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Steam reforming catalyst structure, reforming device provided with said steam reforming catalyst structure, and production method of steam reforming catalyst structure

A technology of steam reforming and manufacturing methods, which is applied in the direction of catalyst activation/preparation, molecular sieve catalysts, chemical instruments and methods, etc., which can solve the problems of catalyst condensation, high cost, insufficient activity and heat resistance, etc., and achieve the maintenance of catalytic active effect

Active Publication Date: 2020-02-07
FURUKAWA ELECTRIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, in the reformer as described above, there is a problem that, due to the combustion reaction caused by the partial oxidation reaction, even in the presence of a trace amount of oxygen, the aggregation of the catalyst is caused due to the high temperature history, and in a short time loss of catalytic performance
Among them, the noble metals Rh and Ru have the highest activity, but there is a problem of high cost
In addition, Ni is relatively cheap and is often used industrially, but there is a problem of insufficient activity and heat resistance when only Ni fine particles are used as a catalyst in the existing form.

Method used

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  • Steam reforming catalyst structure, reforming device provided with said steam reforming catalyst structure, and production method of steam reforming catalyst structure
  • Steam reforming catalyst structure, reforming device provided with said steam reforming catalyst structure, and production method of steam reforming catalyst structure
  • Steam reforming catalyst structure, reforming device provided with said steam reforming catalyst structure, and production method of steam reforming catalyst structure

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Effect test

Embodiment 1~384

[0122] [Synthesis of precursor material (A)]

[0123] A mixed aqueous solution obtained by mixing a silica agent (tetraethoxysilane (TEOS), manufactured by Wako Pure Chemical Industries, Ltd.) and a surfactant as a templating agent was prepared, and the pH was adjusted appropriately. The hydrothermal treatment was performed at 80°C to 350°C for 100 hours. Thereafter, the generated precipitate was filtered, washed with water and ethanol, and fired at 600° C. in air for 24 hours to obtain precursor materials (A) of the types and pore sizes shown in Tables 1-8. In addition, as a surfactant, the following ones are used depending on the type of precursor material (A) (“type of precursor material (A): surfactant”).

[0124] ・MCM-41: cetyltrimethylammonium bromide (CTAB) (manufactured by Wako Pure Chemical Industries, Ltd.)

[0125] · SBA-1: Pluronic P123 (manufactured by BASF Corporation)

[0126] [Production of precursor materials (B) and (C)]

[0127] Next, depending on the me...

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Abstract

A steam reforming catalyst structure which favorably maintains catalyst activity by suppressing aggregation of catalyst particles and which can efficiently generate a reformed gas containing hydrogenfrom a reformed raw material containing hydrocarbons, and a reforming device using said steam reforming catalyst structure, are provided. This steam reforming catalyst structure (1), used to produce areformed gas containing hydrogen from a reformed raw material containing hydrocarbons, comprises a carrier (10) with a porous structure configured from a zeolite compound, and a least one catalytic material (20) present in the carrier (10), wherein the carrier (10) has passages that communicate with each other, and the catalytic material (20) is metal microparticles and is present in at least thepassages (11) in the carrier (10).

Description

technical field [0001] The present invention relates to a catalyst structure for steam reforming, a reformer including the catalyst structure for steam reforming, and a method for producing the catalyst structure for steam reforming. Background technique [0002] Hydrogen is expected as a raw material for new energy, and it is used in stationary fuel cell systems, which are expected to be produced by hydrogen production equipment at hydrogen refueling stations and popularized in homes, small and medium-sized offices, etc., and are being produced at research sites. [0003] For example, steam reforming of natural gas, also known as steam methane reforming (SMR), is the most important method for producing commercially oriented large quantities of hydrogen in addition to hydrogen for industrial ammonia synthesis. In addition, this method is also the cheapest method. In the presence of metal catalysts at high temperatures (700-1100°C), water vapor reacts with methane to produce...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/035B01J29/12B01J29/14B01J29/44B01J29/46B01J29/67B01J29/68B01J29/74B01J29/76C01B3/40
CPCB01J29/44B01J29/46B01J29/67B01J29/68C01B3/40B01J29/0333B01J2229/186B01J29/0325B01J29/0316B01J2229/40B01J29/7469B01J29/7669B01J29/146B01J29/126B01J37/18B01J29/0354B01J29/0356C01B37/02Y02P20/52B01J35/393B01J35/30B01J35/23B01J29/12B01J29/14B01J37/0211B01J37/105C01B2203/0233C01B2203/1011C01B2203/1058C01B2203/1064C01B2203/1235B01J35/394
Inventor 增田隆夫中坂佑太吉川琢也加藤祯宏福岛将行高桥寻子马场祐一郎关根可织
Owner FURUKAWA ELECTRIC CO LTD