Oil film dispersion polymerization gel particle controlling-flooding-plugging agent and synthetic technology thereof
A technology of gel particles and dispersion polymerization, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of large investment in equipment, difficulty in recycling, dust pollution, etc., to reduce the cost of production raw materials, increase the effective content, The effect of safety and stability
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Embodiment 1
[0035] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:
[0036] (1) Preparation of oil film dispersant
[0037] Add 4,000 kg of mineral oil to a 5-ton oil phase kettle, turn on the stirring heat exchange interlayer and pass in steam to raise the temperature of the mineral oil to 60-65°C, then add 123.7 kg of spar, control the temperature at 60-65°C and keep stirring for 120 minutes, then replace The thermal interlayer is fed with cooling water to reduce the temperature to less than 30°C for standby.
[0038] (2) Preparation of Sodium Acrylate
[0039] Add 259.3 kg of acrylic acid and 6.13 kg of deionized water into a 2-ton neutralization kettle, start the stirring heat exchange interlayer and feed the refrigerant to lower the temperature of the acrylic acid to less than 20°C, then slowly add 35wt% liquid caustic soda to a total of 411.3 kg, and continue to cool down under control And the ...
Embodiment 2
[0045] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:
[0046] (1) Oil film dispersant recovery liquid is reused;
[0047] (2) the preparation of sodium acrylate is with embodiment 1;
[0048] (3) Preparation of monomer mixed aqueous solution
[0049] Using N-ethylacrylamide as the functional monomer, add 961.6 kg of deionized water into a 5-ton reaction device, then start stirring and add 326.9 kg of acrylamide, 676.8 kg of sodium acrylate solution, and 34.7 kg of functional monomer in turn and prepare The monomer mixed aqueous solution is adjusted to pH 7 during stirring, and then 21 kg of methylene bisacrylamide is added, and then the temperature of the monomer mixed aqueous solution is controlled to 10° C. by refrigerant circulation. Then pass nitrogen to remove oxygen until the oxygen content is less than 0.1 mg / L, add 0.14 kg of potassium persulfate, add 0.21 kg of sodium bisulfite...
Embodiment 3
[0051] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:
[0052] (1) Oil film dispersant recovery liquid is reused;
[0053] (2) the preparation of sodium acrylate is with embodiment 1;
[0054] (3) Preparation of monomer mixed aqueous solution
[0055] Using sodium 2-methacrylamide-2-methylpropanesulfonate as the functional monomer, add 961.7 kg of deionized water to a 5-ton reaction device, then start stirring and add 326.9 kg of acrylamide and 676.8 kg of sodium acrylate solution in sequence 1. 34.7 kg of functional monomers were prepared into a monomer mixed aqueous solution. During stirring, the pH value was adjusted to 6, and 21 kg of methylene bisacrylamide was added, and then the temperature of the monomer mixed aqueous solution was controlled to 12°C by refrigerant circulation. Then pass nitrogen to remove oxygen until the oxygen content is less than 0.1 mg / L, add 0.14 kg of potas...
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