A kind of non-oxidative ti with the function of selectively killing cancer cells 3 c 2 Quantum dots and their preparation methods and applications
A technology of quantum dots and cancer cells, which is applied to medical preparations containing active ingredients, wave energy or particle radiation treatment materials, titanium carbide, etc., can solve the problems that have not been reported in the preparation, and achieve the purpose of inhibiting and killing cancer cells. Water dispersion characteristics, the effect of simple and convenient preparation method
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Embodiment 1
[0047] Embodiment 1, raw material Ti 3 C 2 Preparation of (MXene)
[0048] First, add Ti to a teflon beaker 3 AlC 2 (MAX phase) 10 parts, and then slowly add 90 parts of hydrofluoric acid in small amounts and several times. After adding, keep stirring for 3 days at an ambient temperature of 30° C. until the complete reaction is complete. Then, centrifugation and multiple water washes were performed until the pH value was close to 7. Then vacuum-drying to obtain black Ti 3 C 2 Base powder.
[0049] Test the Ti obtained in this example 3 C 2 SEM images of substrates, such as figure 2 shown. Depend on figure 2 It can be seen that Ti 3 C 2 The substrate size is in the micrometer scale.
Embodiment 2
[0050] Embodiment 2, "micro-explosive" method prepares Ti 3 C 2 quantum dots
[0051] Put 10 parts of two-dimensional material Ti 3 C 2 Place in a Teflon beaker, pour 50 parts of liquid nitrogen into the beaker and keep at room temperature for 3 minutes. During this process, liquid nitrogen will intercalate the Ti 3 C 2 and with constant evaporation. When the remaining amount of liquid nitrogen in the beaker is very small, quickly add 50 parts of deionized water at 100°C. Since the boiling point of liquid nitrogen is -196°C, extreme temperature differences occur, resulting in 3 C 2 The liquid nitrogen in the interlayer will be rapidly vaporized, and a large amount of deionized water will form a water seal effect, making the Ti 3 C 2 The microscopic accordion-like structure formed a closed space, which in turn caused a "micro-explosion" to obtain an aqueous suspension. The entire process above only takes a few minutes. (Note: If the residual amount of liquid nitroge...
Embodiment 3
[0057] Embodiment 3, "micro-explosive" method prepares Ti 3 C 2 quantum dots
[0058] 20 copies of two-dimensional material Ti 3 C 2 Place in a Teflon beaker, pour 50 parts of liquid nitrogen into the beaker and keep at room temperature for 2 minutes. During this process, liquid nitrogen will intercalate the Ti 3 C 2 and with constant evaporation. When the remaining amount of liquid nitrogen in the beaker is small, quickly add 50 parts of deionized water at 90°C. Since the boiling point of liquid nitrogen is -196°C, extreme temperature differences occur, resulting in 3 C 2 The liquid nitrogen in the interlayer will be rapidly vaporized, and a large amount of deionized water will form a water seal effect, making the Ti 3 C 2 The microscopic accordion-like structure formed a closed space, which in turn caused a "micro-explosion" to obtain an aqueous suspension. The entire process above only takes a few minutes. (Note: If the residual amount of liquid nitrogen is 0, n...
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