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Oil dechlorination agent

A dechlorinating agent and oil technology, applied in the petroleum industry, fuel additives, liquid carbon-containing fuels, etc., can solve the problems of complex preparation process, harsh operating conditions, equipment corrosion, etc., and achieve superior solubility and good bonding stability , good dispersion performance

Inactive Publication Date: 2019-03-05
唐锦宁
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The presence of organic chlorides will seriously affect the subsequent processing and refining of crude oil. For example, in the reforming process, the raw materials are pre-hydrotreated, and organic chlorides will be converted into hydrogen chloride. Hydrogen chloride forms hydrochloric acid and chloride with water and ammonia, respectively. Ammonium will cause serious corrosion to the equipment and block the pipeline. In serious cases, the device will be forced to stop for maintenance and cause huge economic losses to the enterprise.
[0003] At present, the most common way to remove organic chlorine is to use dechlorination agents. Most of the commercially available oil dechlorination agents have defects such as complicated preparation process, harsh operating conditions, narrow application range, and cumbersome follow-up treatment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] The following raw materials were weighed in parts by weight: 30 parts of 3-propanolamine, 20 parts of ethylenediamine, and 38 parts of triethylenediamine. Mix the raw materials evenly, and then filter to remove impurities.

[0013] Adding 35 μg / g of the dechlorination agent to the electric desalination injection water of the atmospheric and vacuum device, the chlorine content removal rate reaches 88%.

Embodiment 2

[0015] Weigh the following raw materials in parts by weight: 25 parts of 3-propanolamine, 22 parts of ethylenediamine, and 42 parts of triethylenediamine. Mix the raw materials evenly, and then filter to remove impurities.

[0016] Adding 35 μg / g of the dechlorination agent to the electric desalination injection water of the atmospheric and vacuum device, the chlorine content removal rate reaches 82%.

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PUM

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Abstract

The invention relates to an oil dechlorination agent, and belongs to the technical field of petrochemical industry. The oil dechlorination agent is composed of the following raw materials in parts byweight: 25 to 35 parts of 3-propanolamine, 15 to 25 parts of ethylenediamine, and 35 to 45 parts of triethylenediamine. The raw materials are uniformly mixed, and then impurities are removed by filtration, so that the oil dechlorination agent is obtained. The oil dechlorination agent of the invention has stable performance, excellent dissolving performance and good dispersing performance in raw oil, good stability with organic chloralkane, and a low usage amount, and the usage amount is 35 [mu]g / g which is a weight of raw oil for normal- and reduced-pressure electric desalination processing.

Description

technical field [0001] The invention relates to an oil dechlorination agent, which belongs to the technical field of petrochemical industry. Background technique [0002] Crude oil is composed of more than 95% carbon and hydrogen compounds, and the remaining 5% is organic and inorganic heteroelement compounds composed of sulfur, chlorine, nitrogen and metal elements. Although the content of such compounds is small, it affects the quality of the entire refinery. Process and product quality. From the perspective of corrosion and anti-corrosion, some of these impurities contained in crude oil are themselves corrosive media, such as hydrogen sulfide, elemental sulfur, mercaptans, organic acids, etc., and some will be converted into corrosive media during processing. For example, the hydrolysis of inorganic salt magnesium chloride produces magnesium hydroxide and hydrochloric acid. In addition to inorganic chlorides, crude oil also contains some organic chlorides. The organic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/14C10L10/18C10L1/222
CPCC10L1/14C10L1/2222C10L1/2225C10L10/18C10L2300/20
Inventor 唐锦宁
Owner 唐锦宁