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Preparation method of coal water slurry dispersing agent

A technology of dispersant and coal-water slurry, applied in the field of preparation of coal-water slurry dispersant, can solve the problems of low degree of dispersing effect, poor adsorption effect of coal particles, etc., and achieve the effect of reducing resistance and reducing surface tension

Inactive Publication Date: 2019-12-10
刘群艳
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is to provide a preparation method of a coal water slurry dispersant in view of the defects that the current coal water slurry dispersant has a low degree of improvement in the dispersion effect of the coal water slurry and has a poor adsorption effect on coal particles

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Preparation of prefabricated reaction solution:

[0031] The wood chips and crop straws were put into the oven at a mass ratio of 5:1, and dried for 5 hours at a temperature of 70 °C. After drying, the materials were put into a planetary ball mill. Grind for 30min under the conditions to obtain mixed powder;

[0032] The above mixed powder and distilled water were put into the reactor at a mass ratio of 1:10, nitrogen was charged into the reactor, the pressure in the reactor was increased to 1.2MPa, the temperature in the reactor was increased to 140°C, and the constant temperature and pressure were maintained. The reaction was carried out for 2 hours to prepare a reaction slurry. The pressure in the kettle was reduced to standard atmospheric pressure, and the temperature was reduced to 20 °C. Ferric chloride powder with a mass of 3% of the reaction slurry was added to the reaction kettle, and mixed with a stirrer at a speed of 500 r / min. 30mnin to prepare a prefabrica...

Embodiment 2

[0040] Preparation of prefabricated reaction solution:

[0041] Put the wood chips and crop straws into the oven at a mass ratio of 5:1, and dry them for 5.5 hours at a temperature of 75 °C. After drying, the materials are put into a planetary ball mill. Grind for 35min under the conditions to obtain mixed powder;

[0042] The above-mentioned mixed powder and distilled water were put into the reactor at a mass ratio of 1:10, and nitrogen was charged into the reactor to increase the pressure in the reactor to 1.4MPa, and the temperature in the reactor was increased to 150 ℃, constant temperature and pressure. The reaction was carried out for 2.5 hours to obtain a reaction slurry. The pressure in the kettle was reduced to standard atmospheric pressure, and the temperature was reduced to 22 °C. Ferric chloride powder with a mass of 4% of the reaction slurry was added to the reaction kettle, and mixed with a stirrer at a speed of 550 r / min. Stir 35mnin to prepare a prefabricated ...

Embodiment 3

[0050] Preparation of prefabricated reaction solution:

[0051] Put the wood chips and crop stalks into the oven at a mass ratio of 5:1, and dry them for 6 hours at a temperature of 80 °C. After drying, the materials are put into a planetary ball mill. Grind for 40min under conditions to obtain mixed powder;

[0052] The above mixed powder and distilled water were put into the reactor at a mass ratio of 1:10, and nitrogen was charged into the reactor to increase the pressure in the reactor to 1.6 MPa, and the temperature in the reactor was increased to 160 ° C, constant temperature and pressure. React for 3 hours to prepare a reaction slurry, reduce the pressure in the kettle to standard atmospheric pressure, reduce the temperature to 24 °C, add ferric chloride powder with a mass of 5% of the reaction slurry into the reaction kettle, and mix and stir with a stirrer at a speed of 600r / min 40mnin to prepare a prefabricated reaction solution;

[0053] Preparation of prefabricat...

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Abstract

The invention discloses a preparation method of a coal water slurry dispersing agent, and belongs to the technical field of dispersing agent preparation. The preparation method comprises the steps: firstly, mixing wood chips with straws, drying and grinding to obtain mixed powder; then, mixing the mixed powder and distilled water, and putting the mixture into a reaction kettle; performing high-temperature and high-pressure treatment to obtain reaction slurry; adding ferric chloride into the reaction slurry; stirring and reacting to obtain a prefabricated reaction solution; then mixing the prefabricated reaction liquid with corn starch; adjusting the pH value to be acidic, adding ammonium persulfate, and heating to react to obtain an oxidation reaction solution; adjusting the pH value to bealkaline, then adding potassium styrene sulfonate, carrying out a reaction to obtain a prefabricated reagent, then adjusting the pH value of the prefabricated reagent to be neutral, then performing fermentation treatment to obtain a prefabricated product, and finally mixing and dispersing the prefabricated product, dodecyl mercaptan and other materials to obtain the coal water slurry dispersing agent.

Description

technical field [0001] The invention discloses a preparation method of a coal-water slurry dispersant, and belongs to the technical field of dispersant preparation. Background technique [0002] Coal slime is the main by-product of the coal washing process. It is a viscous substance composed of fine coal powder, minerals and water. Its main characteristics are small particle size, developed pores, high water content, high ash content and low calorific value. In 2010, my country's coal output reached 3.24 billion tons, the raw coal selection capacity was 1.75 billion tons per year, and the washing rate reached 50.9%. With the deepening of coal mining mechanization and the increase of the ratio of raw coal into washing, the production of coal slime will further increase. Due to the improvement of coal preparation technology, the generated coal slime has low calorific value, and due to the addition of medium powder in the flotation process, the civil use value of coal slime is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/32C10L1/10C10L1/12C10L1/14C10L1/18C10L1/185C10L1/222C10L1/24
CPCC10L1/10C10L1/1275C10L1/143C10L1/1817C10L1/1857C10L1/2227C10L1/2406C10L1/326
Inventor 刘群艳
Owner 刘群艳