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A method for continuous preparation of high-performance plasticized rubber powder by double-stage low-shear co-rotating twin-screws

A twin-screw, low-shear technology, used in plastic recycling, recycling technology, etc., can solve problems such as uneven heat transfer and damage

Active Publication Date: 2021-06-29
NANJING L J R RUBBE & PLASTIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the disadvantages of existing helical or screw rods, such as uneven heat transfer, that there are a large number of hard particles in the rubber compound and that the high-shear twin-screws severely damage the C-C bond of the rubber powder main chain, and provide an environmentally friendly, safe and low-cost Method for continuous preparation of high-performance plasticized rubber powder by shearing co-rotating twin-screws

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Example 1: 100 parts of 20-mesh waste load-carrying carcass rubber powder, 14 parts of aromatic oil, 5 parts of tall oil as softener, 0.2 part of 2,2'-bis(6-tert-butyl-p-phenol) disulfide As an activator, the mixing process is as follows: aromatic oil and tall oil are mixed and preheated in an oil tank at 100°C, and 2,2'-bis(6-tert-butyl-p-phenol) disulfide is put into the oil tank and stirred and mixed for 7 minutes , put the mixture of the three into an airtight mixer mixed with rubber powder according to the ratio of parts by mass, set the discharge temperature at 110°C, and send it into a partially meshed co-rotating twin-screw extruder (D=50mm, L / D =10, H=8mm, C L =38mm, 8 heating sections, among which the first and second zones are the exhaust conveying section, and the third to eighth zones are the plasticizing section), the temperature of each heating zone is set to 140°C, 180°C, 220°C respectively , 240°C, 240°C, 220°C, 180°C, 140°C, the rotational speed of th...

Embodiment 2

[0018] Embodiment 2: Adopt 100 parts of 30 purpose waste radial tire tread rubber powders, 16 parts of aromatic hydrocarbon oil, 4 parts of pine tar are softening agent, 0.4 part of diallyl disulfide is activator, mixing process is as follows: aromatic hydrocarbon oil Stir and mix with pine tar in an oil tank at 120°C for preheating, put diallyl disulfide into the oil tank and stir and mix for 7 minutes, put the mixture of the three into a closed mixer mixed with rubber powder according to the ratio of mass and number of parts, and discharge The material temperature is set at 105°C, and it is fed into a partially intermeshed co-rotating twin-screw extruder (D=50mm, L / D=10, H=8mm, C L =38mm, 8 heating sections, among which the first and second zones are the exhaust conveying section, and the third to eighth zones are the plasticizing section), the temperature of each heating zone is set to 140°C, 180°C, 220°C respectively , 235°C, 235°C, 220°C, 180°C, 140°C), the rotational spe...

Embodiment 3

[0020] Embodiment 3: Adopt 100 parts of 60 purpose waste radial tire tread rubber powders, 16 parts of aromatic hydrocarbon oils, 2 parts of rosin are softening agent, 0.5 part of diallyl disulfide is activator, mixing process is as follows: aromatic hydrocarbon oil and Stir rosin in an oil tank at 130°C to preheat, put diallyl disulfide into the oil tank and stir for 10 minutes, and put the mixture of the three into a closed mixer mixed with rubber powder according to the ratio of parts by mass. Set at 110°C, feed it into a partially intermeshed co-rotating twin-screw extruder (D=300mm, L / D=20, H=30mm, C L =255mm, 8 heating sections, among which the first and second zones are the exhaust conveying section, and the third to eighth zones are the plasticizing section), the temperature of each heating zone is set to 150°C, 190°C, 230°C respectively , 250°C, 250°C, 230°C, 180°C, 140°C, the rotational speed of the first-stage plasticizing screw is 56r / min, and the plasticizing time...

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Abstract

The invention discloses a method for continuously preparing high-performance plasticized rubber powder by using low-shear two-stage co-rotating twin-screw, belonging to the field of waste rubber recycling. Using two partially meshed co-rotating twin-screw in series, the rubber powder mixed with softener and activator evenly is transported to the first-stage plasticizing co-rotating twin-screw extruder. The mixing action of heat and partially meshing low-shear screws completes the selective chain scission of the rubber powder and realizes the rapid and uniform plasticization and regeneration process of the rubber powder. The plasticized high-temperature rubber powder falls vertically into the second-stage cooling co-rotating twin-screw , and also use the good heat transfer effect of the co-rotating twin-screw equipment to complete the cooling and conveying process of the plasticized rubber powder. The low shear of the partially meshed co-rotating twin-screw prevents the sticking of the plasticized rubber powder to the screw, and has a certain self-cleaning function. The Mooney viscosity rebounds; the equipment is safe and continuous and the product quality is stable.

Description

Technical field: [0001] The invention relates to a device and a process method for continuously preparing high-performance plasticized rubber powder with double-stage low-shear co-rotating twin-screws, and belongs to the field of waste rubber recycling. Background technique [0002] my country has always been a big consumer of rubber resources, especially natural rubber, and has long relied on imports. At the same time, the amount of waste rubber products, mainly tires, is gradually increasing. According to statistics from the China Tire Recycling Association, by 2015 The output of waste rubber tires in my country is about 300 million pieces, with a weight of more than 10 million tons. How to efficiently realize the recycling and reuse of waste rubber will greatly reduce the dependence of my country's rubber resources on foreign countries, and at the same time, it is also of great significance to the protection of the environment. [0003] At present, the reclaimed rubber in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C48/40B29C48/505B29C48/68B29C48/80B29C48/84C08L17/00C08L91/00C08J11/10
CPCB29C48/40B29C48/625B29C48/682B29C48/82B29C48/832B29C48/85B29C48/875C08J11/10C08J2317/00C08L17/00C08L91/00Y02W30/62
Inventor 张立群陆涛任冬云史金炜王杰张嘉麟
Owner NANJING L J R RUBBE & PLASTIC CO LTD