Desorption method for recovery of low-concentration adsorbed phase and non-adsorbed phase components by psa
A non-adsorption, phase component technology, applied in separation methods, chemical instruments and methods, dispersed particle separation, etc., can solve problems such as increased PSA load, reduced pressure utilization of adsorption towers, and reduced adsorption efficiency
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Embodiment 1
[0040] Such as figure 1 Shown, a kind of PSA reclaims the desorption method of low concentration adsorption phase and non-adsorption phase component, comprises the steps:
[0041] (1) The components are 44.6% (volume ratio, the same below) H2, 12.5% C2+, 25.5% CH4, 14.4% N2 and 3% other impurities, the pressure is 1.5MPa, the temperature is 60°C, and the flow rate is 10,000 standard The raw material gas composed of cubic meters per hour enters the pressure transformation of the first section of 6 towers consisting of adsorption, forward discharge, reverse discharge I, reverse discharge II / vacuumization, flushing, reverse pressure charging, forward pressure charging and final charging steps The adsorption system (1#PSA) performs adsorption, wherein the hydrogen gas flowing out of the non-adsorbed phase gas has a purity greater than or equal to 99%, and a yield greater than or equal to 80%, which is output as the product gas of the non-adsorbed phase component.
[0042] (2) A...
Embodiment 2
[0055] Such as figure 2 Shown in (dotted line), on the basis of the desorption method that a kind of PSA described in embodiment 1 reclaims low-concentration adsorption phase and non-adsorption phase components, the replacement gas of described 2#PSA replacement step can also come from through The product gas of the adsorption phase component of the pressurized 2#PSA is used as a supplement or switch for standby. Moreover, a part of the replacement waste gas can enter the intermediate tank, so that the gas can continuously enter the pressurization and membrane separation system, or continuously perform reverse pressure to the adsorption tower in the reverse pressure step in 2#PSA.
Embodiment 3
[0057] Such as figure 1 Shown, on the basis of the desorption method that a kind of PSA described in embodiment 1 reclaims low-concentration adsorption phase and non-adsorption phase components, described from the permeation of the membrane separation system between 1#PSA and 2#PSA gas, the pressure drops to 0.3-0.4MPa, and enters the second stage of the 5-tower pressure swing adsorption system ( 2#PSA) for adsorption, the adsorption pressure is 0.3-0.4MPa, the obtained non-adsorbed phase gas is pressurized to 2.0MPa, mixed with raw material gas, enters 1#PSA to continue adsorption, the adsorption pressure is 2.0MPa, and further recovery 2 H2 and C2+ in the non-adsorption phase gas of #PSA; The non-permeable gas is depressurized to 0.3~0.4MPa through the pressure reducing valve, and is used as the replacement gas to replace the adsorption tower in the replacement step in 2#PSA, thereby Realize the difference in the two-stage PSA adsorption pressure.
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