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A glass-ceramic float preparation process applied to 5g communication mobile terminals

A technology of glass-ceramics and mobile terminals, which is applied in the field of glass-ceramics float preparation process applied to 5G communication mobile terminals, can solve the problems of limited forming thickness, low glass viscosity, and shortened life, and achieve improved mechanical properties and mechanical properties. Excellent performance and strong devitrification resistance

Active Publication Date: 2021-08-10
GLASS TECH RES INST OF SHAHE CITY OF HEBEI PROVINCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This can cause severe erosion of the forehearth and damage to the heating element, resulting in a shortened life
In addition, high-temperature flattening also has problems in the forming process. The viscosity of the glass is very low, which leads to the failure of the edge pulling machine. It is easy to cause a full board accident during production, and the process is not easy to control. In addition, the forming thickness will be limited.
At present, the thickness of float glass-ceramic is limited to more than 3mm, so that the current float glass-ceramic can only be used for decorative plates and cannot be used for 5G communication mobile terminals

Method used

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  • A glass-ceramic float preparation process applied to 5g communication mobile terminals

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Experimental program
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Effect test

Embodiment 1

[0038] A float method for preparing glass-ceramics for 5G communication mobile terminals, the preparation process is as follows:

[0039] A. First, the raw materials are accurately weighed according to the material recipe, and the batches that are forced to mix evenly are put into the feeding pool at regular intervals and quantitatively. The ingredients are as follows: 50 parts of quartz sand, 10.5 parts of alumina, 15 parts of sodium carbonate, 2.5 parts of potassium nitrate, 2 parts of lithium carbonate, 9.5 parts of magnesium oxide, 3 parts of titanium oxide, 2.5 parts of zirconia, 4 parts of zinc oxide, 0.5 parts of rubidium, 0.25 parts of gallium oxide, 0.25 parts of europium oxide;

[0040] B. The batch material in the melting pool is heated to 1525°C for melting, clarified, stirred and homogenized to obtain a defect-free molten glass of good quality;

[0041] C. Float forming: Cool the above molten glass to 1200°C and flow it into a tin bath for forming, flatten and po...

Embodiment 2

[0046] A. First, the raw materials are accurately weighed according to the material recipe, and the batches that are forced to mix evenly are put into the feeding pool at regular intervals and quantitatively. The ingredients are as follows: 52 parts of quartz sand, 15.5 parts of alumina, 26.3 parts of sodium carbonate, 4.6 parts of potassium nitrate, 13.3 parts of magnesium oxide, and 4.45 parts of ammonium dihydrogen phosphate.

[0047] B. The batch material in the melting pool is heated to 1500°C for melting, clarified, stirred and homogenized to obtain a high-quality defect-free molten glass.

[0048] C. Float forming: Cool the above molten glass to 1200°C and flow it into a tin bath for forming, flatten and polish at 1130°C, and pull down to thin at 950°C.

[0049] D. When the glass ribbon is cooled to 650°C, enter the annealing kiln for annealing, nucleate at 680°C for 2 hours, and crystallize at 800°C for 2 hours to obtain the original glass ceramics.

[0050] E. Soak t...

Embodiment 3

[0053] A. First, the raw materials are accurately weighed according to the material recipe, and the batches that are forced to mix evenly are put into the feeding pool at regular intervals and quantitatively. The ingredients are as follows: 48.2 parts of quartz sand, 20.6 parts of alumina, 24.5 parts of sodium carbonate, 2.3 parts of potassium nitrate, 10.6 parts of lithium carbonate, 7.5 parts of magnesium oxide, 2 parts of zirconia, 1.55 parts of ammonium dihydrogen phosphate, and 1 part of antimony oxide , rubidium oxide 1 part

[0054] B. The batch materials in the melting pool are heated to 1550°C for melting, clarified, stirred and homogenized to obtain a high-quality defect-free molten glass.

[0055] C. Float forming: Cool the above molten glass to 1225°C and flow it into a tin bath for forming, flatten and polish at 1193°C, and pull down to thin at 1010°C.

[0056] D. When the glass ribbon is cooled to 600°C, enter the annealing kiln for annealing, nucleate at 650°C ...

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Abstract

A glass-ceramics float preparation process applied to 5G communication mobile terminals, belonging to the technical field of glass-ceramics, comprising the following steps: A, raw material preparation: prepare 45-75 parts of quartz sand, alumina 10‑25 parts, 14.5‑39.6 parts of sodium carbonate, 2.3‑9.2 parts of potassium nitrate, 0‑12.5 parts of lithium carbonate, 0‑20 parts of magnesium oxide, 0‑8 parts of titanium oxide, 0‑20 parts of zirconium oxide, 0 parts of zinc oxide -10 parts, 0-9 parts of ammonium dihydrogen phosphate, 0-3 parts of antimony oxide, 0-3 parts of europium oxide, 0-5 parts of iron oxide, mixed to obtain batch materials; B, glass melting; C, float method Forming; D. Glass annealing, nucleation, crystallization, and chemical strengthening to obtain glass-ceramic used in 5G communication mobile terminals. The glass-ceramic prepared by the preparation process of the present invention has excellent optical properties and mechanical properties, excellent surface flatness, and no defects such as ribs and stripes, and can be used for display protection screens and back cover protection shells of electronic terminals.

Description

technical field [0001] The invention belongs to the technical field of glass-ceramics, and relates to glass-ceramic applications applied to 5G communication mobile terminals or other glass applications requiring antimagnetism, light transmittance, strength, etc., and specifically relates to a glass-ceramic applied to 5G communication mobile terminals Float process, the glass-ceramic prepared by the process of the present invention has excellent optical properties and mechanical properties, the visible light transmittance can reach 91%, the surface stress can reach 850Mpa, the stress depth can reach more than 25μm, even more than 60μm, and the hardness Up to 7GPa, four-point bending strength up to 550MPa, surface roughness 0.5nm (Ra), bubble content less than 0.05 bubbles / cm 3 , and no defects such as ribs and stripes. It can be used for electronic terminal display protection screen and rear cover protection shell. Background technique [0002] Almost all portable electroni...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C3/11C03B18/02C03B25/00C03C21/00
CPCC03B18/02C03B25/00C03C3/111C03C21/002
Inventor 郑伟宏袁坚田培静杜晓欧彭志钢史连莹张茂森刘皓
Owner GLASS TECH RES INST OF SHAHE CITY OF HEBEI PROVINCE