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Phosphorus-free corrosion and scale inhibitor composition, phosphorus-free corrosion and scale inhibitor and application thereof

A phosphorus-free corrosion inhibitor and scale inhibitor technology, applied in descaling and water softening, chemical instruments and methods, natural water treatment, etc. question

Active Publication Date: 2021-02-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The formulations of corrosion and scale inhibitors used in cooling water treatment in my country are basically based on phosphorus-based formulations. Although the performance can basically meet the requirements for use, there are still deficiencies in phosphorus-based formulations: phosphorus-based water treatment agents are used in the process of using There is a hidden danger of easy formation of phosphate scale, which affects the heat exchange effect of the water cooler during long-term operation; the phosphorus formula promotes the reproduction of microorganisms in the circulating water, and consumes a large amount of fungicides; the discharge of a large amount of phosphorus can easily lead to eutrophication of the receiving water
Both acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid copolymer substances can promote corrosion. In order to offset the increased corrosion of these substances, the amount of corrosion inhibitor in the formula must be increased, resulting in increased use costs

Method used

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  • Phosphorus-free corrosion and scale inhibitor composition, phosphorus-free corrosion and scale inhibitor and application thereof
  • Phosphorus-free corrosion and scale inhibitor composition, phosphorus-free corrosion and scale inhibitor and application thereof
  • Phosphorus-free corrosion and scale inhibitor composition, phosphorus-free corrosion and scale inhibitor and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Weigh 4.8g zinc chloride and place it in a 250mL beaker, add 39.4g deionized water, stir and dissolve, then add 30gMA-APEM (weight average molecular weight 2000), 22.5g HPMA (product number LH-10), and 3.3g Ascorbic acid, stir well.

Embodiment 2

[0066] Weigh 7.9g of zinc sulfate and place it in a 250mL beaker, add 29g of deionized water, stir and dissolve, then add 20g of MA-APEM (weight average molecular weight 10000), 37.5g of PASP (product number HL-157) and 5.6g of dehydroascorbic acid , stir well.

Embodiment 3

[0068] Take by weighing 6.3g zinc nitrate and place in a 250mL beaker, add 49.2g deionized water, after stirring and dissolving, add 10gMA-APEM (weight average molecular weight 5500), 30g PESA (product number LH-158) and 4.5g isoascorbic acid, Stir well.

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Abstract

The invention relates to the field of corrosion and scale inhibitors and discloses a phosphorus-free corrosion and scale inhibitor composition. The composition comprises a polymer A, a polymer B, organic acid and / or organic acid salt and water-soluble inorganic zinc salt; the polymer A is a copolymer of maleic anhydride and allyloxy polyoxyethylene maleic acid monoester, and the polymer B is a corrosion inhibition polymer; the weight ratio of the polymer A to the polymer B to the organic acid and / or organic acid salt to the water-soluble inorganic zinc salt is 1:(0.3-6.67):(0.025-1.25):(0.05-1.6). The invention further provides a phosphorus-free corrosion and scale inhibitor and application thereof. According to the phosphorus-free corrosion and scale inhibitor composition, the applicationamount of the corrosion and scale inhibitor is effectively lowered, and the cost is greatly reduced.

Description

technical field [0001] The invention relates to a phosphorus-free corrosion and scale inhibitor composition, a phosphorus-free corrosion and scale inhibitor and applications thereof. Background technique [0002] The formulations of corrosion and scale inhibitors used in cooling water treatment in my country are basically based on phosphorus-based formulations. Although the performance can basically meet the requirements for use, there are still deficiencies in phosphorus-based formulations: phosphorus-based water treatment agents are used in the process of using There is a hidden danger of easy formation of phosphate scale, which affects the heat exchange effect of the water cooler during long-term operation; the phosphorus formula promotes the reproduction of microorganisms in the circulating water, and consumes a large amount of fungicides; the discharge of a large amount of phosphorus can easily lead to eutrophication of the receiving water. Therefore, the development and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F5/10C02F5/12C02F103/02
CPCC02F5/105C02F5/125C02F2103/023C02F2303/08
Inventor 王金华余正齐孙飞
Owner CHINA PETROLEUM & CHEM CORP