Preparation method of titanium alloy ingot containing prone to segregation elements
A technology of titanium alloy and easy segregation is applied in the field of preparation of titanium alloy ingots, which can solve problems such as being difficult to realize, and achieve the effects of reducing segregation, shortening solute redistribution time and uniform composition.
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[0026] The present invention proposes the preparation method of this alloy, specifically comprises the following steps:
[0027] 1) Master alloy selection
[0028] The main elements of the titanium alloy ingot are analyzed, and the main element ratio in the titanium alloy ingot is added in the form of a ternary or higher intermediate alloy; the matrix is titanium sponge, and the ternary or higher intermediate alloy is guaranteed not to be added. Or add less other elements. If the composition of the target ingot is not satisfied, add a pure metal or binary alloy to meet the composition of the target ingot.
[0029] 2) Electrode preparation
[0030] According to the composition of the titanium alloy ingot to be prepared, the intermediate alloy of ternary and above ternary, titanium sponge, aluminum bean or titanium-tin alloy is weighed according to the mass percentage of the target ingot, and the electrode block is pressed after mixing evenly. Then the pressed electrode grou...
Embodiment 1
[0044] 500Kg grade TB3 titanium alloy (nominal composition Ti-3.5Al-10Mo-8V-1Fe) ingot preparation:
[0045] 1) Master alloy selection
[0046] Contain Al, Mo, V, Fe in this alloy, wherein Mo, Fe are easy segregation elements, select molybdenum vanadium aluminum iron master alloy (Mo, V, Al, Fe mass ratio is 45:36: 14:5), wherein the grain size of the alloy is controlled at 0.25-3mm;
[0047] 2) Electrode preparation
[0048] The molybdenum-vanadium-aluminum-iron master alloy, titanium sponge and aluminum beans are weighed according to the mass percentage, mixed evenly, and the electrode block is pressed, and then the pressed electrode group is welded into an electrode.
[0049] 3) One smelting
[0050] The electrode prepared in step 2) is used as a consumable electrode in a vacuum consumable electric arc furnace to obtain a φ220mm primary ingot, the melting current is 8.0-10.0KA, and the arc-stabilizing current is DC7-8A;
[0051] 4) Secondary smelting
[0052] The prima...
Embodiment 2
[0059]700Kg grade TB5 titanium alloy (nominal composition Ti-10V-3Al-3Cr-3Sn) ingot preparation:
[0060] 1) Master alloy selection
[0061] Contain V, Al, Cr, Sn in this alloy, wherein Cr, Sn are easy segregation elements, select vanadium-aluminum-chromium-tin master alloy (V, Al, Cr, Sn mass ratio is 64:12: 12:10), wherein the grain size of the alloy is controlled at 0.25-3mm;
[0062] 2) Electrode preparation
[0063] The vanadium-aluminum-chromium-tin master alloy, titanium sponge and titanium-tin alloy are weighed according to the mass percentage, mixed evenly, and the electrode block is pressed, and then the pressed electrode group is welded into an electrode.
[0064] 3) One smelting
[0065] The electrode prepared in step 2) is used as a consumable electrode in a vacuum consumable electric arc furnace to obtain a φ220mm primary ingot, the melting current is 8.0-10KA, and the arc-stabilizing current is DC 6.0-7.0A;
[0066] 4) Secondary smelting
[0067] The primar...
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