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A kind of superhydrophobic wear-resistant glaze coating and preparation method thereof

A super-hydrophobic and coating technology, applied in the field of super-hydrophobic wear-resistant glaze coating and its preparation, can solve the problems of cumbersome process flow, high cost, unstable coating, etc.

Active Publication Date: 2020-12-18
HAINAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Special instruments are required, the cost is high, and the process is cumbersome
Moreover, the rough structure in the coating and the coating are mostly combined by non-bonding, and the coating is unstable and easy to fall off

Method used

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  • A kind of superhydrophobic wear-resistant glaze coating and preparation method thereof
  • A kind of superhydrophobic wear-resistant glaze coating and preparation method thereof
  • A kind of superhydrophobic wear-resistant glaze coating and preparation method thereof

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preparation example Construction

[0071] The present invention also provides a method for preparing a superhydrophobic wear-resistant glaze coating, comprising the following steps:

[0072] A) In terms of mass fraction, 30-55% SiO 2 , 15-21% Al 2 o 3 , 10-15% NaO, 5-12% MgO, 1-5% H 3 BO 3 , 2-8% TiO 2 , 1~3% BaCO 3 , 0.5-3% of ZnO and 0.5-3% of CaO are mixed and heated to obtain molten glass;

[0073] B) water-quenching and drying the glass liquid obtained in the step A) in sequence to obtain glass powder, and preparing the glass powder into a glaze, and coating it on the surface of the ceramic substrate to obtain an intermediate coating;

[0074] C) rapid cooling after heating the intermediate coating;

[0075] D) Carry out crystallization heat treatment on the product after the rapid cooling, heat preservation at the nucleation temperature Tg for 5-20 minutes, heat preservation at the first crystallization temperature Tp1 for 10-25 minutes, heat preservation at the second crystallization temperature T...

Embodiment 1

[0095] 1) Weighing: Gold tailings: 55%; Al 2 o 3 : 10%; NaO: 15%; MgO: 6%; H 3 BO 3 : 2.5%; TiO 2 : 6%; BaCO 3 : 2.5%; ZnO: 1.5%; CaO: 1.5%. Mix thoroughly and evenly, heat to 1600°C in a high-temperature furnace, and keep warm for 2 hours. Stir the glass liquid during the heat preservation process to promote the homogenization of the glass.

[0096] 2) Quenching the molten glass melted in the above 1) with water, drying, and grinding through a 200-mesh sieve to obtain glass powder. And do DSC test to get crystallization temperature results nucleation temperature 610 ℃, crystallization temperature 709 ℃, 805 ℃.

[0097] 3) Prepare the glass powder in the above 2) into a glaze, apply it on the surface of the ceramic sheet, and let it stand for 6 hours.

[0098] 4) Place the glazed ceramic sheet in the above 3) in a high-temperature furnace at 1200°C, keep it warm for 10 minutes, and rapidly cool it to below 500°C.

[0099] 5) Put the sample prepared in the above 4) into ...

Embodiment 2

[0104] 4) Weighing: gold tailings: 30%; Al 2 o 3 : 21%; NaO: 13%; MgO: 7%; H 3 BO 3 : 4%; TiO 2 : 8%; BaCO 3 : 2%; ZnO: 1.5%; CaO: 1.5%. Mix thoroughly and evenly, heat to 1600°C in a high-temperature furnace, and keep warm for 2 hours. Stir the glass liquid during the heat preservation process to promote the homogenization of the glass.

[0105] 5) Quenching the molten glass melted in the above 1) with water, drying, and pulverizing through a 200-mesh sieve to obtain glass powder. And do DSC test to get the crystallization temperature result nucleation temperature 600 ℃, crystallization temperature 700 ℃, 800 ℃.

[0106] 6) Prepare the glass powder in the above 2) into a glaze, apply it on the surface of the ceramic sheet, and let it stand for 6 hours.

[0107] 4) Place the glazed ceramic sheet in the above 3) in a high-temperature furnace at 1200°C, keep it warm for 10 minutes, and rapidly cool it to below 500°C.

[0108] 5) Put the sample prepared in the above 4) i...

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Abstract

The invention provides a superhydrophobic and wear-resistant glaze coating. The superhydrophobic and wear-resistant glaze coating is prepared from, by mass, 30-55% of SiO2, 15-21% of Al2O3, 10-15% ofNaO, 5-12% of MgO, 1-5% of H3BO3, 2-8% of TiO2, 1-3% of BaCO3, 0.5-3% of ZnO and 0.5-3% of CaO. Micro-nano microcrystalline glass is used as a glaze, and certain crystals grow in the glaze, so that the wear resistance is good; and the micro-nano microcrystalline glass is not prone to falling off due to the self roughness. The invention also provides a preparation method of the superhydrophobic andwear-resistant glaze coating. Micron-scale blocky crystals and nano-scale vermicular spherical crystals are separated out of the surface after crystallization in order to form a layered structure, sothat the surface has two different levels of roughness. The prepared super-hydrophobic rough surface is derived from the coating, is resistant to wear and is not prone to falling off.

Description

technical field [0001] The invention belongs to the technical field of superhydrophobic coating preparation, in particular to a superhydrophobic wear-resistant glaze coating and a preparation method thereof. Background technique [0002] Glaze is a thin, glassy coating applied to the surface of ceramic components for aesthetic protection. It widely exists in daily life, such as household kitchen and bathroom tiles, bathroom equipment, electric porcelain devices, etc. [0003] Superhydrophobic is a special wettability of solid surface. It is usually defined that the contact angle between the surface and water is greater than 150°, and the rolling angle is less than 10°. It is a superhydrophobic surface with self-cleaning characteristics. Water droplets move in the form of rolling on this surface, which can take away the dirt and dust attached to the surface. [0004] The Chinese patent with the publication number CN106987835A discloses a superhydrophobic wear-resistant coat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C8/00C03C10/00C04B41/86C03B32/02
CPCC03B32/02C03C8/00C03C10/0063C04B41/5022C04B41/86
Inventor 李长久
Owner HAINAN UNIV