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Method of one-dimensional co-assembly by micron and/or nanoparticles with different particle sizes, substrate and application

A nanoparticle and co-assembly technology, which is applied in the direction of nanotechnology, nanotechnology, and nanotechnology for materials and surface science, can solve problems such as harsh conditions, high particle requirements, and poor patterning effects, and achieve more patterned patterns. , the effect of pattern refinement

Pending Publication Date: 2019-04-02
INST OF CHEM CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] The purpose of the present invention is to overcome the harsh conditions existing in the prior art, high particle requirements, poor controllability of forming structures, poor patterning effect, and difficulty in realizing ordered one-dimensional co-assembly of two kinds of micron and / or nanoparticle The problem of structure, providing a method for one-dimensional co-assembly of micron and / or nanoparticle with different particle sizes, and the substrate and application of one-dimensional co-assembly structure containing micron and / or nanoparticle with different particle size prepared by this method

Method used

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  • Method of one-dimensional co-assembly by micron and/or nanoparticles with different particle sizes, substrate and application
  • Method of one-dimensional co-assembly by micron and/or nanoparticles with different particle sizes, substrate and application
  • Method of one-dimensional co-assembly by micron and/or nanoparticles with different particle sizes, substrate and application

Examples

Experimental program
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Effect test

Embodiment 1

[0098] Select the silicon wafer, adopt the mask optical etching method, etch the surface of the silicon wafer to have a prominent linear column array structure (such as Figure 2a shown) as the first substrate, in which each linear column array unit is 200 μm (C) × 12 μm (H) × 3 μm (W), choose a silicon wafer with a flat surface as the second substrate, use ethanol and ultrapure The second substrate was ultrasonically cleaned with water for 10 minutes, and then dried with nitrogen gas for later use. Mix polystyrene colloidal particles with a particle size of 1.8 μm and polystyrene colloidal particles with a particle size of 0.3 μm at a mass ratio of 2:1 to prepare dodecylbenzenesulfonate with a mass fraction of nanoparticles of 0.5%. Sodium acid is 0.1%, water is 99.4% mixed suspension. The surfaces of the first substrate and the second substrate were treated with a surface plasma surface treatment instrument (manufactured by Alcatel, model 601E) with a power of 80W for 60s. ...

Embodiment 2

[0101] Select a quartz plate, and use mask optical etching to etch a prominent curved column array structure on the surface of the quartz plate (such as Figure 2bshown) as the first substrate, wherein each curved column is 200 μm (C) × 10 μm (H) × 2 μm (W), the C of the curved column refers to the total length of each curved column, and the quartz with a flat surface is selected The sheet was used as the second substrate, and the second substrate was ultrasonically cleaned with ethanol and ultrapure water for 10 minutes and then dried with nitrogen gas for later use. CdSe quantum dots with a particle size of 2 μm are used as the core, the core is coated with silica core-shell particles, and CdSe quantum dots with a particle size of 0.2 μm are used as the core, and the core is coated with a shell core of silica The particles of the structure were mixed according to the mass ratio of 3:1 to prepare a mixed suspension with a mass fraction of micron and nano particles of 0.3%, so...

Embodiment 3

[0104] Choose the PDMS film, adopt the method of mask optical etching, etch out the array structure (such as Figure 2c shown) as the first substrate, wherein each array unit composed of straight columns and curved columns is 200 μm (C)×10.2 μm (H)×3.4 μm (W). A PDMS membrane with a flat surface was selected as the second substrate, and the second substrate was ultrasonically cleaned with ethanol and ultrapure water for 10 minutes and then dried with nitrogen gas for later use. Mix polystyrene microspheres with a particle size of 2 μm and silicon dioxide microspheres with a particle size of 0.84 μm and a mass ratio of 2:1 to prepare a particle with a mass fraction of microns and nanoparticles. 5%, stearic acid 0.3%, water 94.7% mixed suspension. The surfaces of the first substrate and the second substrate were treated with 80W power of a surface plasma surface treatment instrument for 60s. Take 2.5 μL of the suspension and drop it on the surface of the first substrate of 5mm...

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Abstract

The invention relates to the field of assembly of micro-nanoparticles, in particular to a method of one-dimensional co-assembly by micron and / or nanoparticles with different particle sizes, a substrate and application. The preparation method comprises steps: a suspension containing particles A and B is dripped on the surface of a first substrate with a prominent column array structure surface; thefirst substrate and a second substrate with a flat surface are arranged parallelly at a distance of L; after volatilization of the solvent in the suspension, the first substrate and the second substrate are separated; and a one-dimensional co-assembly structure containing particles A and B is formed on the surface of the second substrate, wherein the particles A and B are micron and / or nanoparticles with different particle sizes, the particle size ratio of D to d is 1 to (0.001-0.5), the ratio of L to D is 1.2-3, or, the ratio of L to d is below 1.2. The method is strong in controllability, and the prepared co-assembly structure has the advantages of being orderly, more refined in patterns and complex in structure, and being composite to a multi-functional material.

Description

technical field [0001] The present invention relates to the field of assembly of micro-nanoparticles, in particular to a method for one-dimensional co-assembly of micron and / or nanoparticle with different particle sizes, and a one-dimensional co-assembly method containing micron and / or nanoparticle with different particle sizes. Substrates and applications for assembled structures. Background technique [0002] With the extensive research on the synthesis of micro-nano particles and the increasingly obvious application value in industry, it provides a broad prospect and development space for the development of particle-based microelectronic circuits, optical components and magnetic devices. Particle assembly, as a bottom-up economical and environmentally friendly method, has shown great potential in the development of a variety of new materials and functional devices, especially the co-assembly of mixed particles is very important for the preparation of a variety of new mate...

Claims

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Application Information

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IPC IPC(8): B81C1/00B82Y30/00B82Y40/00
CPCB81C1/00031B81C1/00349B82Y30/00B82Y40/00B81B2207/056
Inventor 郭丹李亚楠宋延林
Owner INST OF CHEM CHINESE ACAD OF SCI