Water-based coating adopting high-performance water-based acrylic acid modified polyurethane, and preparation method and preparation device thereof
A water-based acrylic and water-based paint technology, applied in polyurea/polyurethane coatings, fire-retardant coatings, chemical instruments and methods, etc., can solve the problem that water-based coatings do not have intumescent flame retardancy, can not better ensure the quality of coatings, and the weight of raw materials. To solve problems such as missing points, it can achieve the effect of good fire resistance, good expansion and flame retardancy, and easy operation.
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[0044] (1) Preparation of polyurethane prepolymer: Add macromolecular polyols and small molecular hydrophilic compounds into a four-neck flask, stir evenly, heat up to 90-100°C for vacuum dehydration, cool down to 60°C after dehydration, and then add diisocyanate , and the catalyst was added dropwise, and the temperature was raised to 75°C to keep warm for reaction;
[0045] (2) Preparation of acrylic acid monomer mixture: mix acrylic acid monomer and oil-soluble initiator and stir evenly;
[0046] (3) Preparation of polyvinyl alcohol aqueous solution: add polyvinyl alcohol into deionized water, heat up to 80-90°C and stir until completely dissolved;
[0047] (4) Preparation of polyvinyl alcohol-modified water-based polyurethane-acrylate emulsion: add the prepared acrylic monomer mixture to the polyurethane prepolymer, stir evenly, then add polyvinyl alcohol aqueous solution, and stir quickly to make the prepolymer uniform Disperse, add a neutralizing agent, heat up to 70°C a...
Embodiment 1
[0051] The water-based paint using high-performance water-based acrylic-modified polyurethane provided in this example is made of the following components in parts by weight: 10 parts of water-based acrylic-modified polyurethane resin emulsion, 5 parts of self-crosslinking curing agent, defoaming 4 parts of agent, 1 part of thickener, 0.2 parts of leveling agent, 6 parts of filler, 15 parts of deionized water and 5 parts of expansion agent.
[0052] Wherein, the water-based acrylic modified polyurethane resin emulsion is prepared by the following components and steps: 20 parts of diisocyanate, 100 parts of macromolecular polyol, 2 parts of small molecule hydrophilic compound, 1 part of catalyst, acrylic monomer 100 parts, 1 part of oil-soluble initiator, 60 parts of polyvinyl alcohol, 100 parts of deionized water, 1 part of neutralizer;
[0053] Its preparation method is:
[0054] (1) Preparation of polyurethane prepolymer: Add macromolecular polyols and small molecular hydro...
Embodiment 2
[0072] The water-based paint, preparation method and equipment provided by this embodiment using high-performance water-based acrylic modified polyurethane are basically the same as in Example 1, except that:
[0073] A water-based paint using high-performance water-based acrylic-modified polyurethane provided in this embodiment is made of the following components in parts by weight: 50 parts of water-based acrylic-modified polyurethane resin emulsion, 14 parts of self-crosslinking curing agent, 7 parts of defoamer, 7 parts of thickener, 6 parts of leveling agent, 19 parts of filler, 25 parts of deionized water and 7 parts of expansion agent.
[0074] Wherein, the water-based acrylic modified polyurethane resin emulsion is prepared by the following components and steps: 30 parts of diisocyanate, 300 parts of macromolecular polyol, 5 parts of small molecule hydrophilic compound, 3 parts of catalyst, acrylic monomer 300 parts, 3 parts of oil-soluble initiator, 120 parts of polyv...
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