hole channels of the membrane; the water channel distribution anion membrane with the sulfonicgroups distributed on the surface and the hole channels is prepared; and the anion dye in the aqueous solution is entrapped by a charge repulsion effect. A new material is provided for the treatmentof dye-containing sewage.

Description

technical field [0001] The invention relates to a polyamide 6 membrane for retaining anions in aqueous solution, and relates to the preparation of a polymer membrane material and its application in organic pollutant wastewater treatment. Background technique [0002] Dye wastewater has the characteristics of high organic matter content, high concentration, complex composition, and high pH, ​​and belongs to difficult-to-treat industrial wastewater. With the strengthening of industrial pollution control in our country and the continuous improvement of environmental protection requirements, the high-quality and efficient treatment of dye sewage has become the main public relations direction. Membrane treatment of dye wastewater has the advantages of high removal rate and energy saving, but serious membrane fouling and high operating pressure restrict the application of membrane technology. It is imminent to develop high-efficiency, pollution-resistant membrane materials for th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/56C02F1/44
CPCB01D71/56C02F1/444C02F2101/308
Inventor 刘冬青张宇峰任顺朱泽晛李珂
Owner TIANJIN POLYTECHNIC UNIV