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A method for preparing activated coke from chemical carbon-containing waste

A carbon waste and activated coke technology, which is applied in the field of using chemical carbon-containing waste to prepare activated coke, can solve the problems of tailings and waste that cannot be reused or have low utilization value, and achieve reduced desulfurization and denitrification costs, high desulfurization value and denitrification rate , high compressive strength and high wear resistance

Active Publication Date: 2022-05-10
鞍钢化学科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The invention provides a method for preparing active coke by utilizing chemical carbon-containing waste, which not only solves the problem that a large amount of tailings and waste in the chemical industry cannot be reused or the use value is too low, but also produces active coke whose demand in the environmental protection industry is increasing day by day products, reducing desulfurization and denitrification costs for iron and steel enterprises

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] In this example, the carbon-containing chemical waste is a mixture of coke powder and heavy-phase coal tar pitch; the coke powder is coke obtained from coking coal by high-temperature dry distillation at 1000°C and then sieved. The particle size is less than 10mm, the mass fraction of fixed carbon in the coke powder is 78%, the mass fraction of ash is 14%, the mass fraction of volatile matter is 0.8%, and the mass fraction of total sulfur is 0.8%; the heavy phase coal tar pitch is produced The remaining bitumen tailings with a softening point of 78°C in the needle coke process, the coking value of the heavy phase coal tar pitch is 55%, and the mass percentage of quinoline insoluble matter is 15%.

[0029] The chemical carbon-containing waste is composed of the following components by mass percentage: heavy phase pitch 25%, coke powder 75%.

[0030] The heavy phase asphalt and coke powder are crushed and ground separately, and then uniformly mixed to obtain a mixed raw m...

Embodiment 2

[0033] In this embodiment, the carbon-containing chemical waste is a mixture of coke powder and heavy-phase coal tar pitch; the coke powder is coking dust removal ash with a particle size of less than 10mm, the mass fraction of fixed carbon in the coke powder is 76%, and the mass fraction of ash is Fraction is 17%, the mass fraction of volatile matter is 0.5%, and the mass fraction of total sulfur is 1.0%. The coking value of phase coal tar pitch is 58%, and the mass percentage of quinoline insoluble matter is 13%.

[0034] The chemical carbon-containing waste is composed of the following components by mass percentage: heavy phase pitch 35%, coke powder 65%.

[0035] The heavy phase pitch and coke powder were crushed and ground separately, and then uniformly mixed to obtain carbonized raw materials, and tar with a mass fraction of 18% and water with a mass fraction of 10% were added to the carbonized raw materials as binders, and the carbonized raw materials and viscous The b...

Embodiment 3

[0038] In this example, the carbon-containing chemical waste is a mixture of coke powder and heavy-phase coal tar pitch; the coke powder is coke obtained by high-temperature dry distillation of coking coal at 980°C and then sieved undersize and coking dedusting ash The mixture, the mixing ratio is 1:1 (the two can be mixed in any ratio in the present invention), the particle size of the coke powder is less than 10mm, the mass percentage of fixed carbon in the coke powder is 77%, the mass percentage of ash is 15%, and the volatilization The mass percentage of fen is 1.1%, and the mass percentage of total sulfur is 0.6%; the heavy phase coal tar pitch is the remaining bitumen tailings with a softening point of 92°C in the process of producing needle coke, and the coking value of the heavy phase coal tar pitch is It is 59%, and the mass percentage of quinoline insoluble matter is 19%.

[0039] The chemical carbon-containing waste is composed of the following components by mass pe...

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Abstract

The invention relates to a method for preparing activated coke from chemical waste containing carbon, wherein the carbon-containing chemical waste is a mixture of coke powder and heavy phase coal tar pitch; the coke powder is coke undersize and / or coking Dust removal ash, the heavy phase coal tar pitch is the asphalt tailings with a softening point of 70°C to 95°C; the composition of the carbon-containing chemical waste is 25% to 45% of heavy phase pitch and 55% to 75% of coke powder by mass percentage; The specific preparation process includes: crushing the heavy phase coal tar pitch and coke powder separately, and then uniformly mixing according to the proportion to obtain the mixed raw material; adding a binder composed of tar and water to the mixed raw material, and then kneading and molding; carbonizing and activating the molding material Treated to get active coke. The invention not only solves the problem that a large amount of tailings and wastes in the chemical industry cannot be reused or the use value is too low, but also produces active coke products that are increasingly in demand in the environmental protection industry, reducing the desulfurization and denitrification costs of iron and steel enterprises.

Description

technical field [0001] The invention relates to the technical field of activated carbon preparation, in particular to a method for preparing activated coke from chemical carbon-containing waste. Background technique [0002] Compared with activated carbon, activated coke has reasonable pore structure, moderate specific surface area, high wear resistance and high ignition point, and can be regenerated repeatedly during practical application. At the same time, compared with activated carbon, activated coke has better adaptability to cycle desulfurization and denitrification, so activated coke is the preferred adsorbent for flue gas desulfurization and denitrification. In recent years, due to the enhancement of corporate environmental protection awareness and the improvement of national environmental protection requirements, the demand for active coke for desulfurization and denitrification has shown a doubling trend. Reached 2 million tons. [0003] At present, most activate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/30B01D53/02
CPCB01D53/02B01J20/20B01J20/30B01D2257/40B01D2257/30B01D2253/102
Inventor 薛占强穆春丰张大奎徐国忠庞克亮武吉王颢玉
Owner 鞍钢化学科技有限公司