Antibody medicine conjugate of anti-CD30 antibody and lidamycin as well as preparation method and application thereof
An antibody drug, lidamycin technology, applied in botany equipment and methods, biochemical equipment and methods, antibody mimics/stents, etc., can solve problems such as toxic side effects, poor selectivity, and damage to normal cells
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Embodiment 1
[0120] Example 1. Preparation and properties of protein CD30-IgG-LDP in the antibody-drug conjugate of anti-CD30 antibody and lidamycin
[0121] 1. Construction of recombinant expression vector pIZDHL-IgG-LDP
[0122] The plasmid pIZDHL used in this example (Xiao-Yun Liu, et al. Chimetric, divalent and tetravalent anti-CD19monoclonal antibodies with potent in vitro and in vivoantitumor activity against human B-cell lymphoma and pre-B acutelymphoblastic leukemia cell lines.Int J Cancer, 2011, 129(2):497-506.) contains constant regions of antibody heavy and light chains. The LDP-VL gene of MluI-Kozac-SP-LDP-VL-BsiWI containing lidamycin prosthetic protein LDP and VL of anti-CD30 antibody shown in the 1-768 position of SEQ ID No.1 The fragment and the fragment of the VH gene containing the anti-CD30 antibody named XhoI-Kozac-SP-VH-NheI shown in the 1-426th position of SEQID No.3 were synthesized by Nanjing GenScript Biotechnology Co., Ltd., and passed OptimumGeneTM codon optimi...
Embodiment 2
[0147] Example 2. Antibody drug conjugate CD30-IgG-LDM of anti-CD30 antibody and lidamycin
[0148] 1. The protein CD30-IgG-LDP is assembled with AE to strengthen the ADC drug CD30-IgG-LDM
[0149] Take the pure product of lidamycin, separate the active chromophore through a hydrophobic column, the mobile phase is acetonitrile: water = 23%: 77% (volume ratio), detect the absorption peak at 340nm wavelength, and collect AE. Mix the protein CD30-IgG-LDP of Example 1 with the chromophore AE according to the molecular ratio (molar ratio) of 1:3, place on a shaker at 4°C in the dark and shake slowly for 12-16 hours to obtain the protein CD30-IgG - Boosted ADC drug CD30-IgG-LDM assembled by LDP and AE.
[0150] The mixture of the two was ultrafiltered with an ultrafiltration tube until there was no AE in the filtrate ( Figure 7 Middle A), indicating that free AE has been removed after protein fortification. The peak type of AE in the protein solution detected by HPLC ( Figure ...
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