Removable contact-adhesive tape
A technology of pressure-sensitive tapes and pressure-sensitive adhesives, applied in the direction of pressure-sensitive films/sheets, adhesives, film/sheet-like adhesives, etc.
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preparation example Construction
[0265] In an alternative preparation method, all components of the adhesive are dissolved in a solvent mixture (petrol / toluene / acetone). The microspheres are foamed in gasoline and introduced into the dissolved adhesive. Once the microspheres are evenly distributed in the solution, the adhesive can be applied, for example by doctor blade on a conventional PET liner.
[0266] In a first step, the coated adhesive was exposed to 100° C. for 15 minutes to dry. After drying, the adhesive layer was covered with a second PET liner and foamed in an oven at 150° C. for 5 minutes, in particular covered between the two liners to produce a particularly smooth surface.
[0267] The surface thus produced has a roughness R of less than 15 μm, more preferably less than 10 μm a .
[0268] Surface roughness R a is an industry standard unit for the quality of a surface finish and expresses the mean height of roughness, specifically the mean absolute distance from the centerline of the roughn...
Embodiment 1 to 3
[0281]
[0282]
[0283] The composition of the adhesive:
[0284] Kraton 1102 Styrene-butadiene-styrene-block copolymer from Kraton Polymers, 83% by weight 3-block, 17% by weight 2-block; block polystyrene content: 30% by weight %
[0285] Dercolyte 115 solid α-pinene tackifying resin with a ring and ball softening temperature of 115°C and a DACP of 35°C
[0286] ●Wingtack 10 liquid hydrocarbon resin from Cray Valley Company
[0287] ●Expancel 920 DU20 microspheres
[0288] The aging inhibitors used include in particular Irganox 1010 (phenolic antioxidant).
[0289] comparative example Example 1 Example 2 Example 3 thickness [μm] 109 107 103 109 density [g / cm 3 ]
1 0.752 0.593 0.50 Microspheres [weight%] 1.5 2.5 3.5 Bond Strength, Steel [N / cm] 9 10.0 8.5 8.0 Bond strength, PE [N / cm] 7 6.9 6.7 6.2 Falling Ball, (13.8g) [cm] 50 225 >245 Falling Ball, (32.6g) [cm] -- 1...
Embodiment 4 to 7
[0296]
[0297]
[0298]
[0299]
[0300] Examples 4 to 7 show the effect of increased microsphere content in the adhesive compared to the unfoamed adhesive.
[0301] result:
[0302] ● Even at a microsphere content of 0.5% by weight, a clear improvement in impact resistance (falling balls) was measured
[0303] ●The impact resistance increases with the increase of microsphere content
[0304] ●Peel force decreased with the increase of microsphere content.
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Abstract
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