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Oil film dispersion polymerization gel particle controlling-flooding-plugging agent and synthetic technology thereof

A technology of gel particles and dispersion polymerization, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of large investment in equipment, difficulty in recycling, dust pollution, etc., to reduce the cost of production raw materials, increase the effective content, The effect of safety and stability

Inactive Publication Date: 2019-07-26
HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The production process of dry powder gel particle control and displacement plugging agent is complicated, the equipment investment is large, the process is cumbersome, the equipment investment cost and energy consumption loss of drying and crushing in the later stage is large, and the particles with small particle size are extremely difficult to recover during crushing and screening. Easy to cause dust pollution

Method used

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  • Oil film dispersion polymerization gel particle controlling-flooding-plugging agent and synthetic technology thereof
  • Oil film dispersion polymerization gel particle controlling-flooding-plugging agent and synthetic technology thereof
  • Oil film dispersion polymerization gel particle controlling-flooding-plugging agent and synthetic technology thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:

[0036] (1) Preparation of oil film dispersant

[0037] Add 4,000 kg of mineral oil to a 5-ton oil phase kettle, turn on the stirring heat exchange interlayer and pass in steam to raise the temperature of the mineral oil to 60-65°C, then add 123.7 kg of spar, control the temperature at 60-65°C and keep stirring for 120 minutes, then replace The thermal interlayer is fed with cooling water to reduce the temperature to less than 30°C for standby.

[0038] (2) Preparation of Sodium Acrylate

[0039] Add 259.3 kg of acrylic acid and 6.13 kg of deionized water into a 2-ton neutralization kettle, start the stirring heat exchange interlayer and feed the refrigerant to lower the temperature of the acrylic acid to less than 20°C, then slowly add 35wt% liquid caustic soda to a total of 411.3 kg, and continue to cool down under control And the ...

Embodiment 2

[0045] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:

[0046] (1) Oil film dispersant recovery liquid is reused;

[0047] (2) the preparation of sodium acrylate is with embodiment 1;

[0048] (3) Preparation of monomer mixed aqueous solution

[0049] Using N-ethylacrylamide as the functional monomer, add 961.6 kg of deionized water into a 5-ton reaction device, then start stirring and add 326.9 kg of acrylamide, 676.8 kg of sodium acrylate solution, and 34.7 kg of functional monomer in turn and prepare The monomer mixed aqueous solution is adjusted to pH 7 during stirring, and then 21 kg of methylene bisacrylamide is added, and then the temperature of the monomer mixed aqueous solution is controlled to 10° C. by refrigerant circulation. Then pass nitrogen to remove oxygen until the oxygen content is less than 0.1 mg / L, add 0.14 kg of potassium persulfate, add 0.21 kg of sodium bisulfite...

Embodiment 3

[0051] A process for synthesizing oil film dispersed polymeric gel particle control and displacement plugging agent, the steps are as follows:

[0052] (1) Oil film dispersant recovery liquid is reused;

[0053] (2) the preparation of sodium acrylate is with embodiment 1;

[0054] (3) Preparation of monomer mixed aqueous solution

[0055] Using sodium 2-methacrylamide-2-methylpropanesulfonate as the functional monomer, add 961.7 kg of deionized water to a 5-ton reaction device, then start stirring and add 326.9 kg of acrylamide and 676.8 kg of sodium acrylate solution in sequence 1. 34.7 kg of functional monomers were prepared into a monomer mixed aqueous solution. During stirring, the pH value was adjusted to 6, and 21 kg of methylene bisacrylamide was added, and then the temperature of the monomer mixed aqueous solution was controlled to 12°C by refrigerant circulation. Then pass nitrogen to remove oxygen until the oxygen content is less than 0.1 mg / L, add 0.14 kg of potas...

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Abstract

The invention discloses an oil film dispersion polymerization gel particle controlling-flooding-plugging agent and a synthetic technology thereof. The synthetic technology comprises the following steps: firstly adding acrylamide, sodium acrylate, a functional monomer and deionized water to a reaction device and preparing monomer mixed water solution, after adjusting a pH value, adding a cross-linking agent and an initiator, and performing polymerization; while a polymerization reaction reaches an acceleration period, enabling the monomer mixed water solution to be turned into non-Newtonian fluid in a semi-gel state, performing stretchability cutting on the non-Newtonian fluid in the semi-gel state by using stirring tension; coating cut gel particles by an oil film through using an oil filmdispersing agent, and avoiding mutual adhesion between the particles; after that, continuously performing the polymerization reaction in a low-speed stirring state, and ending the reaction while a reaction temperature is risen to 80-90 DEG C; and adding the diluent oil film dispersing agent to form a solid-liquid mixed phase, screening out finished products in different particle sizes through a solid-liquid separation sieve, and recovering the oil film dispersing agent. The synthetic technology is a new-type gel particle synthetic technology, safe and environment-friendly, and capable of greatly reducing a dosage of oil and a surfactant.

Description

technical field [0001] The invention belongs to the technical field of control and displacement agents for oil fields, and in particular relates to a control and displacement plugging agent for oil film dispersed polymer gel particles and a synthesis process thereof. Background technique [0002] With the development of the world economy and industry, the human demand for oil is also increasing. Due to the large-scale concentrated exploitation of oil in recent decades, the oilfield blocks with good reservoir geological conditions and low exploitation cost are close to depletion, and many oilfields have entered the period of high and ultra-high water cut, with low development efficiency and high exploitation cost. Reservoir conditions are poor and heterogeneity is serious. At present, because new energy cannot completely replace traditional energy, some oilfields with poor reservoir conditions, such as the Middle East reservoir, have a permeability ranging from 0.001 to 5 Da...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/56C08F220/06C08F220/54C09K8/512C09K8/88
CPCC08F220/56C09K8/512C09K8/887C08F220/06C08F220/54
Inventor 贾贝刘正正杨力生李二晓卢卫兵
Owner HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD