A test method for nitrobenzene compounds in textiles and leather products
A leather product and testing method technology, applied in the field of chemical testing, can solve the problems of few testing methods, inaccurate measured quantity, poor effect of nitrobenzene compounds, etc.
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Embodiment 1
[0042] Use high performance liquid chromatography, gas chromatography, gas chromatography-mass spectrometry to test nitrobenzene compounds in textiles and leather products, and the steps are as follows:
[0043] 1. Pretreatment method:
[0044] (1) The pretreatment method of textiles is: accurately weigh 1.0 g (accurate to 0.01 g) of sample, and put it into a fast solvent extraction apparatus for extraction. The conditions of fast solvent extraction were: extraction temperature 70 ℃; pressure: 10.34 MPa; extraction cell volume 10 mL; static extraction time 5 min; extraction solvent was methanol; cleaning volume was 60% of cell volume; purge time 100 s; cycle Times: 5 times. After the extraction was completed, the extract was collected in a chicken heart bottle, rotary evaporated in a water bath at 40 °C until it was nearly dry, then blown dry with nitrogen, and dilute to 2.0 mL with methanol solution for instrumental testing and analysis.
[0045] (2) The pretreatment method...
Embodiment 2
[0055] Use high performance liquid chromatography, gas chromatography, gas chromatography-mass spectrometry to test nitrobenzene compounds in textiles and leather products, and the steps are as follows:
[0056] 1. Pretreatment method:
[0057] (1) The pretreatment method of textiles is: accurately weigh 1.0 g (accurate to 0.01 g) of sample, and put it into a fast solvent extraction apparatus for extraction. The conditions of fast solvent extraction were: extraction temperature 60 ℃; pressure: 9.0 MPa; extraction cell volume 10 mL; static extraction time 4 min; extractant was toluene; cleaning volume was 60% of cell volume; purge time 100 s; cycle Times: 5 times. After the extraction was completed, the extract was collected in a chicken heart bottle, rotary evaporated in a water bath at 40 °C until it was nearly dry, then blown dry with nitrogen, and dilute to 2.0 mL with methanol solution for instrumental testing and analysis.
[0058] (2) The pretreatment method of leather...
Embodiment 3
[0065] Use high performance liquid chromatography, gas chromatography, gas chromatography-mass spectrometry to test nitrobenzene compounds in textiles and leather products, and the steps are as follows:
[0066] 1. Pretreatment method:
[0067] (1) The pretreatment method of textiles is: accurately weigh 1.0 g (accurate to 0.01 g) of sample, and put it into a fast solvent extraction apparatus for extraction. The conditions of fast solvent extraction are: extraction temperature 75°C; pressure: 11.0 MPa; extraction cell volume 10 mL; static extraction time 6 min; Number of cycles: 5 times. After the extraction was completed, the extract was collected in a chicken heart bottle, rotary evaporated in a water bath at 40 °C until it was nearly dry, then blown dry with nitrogen, and dilute to 2.0 mL with methanol solution for instrumental testing and analysis.
[0068] (2) The pretreatment method of leather products is: accurately weigh 1.0 g (accurate to 0.01 g) of sample, and put it...
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