A kind of environmental protection cable material and preparation method thereof
A cable material and environmental protection technology, applied in the field of environmental protection cable material and its preparation, can solve the problems of weak anti-electromagnetic interference, high price, and low requirements
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Embodiment 1
[0030] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 1 part of sulfur, 1 part of maleic anhydride grafted polyethylene, and 10 parts of waste tire rubber powder.
[0031] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0032] 1) After adding 20g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 50g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 50 g of 2-dihydroquinoline was stirred and reacted at room temperature under a nitrogen atmosphere for 18 hours. After the reaction was completed, it was precipitated in ether, filtered, and the product was washed 5 times with ether, and the solvent was removed by rotary evaporation to obtain a modified silicone rubber; Said organic solvent is the mixture that dichloromethane and methanol solvent...
Embodiment 2
[0036] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 2 parts of vulcanizing agent DTDM, 2 parts of maleic anhydride grafted polypropylene, and 12 parts of waste tire rubber powder.
[0037] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0038] 1) After adding 23g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 65g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 3.5 g of 2-dihydroquinoline was stirred and reacted at room temperature under a helium atmosphere for 20 hours. After the reaction, it was precipitated in ether, filtered, and the product was washed with ether for 6 times, and the solvent was removed by rotary evaporation to obtain a modified silicone rubber ; The organic solvent is a mixture of dichloromethane and Virahol solv...
Embodiment 3
[0042] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 2 parts of vulcanizing agent DCP, 3 parts of maleic anhydride grafted polyethylene, and 13 parts of waste tire rubber powder.
[0043] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0044] 1) After adding 25g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 80g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 4g of 2-dihydroquinoline was stirred and reacted at room temperature for 21 hours under a neon gas atmosphere. After the reaction, it was precipitated in ether, filtered, and the product was washed with ether for 7 times, and then the solvent was removed by rotary evaporation to obtain a modified silicone rubber; Described organic solvent is the mixture that dichloromethane and e...
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