High-flowability polycarbonate modified material
A technology of polycarbonate and modified materials, which is applied in the field of high fluidity polycarbonate modified materials and polycarbonate modified materials, can solve the problems of affecting material transparency, poor scratch resistance, product cracking, etc. And the preparation process is environmentally friendly, scratch-resistant rigidity, high fluidity effect
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[0032] The present invention will be further described in detail below in conjunction with examples and comparative examples.
[0033] Polycarbonate No. 1, referred to as PC-1, selects 2805 from Bayer Company of Germany.
[0034] Polycarbonate No. 2 referred to as PC-2 is selected from Jiaxing Teijin L-1250Z100.
[0035] Homemade polymethylpentene copolymer, referred to as PMP. By bulk polymerization of 4-methyl-1-pentene monomer, the initiator is 2,2-dimethylpropionic acid and ferrous ion. The preparation method is as follows:
[0036] In an autoclave with stirrer under nitrogen atmosphere, 4-methyl-1-pentene monomer was added. Use ethylene to pressurize to 1.03MPa, and evacuate for 3 times to replace nitrogen. Then, quickly inject the mixed solution of 2,2-dimethylpropionic acid and ferrous ions through the inlet at the top of the kettle. Seal the autoclave, and immediately pressurize it with hydrogen to 1800-2300Pa; then use the mixed gas to pressurize it to 3200-4000Pa...
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