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Method for treating residual active sludge by combined process of bipolar membrane electrodialysis for acid and alkali production, thermal hydrolysis and anaerobic digestion

A technology of bipolar membrane electrodialysis and residual activity, applied in chemical instruments and methods, water/sludge/sewage treatment, sludge treatment, etc., can solve the problem of low digestion efficiency of residual sludge, carbon removal rate needs to be improved, and limitations Sludge anaerobic digestion and other problems, to achieve the effect of easy promotion and use, increase difficulty, and enhance digestibility

Inactive Publication Date: 2019-10-29
SUN YAT SEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in this process, due to the protection and encapsulation of protoplasts by the extracellular polymers on the surface of sludge flocs and microbial cell membranes and cell walls, it is difficult for the hydrolytic enzymes secreted by microorganisms to effectively enter the cytoplasm to complete the hydrolysis process, thus limiting The effect of sludge anaerobic digestion
As a result, the digestion efficiency of the remaining sludge is low, and the carbon removal rate needs to be improved

Method used

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  • Method for treating residual active sludge by combined process of bipolar membrane electrodialysis for acid and alkali production, thermal hydrolysis and anaerobic digestion
  • Method for treating residual active sludge by combined process of bipolar membrane electrodialysis for acid and alkali production, thermal hydrolysis and anaerobic digestion
  • Method for treating residual active sludge by combined process of bipolar membrane electrodialysis for acid and alkali production, thermal hydrolysis and anaerobic digestion

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Embodiment 1

[0039] A bipolar membrane electrodialysis acid-base generation-thermal hydrolysis-anaerobic digestion combined process for treating excess activated sludge is as follows:

[0040] according to figure 2 and image 3 In the process shown, the alkali produced by the bipolar membrane is used in conjunction with thermal pretreatment. After the NaOH produced by the bipolar membrane is added to the remaining activated sludge in proportion, 0.01mol of hydrogen per gram of the remaining activated sludge is added Sodium; under the condition of 170°C, react for 70 minutes to treat the remaining activated sludge, and then mix the acid produced by the bipolar membrane with the treated remaining activated sludge evenly, adjust the pH to about 7, and then mix the acid after adjusting the pH The remaining activated sludge is put into the anaerobic digestion reactor. The remaining activated sludge is digested in the anaerobic digestion reactor, the digestion temperature is constant at about...

Embodiment 2

[0043] The difference between this embodiment and embodiment 1 is that the temperature of thermal pretreatment is 100°C;

[0044] Other steps and conditions are identical with embodiment 1.

Embodiment 3

[0046] The difference between this embodiment and embodiment 1 is that the temperature of thermal pretreatment is 140°C;

[0047] Other steps and conditions are identical with embodiment 1.

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Abstract

The invention discloses a method for treating residual active sludge by a combined process of bipolar membrane electrodialysis for acid and alkali production, thermal hydrolysis and anaerobic digestion. The method comprises the following steps: S1, with salt as a raw material, producing acid and alkali with an equal molar concentration by utilizing a bipolar membrane electrodialysis device; S2, pouring the alkali obtained in the step S1 into remaining active sludge, carrying out uniform mixing, carrying out alkali pretreatment, and jointly carrying out thermal pretreatment, wherein the temperature of thermal pretreatment is 100 to 190 DEG C, and the time of thermal pretreatment is 20 to 100 min; and S3, uniformly mixing a product obtained in the step S2 with the acid obtained in the step S1, and carrying out anaerobic digestion treatment. According to the invention, through the process of pretreatment, the release and hydrolysis process of organic matters in the process of anaerobic fermentation can be promoted, and high-efficiency pretreatment to the remaining active sludge can be realized, so the digestion efficiency of the remaining active sludge is improved, and the removal rate of carbon is increased; meanwhile, the treatment method provided by the invention has low acid and alkali production cost, simple operation, no increase of the pretreatment operation difficulty of the remaining active sludge, strong applicability and easy popularization and application.

Description

technical field [0001] The invention relates to the technical field of anaerobic treatment of sludge, and more specifically relates to a method for treating excess activated sludge through the combined process of bipolar membrane electrodialysis acid-base generation-thermal hydrolysis-anaerobic digestion. Background technique [0002] In the research of sewage treatment, the treatment and disposal of excess activated sludge is a big problem. It is predicted that the surplus sludge output in my country will reach 83.82 million tons in 2020. The remaining activated sludge contains a large amount of organic matter and rich nutrients such as nitrogen and phosphorus. It also contains factors that are likely to endanger human health such as pathogenic bacteria and parasite eggs. If it is not stabilized and discharged arbitrarily, it will cause serious environmental pollution. question. Therefore, the remaining activated sludge must be treated and disposed of to achieve the purpo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/04C02F11/00
CPCC02F11/00C02F11/04
Inventor 汪善全李浩聪余泽晖
Owner SUN YAT SEN UNIV
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