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A kind of preparation method of low-density flame-retardant polyethylene plastic

A flame-retardant polyethylene and low-density technology, which is applied in the field of preparation of low-density flame-retardant polyethylene plastics, can solve the problems of reducing the mechanical properties of polyethylene and the easy burning of polyethylene, and achieve enhanced anti-aging performance, reduced toxicity, The preparation method is simple and environmentally friendly

Active Publication Date: 2021-02-26
SHANTOU SHUANGPENG PLASTIC IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the problem that traditional polyethylene is easy to burn, the traditionally added flame retardants significantly reduce the mechanical properties of polyethylene. This invention provides a method for preparing low-density flame-retardant polyethylene plastics.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A method for preparing environmentally friendly low-density flame-retardant polyethylene plastics, the preparation steps are as follows:

[0022] (1) Mix pentaerythritol and phosphoric acid at a molar ratio of 1:4.1, stir at room temperature for 30 minutes, heat to 90°C, and react for 2 hours to form a mixture of pentaerythritol and phosphate;

[0023] (2) After adding montmorillonite k10 of 0.5 times the amount of pentaerythritol to the pentaerythritol phosphate mixture, stirring at room temperature for 24 hours, then heating to 100° C. and maintaining for 1 hour, filtering to prepare pentaerythritol phosphate montmorillonite;

[0024] (3) After dispersing the pentaerythritol phosphate montmorillonite in 30% choline chloride-urea eutectic reagent-water mixture, add 1.05 times the amount of melamine of pentaerythritol, and then raise the temperature of the mixture to 110°C to react 8 Hours later, the reaction solution was filtered, and the obtained solid was recrystalli...

Embodiment 2

[0027] A method for preparing environmentally friendly low-density flame-retardant polyethylene plastics, the preparation steps are as follows:

[0028] (1) Mix pentaerythritol and phosphoric acid at a molar ratio of 1:4, stir at room temperature for 30 minutes and heat to 90°C, and react for 2 hours to form a pentaerythritol phosphate mixture;

[0029] (2) After adding montmorillonite k10 of 0.5 times the amount of pentaerythritol to the pentaerythritol phosphate mixture, stirring at room temperature for 24 hours, then heating to 100° C. and maintaining for 1 hour, filtering to prepare pentaerythritol phosphate montmorillonite;

[0030] (3) After dispersing the pentaerythritol phosphate montmorillonite in 35% choline chloride-urea eutectic reagent-water mixture, add 1 times the amount of melamine of pentaerythritol, and then raise the temperature of the mixture to 100°C to react 9 Hours later, the reaction solution was filtered, and the obtained solid was recrystallized with ...

Embodiment 3

[0033] A method for preparing environmentally friendly low-density flame-retardant polyethylene plastics, the preparation steps are as follows:

[0034] (1) Mix pentaerythritol and phosphoric acid at a molar ratio of 1:4, stir at room temperature for 30 minutes and heat to 90°C, and react for 2 hours to form a pentaerythritol phosphate mixture;

[0035] (2) After adding montmorillonite k10 of 0.5 times the amount of pentaerythritol to the pentaerythritol phosphate mixture, stirring at room temperature for 24 hours, then heating to 100° C. and maintaining for 1 hour, filtering to prepare pentaerythritol phosphate montmorillonite;

[0036] (3) After dispersing the pentaerythritol phosphate montmorillonite in 25% choline chloride-urea eutectic reagent-water mixture, add melamine with 1.05 times the amount of pentaerythritol, and then raise the temperature of the mixture to 110°C for 9 Hours later, the reaction solution was filtered, and the obtained solid was recrystallized with ...

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PUM

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Abstract

The invention discloses a preparation method of low-density flame-retardant polyethylene plastic. The preparation method first uses pentaerythritol as a raw material, reacts with phosphoric acid, montmorillonite and melamine in turn to prepare a new type of flame retardant pentaerythritol phosphate montmorillonite melamine salt (MPPM); then low-density polyethylene, MPPM, antioxidant After mixing, a twin-screw extruder is used to prepare a low-density flame-retardant polyethylene plastic. The environmentally friendly low-density flame-retardant polyethylene plastic prepared by the invention has good flame-retardant performance and excellent mechanical properties.

Description

technical field [0001] The invention relates to the technical field of plastics, in particular to a method for preparing low-density flame-retardant polyethylene plastics. Background technique [0002] Polyethylene is a thermoplastic resin material obtained by polymerization of ethylene monomer. Polyethylene is non-toxic, easy to store, smooth to the touch, and has excellent low temperature resistance, chemical properties, and stability. Polyethylene can be processed by conventional thermoforming methods, and is mainly used to manufacture wires and cables, plastic bags, packaging plastics, electronic components, building materials, daily necessities, etc., and has a wide range of uses. With the development of the chemical industry and the improvement of people's living standards, the application of polyethylene has been rapidly increased, and the output accounts for about 25% of the total plastic usage. But no matter what kind of polyethylene material has a fatal weakness,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08K5/521C08K3/34C08K5/3492C08K5/13C08K13/02
CPCC08K3/34C08K5/13C08K5/34922C08K5/521C08K13/02C08L23/06
Inventor 马育胜
Owner SHANTOU SHUANGPENG PLASTIC IND