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Curing resin composition and transparent conductive film

A transparent conductive film, curing resin technology, applied in conductive coatings, coatings, polyurea/polyurethane coatings, etc., can solve the problem of low adhesion of metal nanowires and carbon nanotubes, low total light transmittance, and high haze problem, to achieve the effect of high production efficiency, high total light transmittance, and low haze

Active Publication Date: 2018-11-06
宁波安特弗新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to solve the problems of high haze and low total light transmittance of existing transparent conductive films, the present invention provides a cured resin composition and a transparent conductive film
The invention also solves the problem of low adhesion of metal nanowires and carbon nanotubes on substrates

Method used

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  • Curing resin composition and transparent conductive film
  • Curing resin composition and transparent conductive film
  • Curing resin composition and transparent conductive film

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0090]The preparation method of the cured resin composition provided by the invention is: dissolving the ionizing radiation curing reactive matrix into a solvent, adding carbon nanotubes and silver nanowires after stirring, adding a leveling agent and a photoinitiator after stirring, and curing after stirring resin composition.

[0091] The preparation method of the transparent conductive film provided by the invention is as follows: coating the cured resin composition on the surface of the base material, drying, and then curing with an ultraviolet lamp to form a transparent conductive layer.

[0092] The test method of the main performance of transparent conductive film provided by the invention is as follows:

[0093] (1) Coating thickness test

[0094] Use the coating thickness gauge ETA-SST thickness testing system to test the thickness of the transparent conductive layer by using the principle of light diffraction.

[0095] (2) Haze, total light transmittance test

[0...

Embodiment 1

[0117] The present invention provides a cured resin composition and a transparent conductive film. The cured resin composition includes an ionizing radiation curing reactive matrix; a photoinitiator; carbon nanotubes; metal nanowires; the transparent conductive film includes a substrate 20 and Transparent conductive layer 10 (such as figure 1 shown), the conductive layer includes resin, carbon nanotubes and metal nanowires; the carbon nanotubes and metal nanowires are bonded to the surface of the substrate by resin; the conductive layer is coated with a cured resin composition, formed after curing. The formula of curing resin composition is as follows:

[0118]

[0119] 5.1kg of aliphatic urethane acrylate oligomer (manufactured by China Taiwan Changxing Chemical Industry Co., Ltd., trade name: Etercure 6195-100) and 1.5kg aliphatic polyurethane diacrylate oligomer (China Taiwan Changxing Chemical Industry Co., Ltd. Co., Ltd., trade name: Etercure 611A-85) was dissolved i...

Embodiment 2

[0122] The cured resin composition and transparent conductive film provided in Example 1.

[0123] The formula of curing resin composition is as follows:

[0124]

[0125] 4kg of aliphatic urethane acrylate oligomer (manufactured by China Taiwan Double Bond Chemical Co., Ltd., trade name: Doublemer 5812) and 3.1kg tripropylene glycol diacrylate (manufactured by China Taiwan Changxing Chemical Industry Co., Ltd., trade name: EM 223) was dissolved in 15.5kg of toluene and 5.0kg of isopropanol mixed solvent, after stirring for 20 minutes, add 0.31kg carbon nanotubes (length 20 μm, diameter 20nm), 0.48kg silver nanowires (length 30 μm, diameter 60nm) , after stirring for 20 minutes, then add 0.03kg of leveling agent with polydimethylsiloxane skeleton structure (manufactured by BYK Chemicals; trade name: BYK-377) and 0.33kg of photoinitiator (China Taiwan Double Bond Chemical Co., Ltd. Co., Ltd., trade name: Doublecure 184), after stirring for 30 minutes, a cured resin composit...

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Abstract

The invention relates to the technical field of a flexible transparent conductive film, in particular to a curing resin composition and a transparent conductive film. In order to solve the problems that the conventional transparent conductive film has slightly high haze and slightly low full light transmittance, the invention provides the curing resin composition and the transparent conductive film. The problem of adhesive force of a metal nanowire and a carbon nanotube on a base material is solved. The curing resin composition comprises an ionizing radiation curing reactive substrate, a photoinitator, a carbon nanotube and a metal nanowire. The transparent conductive film comprises a base material and a transparent conductive layer; and the conductive layer comprises resin, a carbon nanotube and a metal nanowire. The transparent conductive layer is formed after the curing resin composition is cured. The transparent conductive film provided by the invention has low haze, low sheet resistance, high full light transmittance, high physical property and flexibility, can be applied to continuous roll production and has high production efficiency.

Description

technical field [0001] The invention relates to the technical field of flexible transparent conductive films, in particular to a cured resin composition and a transparent conductive film. Background technique [0002] Transparent conductive film refers to a visible light transmittance of more than 80% and a sheet resistance value of less than 1000 Ω / □. Depending on its conductivity, the application is different. For example, when the sheet resistance value is less than 1000 Ω / □, it can be used for liquid crystal displays. , resistive touch panel, electromagnetic wave protection, anti-static film; when the sheet resistance value is 40~300Ω / □, it can be used for capacitive touch panel, organic light-emitting diode, home appliance LCD panel, smart glass, etc.; sheet resistance When the value is less than 10Ω / □, it can be applied to related products such as large liquid crystal displays and solar cells. [0003] Indium tin oxide (ITO for short) is a ceramic material of metal ox...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D5/24C08J7/04C08L67/02
CPCC08J7/0427C08J2367/02C08J2475/14C08K2201/011C08L2205/025C09D5/24C09D175/14C08L75/14C08K3/041C08K7/06
Inventor 史良李宇芬张克然张永汉
Owner 宁波安特弗新材料科技有限公司