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Method for separating iron from vanadium titano-magnetite

A technology for vanadium-titanium magnetite and iron selection, which is applied in the field of metallurgy, can solve the problems of high energy consumption for smelting metallized pellets, poor separation effect of iron and vanadium-titanium, dispersion of vanadium-titanium, etc., to achieve high-efficiency utilization, The effect of reducing reaction energy consumption and reducing system reduction temperature

Inactive Publication Date: 2019-01-04
HEBEI IRON AND STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] Although the above method has realized the effective treatment of vanadium-titanium magnetite, there are common problems of high reduction temperature, high energy consumption and long time for smelting metallized pellets, poor separation effect of iron and vanadium-titanium, dispersion of vanadium-titanium direction and vanadium-titanium Defects such as low yield

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  • Method for separating iron from vanadium titano-magnetite
  • Method for separating iron from vanadium titano-magnetite

Examples

Experimental program
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Effect test

Embodiment 1

[0044] like figure 1 Shown, the present embodiment carries out the operation of vanadium-titanium-magnetite iron selection according to the following methods:

[0045] (1) Take 10g of vanadium-titanium magnetite, grind the ore to pass through a -80 mesh sieve, add 1.91g of graphite, 0.71g of PVA, 0.3g of anhydrous sodium carbonate, 0.1g of ammonium carbonate and 0.5ml of water, and press the ball after mixing;

[0046] (2) Place the pellets obtained in step (1) in a rotary kiln, feed in natural gas, heat up to 1000° C. to reduce the pellets for 1 hour, and water quench and cool after the reduction to obtain the reduced product;

[0047] (3) the reduction product that step (2) is obtained is crushed, and the ball milling into a particle diameter is a fine powder of -200 mesh. In the magnetic separation tube, the magnetic field intensity is controlled to be 70mT for magnetic separation. After the magnetic separation, a magnetic product and a non-magnetic product are obtained. M...

Embodiment 2

[0050] (1) Take 10g of vanadium-titanium magnetite, grind the ore to pass through a -200 mesh sieve, add 2.39g of graphite, 0.37g of starch, 0.3g of anhydrous sodium carbonate, 0.3g of ammonium carbonate and 0.6ml of water, and press the ball after mixing;

[0051] (2) Place the pellets obtained in step (1) in a rotary kiln, feed in natural gas, heat up to 1200° C. to reduce the pellets for 2 hours, and water quench and cool after the reduction to obtain the reduced product;

[0052] (3) the reduction product that step (2) is obtained is crushed, and the ball milling into a particle diameter is a fine powder of -200 mesh, and in the magnetic separation tube, the magnetic field intensity is controlled to be 35mT for magnetic separation, and magnetic product and non-magnetic product are obtained after magnetic separation, Metallic iron accounts for 98% of the total iron in the magnetic products.

[0053] The obtained magnetic product is used for converter steelmaking or powder m...

Embodiment 3

[0055] (1) Take 10g of vanadium-titanium magnetite, grind it to pass through a -120 mesh sieve, add 3.58g of petroleum coke, 0.68g of PVA, 0.2g of anhydrous sodium carbonate, 0.2g of ammonium carbonate and 0.8ml of water, mix and press the ball ;

[0056] (2) Place the pellets obtained in step (1) in a pusher kiln, feed blast furnace gas, heat up to 1100° C. to reduce the pellets for 1.5 hours, and water quench and cool after the reduction to obtain the reduced product;

[0057] (3) the reduction product that step (2) is obtained is crushed, and the ball milling into a particle diameter is a fine powder of -400 mesh, and in the magnetic separation tube, the magnetic field intensity is controlled to be 100mT for magnetic separation, and magnetic product and non-magnetic product are obtained after magnetic separation, Metallic iron accounts for 95% of the total iron in the magnetic products.

[0058] The obtained magnetic product is used for converter steelmaking or powder meta...

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Abstract

The invention relates to a method for separating iron from vanadium titano-magnetite. The method comprises the following steps: mixing the vanadium titano-magnetite, a reducing agent and ammonium carbonate, raising the temperature in a reducing atmosphere to carry out a reduction reaction, performing water quenching cooling on the materials after the reaction is ended to obtain a reduction product; crushing and grinding the reduction product, and performing magnetic separation to obtain a magnetic product and a non-magnetic product. According to the method disclosed by the invention, deep ironseparation of the vanadium titano-magnetite is realized by directly utilizing a manner of direct reduction-grinding iron separation, and the metal iron in the obtained magnetic product accounts for 92% or higher of total iron. Meanwhile, the reaction energy consumption of the system is reduced, the reaction efficiency is improved, and the whole process is simple and clean, and the method has excellent economic benefits and application prospects.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and in particular relates to a method for selecting iron from vanadium-titanium magnetite. Background technique [0002] Vanadium-titanium magnetite is a composite iron ore that contains iron, titanium, vanadium, chromium and other beneficial elements. It is mainly distributed in Panxi, Chengde and Ma'anshan in China. At present, the method of using vanadium-titanium magnetite in my country is the blast furnace method, and the main problem is that the recovery rate of valuable components of iron, vanadium and titanium is not high. In addition, with the increasing shortage of coking coal, the separation process of vanadium-titanium-magnetite blast furnace method will be severely restricted. At present, the non-blast furnace method, especially the use of coal-based direct reduction technology to treat vanadium-titanium magnetite has become a research hotspot. Practice has proved that the direc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21B13/00B03C1/015
CPCB03C1/015C21B13/006C21B13/008Y02P10/143
Inventor 李兰杰周欣常福增高明磊王树生
Owner HEBEI IRON AND STEEL