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Anti-corrosion ultra-low carbon high-silicon iron-base alloy and preparation method thereof

An ultra-low carbon, high ferrosilicon technology, applied in the field of corrosion-resistant alloys, can solve the problems of low strength and impact toughness, poor corrosion resistance, high brittleness, etc., to avoid the precipitation of graphite, improve mechanical properties and corrosion resistance, The effect of improving corrosion resistance

Inactive Publication Date: 2019-07-23
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of poor corrosion resistance of ordinary castings, and low strength and impact toughness, high hardness, and high brittleness of high-silicon cast iron. Through effective chemical composition design, an ultra-low carbon high Ferrosilicon-based alloy, which further improves the corrosion resistance

Method used

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  • Anti-corrosion ultra-low carbon high-silicon iron-base alloy and preparation method thereof
  • Anti-corrosion ultra-low carbon high-silicon iron-base alloy and preparation method thereof
  • Anti-corrosion ultra-low carbon high-silicon iron-base alloy and preparation method thereof

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Embodiment 1

[0025] The chemical composition (percentage by weight) of a corrosion-resistant ultra-low carbon high-silicon iron-based alloy is: carbon 0.004%, silicon 16.2%, phosphorus<0.008%, sulfur<0.008%, RE 0.05%, and the balance is iron and unavoidable of impurities. Its preparation process and heat treatment process are as follows:

[0026] (1) Smelting: Two smelting methods are adopted. In the first smelting, pure iron, scrap steel, ferrosilicon and other raw materials are prepared into alloys, and these raw materials are added to an induction furnace or an electric arc furnace to melt and mix evenly, and cast into ingots. The ingot poured in the first smelting is used for the second smelting. The slagging agent sodium silicate is added during the smelting process. The smelting temperature is 1530°C. After melting, it is left to stand for a long enough time to remove the gas and inclusions in the alloy liquid.

[0027] (2) Metamorphic treatment: adopt molten iron ladle to carry out...

Embodiment 2

[0031] The chemical composition (percentage by weight) of a corrosion-resistant ultra-low-carbon high-silicon iron-based alloy is: carbon 0.005%, silicon 15.05%, phosphorus<0.008%, sulfur<0.008%, RE 0.03%, and the balance is iron and unavoidable of impurities. Its preparation process and heat treatment process are as follows:

[0032](1) Smelting: Two smelting methods are adopted. For the first smelting, pure iron, scrap steel, ferrosilicon and other raw materials are prepared into alloys, and these raw materials are added to an induction furnace or an electric arc furnace to melt and mix evenly, and cast into ingots. The ingot poured in the first smelting is used for the second smelting, and the slagging agent sodium silicate is added during the smelting process, and the smelting temperature is 1550°C. After melting, it is left to stand for a long enough time to remove the gas and inclusions in the alloy liquid.

[0033] (2) Metamorphic treatment: adopt molten iron ladle to ...

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Abstract

The invention discloses an anti-corrosion ultra-low carbon high-silicon iron-base alloy and a preparation method thereof, and belongs to the field of anti-corrosion alloys. The anti-corrosion ultra-low carbon high-silicon iron-base alloy is characterized in that the alloy chemical components comprise, by weight, smaller than or equal to 0.005% of C, 14.4-20.0% of Si, smaller than or equal to 0.008% of P, smaller than or equal to 0.008% of S, 0.01-0.05% of RE, and the balance Fe and inevitable impurities. The preparation method of the anti-corrosion ultra-low carbon high-silicon iron-base alloycomprises the following steps that pure iron, waste steel, silicon iron and other raw materials are added into an electric induction furnace or an electric arc furnace for two times of smelting, theraw materials are sufficiently mixed evenly, the smelting temperature of the alloy is 1530-1550 DEG C, the discharging temperature is 1450-1480 DEG C, rare earth silicon iron alloys are added in a ladle before discharging from the furnace, resin casting is adopted for forming, the casting temperature is 1380-1420 DEG C, annealing is performed immediately after solidification for 0.5-1 hour, the mixture is loaded into a heat treatment furnace which is preheated to 700-850 DEG C under the state of not opening a box, the furnace is cooled to 50 DEG C with the cooling speed of 5-8 DEG C per hour after heat preservation of 2-3 hours, and then the mixture is discharged from the furnace to be air-cooled. The anti-corrosion ultra-low carbon high-silicon iron-base alloy prepared by the method has the good anti-corrosion performance and can be used for manufacturing components making contact with strong corrosive media.

Description

technical field [0001] The invention relates to a corrosion-resistant ultra-low-carbon high-silicon iron-based alloy and a preparation method thereof, belonging to the field of corrosion-resistant alloys. Background technique [0002] With the development of industry, people have higher and higher requirements for materials on equipment exposed to strong corrosive environments. Generally, the electrode potential of iron and steel materials is low, and a dense oxide film cannot be formed. Adding a large amount of Cr element to stainless steel can form dense Cr 2 o 3 The passivation film significantly improves the corrosion resistance of the alloy, but in strong oxidizing acid solution Cr 2 o 3 The poor stability of the passivation film significantly reduces its corrosion resistance, so the corrosion problem under strong oxidizing acid medium has attracted people's attention, so the material of high silicon cast iron has been produced. High-silicon cast iron contains a hig...

Claims

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Application Information

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IPC IPC(8): C22C38/02C22C33/08C22C37/10C21D6/00C21D5/00B22C9/02
CPCB22C9/02C21D5/00C21D6/008C22C33/08C22C37/10C22C38/004C22C38/005C22C38/02
Inventor 赵爱民张月尹鸿祥刘伟孙绍恒裴伟郭军蒋有辉刘素鹏李迁刘逸飞赵子肖张宜顺娄殿川刘涵赜
Owner UNIV OF SCI & TECH BEIJING
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