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Preparation method for alumina ceramic

A technology of alumina ceramics and alumina, which is applied in the field of preparation of alumina ceramics, can solve the problems of alumina ceramics to be improved in density, high equipment cost, poor bending strength, etc., and achieve high bonding strength, high specific surface area, Effect of improving toughness and bending strength

Pending Publication Date: 2020-04-10
佛山市博特美陶瓷有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The technical problem mainly solved by the present invention is that the existing alumina ceramics have poor flexural strength and are easy to break under force. At present, low-temperature sintering technology is generally used to suppress the growth of alumina ceramic grains, but the cost of equipment is relatively high. The defect that the density of the prepared alumina ceramics needs to be improved provides a preparation method of alumina ceramics

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Preparation of sintering aids:

[0037] Take 400g of rice husk and ignite to get rice husk ash, put the rice husk ash into the glass tank, add 500mL of 30% sodium hydroxide solution into the glass tank to soak the rice husk ash, after soaking for 10min, then put it into the glass tank Add 600mL of sulfuric acid solution with a mass fraction of 20%, heat up to 90°C, start the stirrer to stir at a speed of 70r / min, keep the reaction for 20min, filter and remove the filter residue to obtain a gel;

[0038] Wash the above-mentioned gel with deionized water for 3 times, then put the washed gel into an oven, heat up to 100°C, and dry for 45 minutes to obtain a dry gel, then place the dry gel in a nanometer high-pressure pulse pulverizer, After pulverizing for 10 minutes, nano-gel powder is obtained, and the nano-gel powder and chromium oxide are mixed at a mass ratio of 3:1 to obtain a sintering aid, which is set aside;

[0039] Preparation of alumina seed liquid:

[0040] ...

Embodiment 2

[0047] Preparation of sintering aids:

[0048] Take 450g of rice husk and ignite to get rice husk ash, put the rice husk ash into the glass tank, add 550mL sodium hydroxide solution with a mass fraction of 30% to the glass tank to soak the rice husk ash, soak for 12min, then pour it into the glass tank Add 700mL of sulfuric acid solution with a mass fraction of 20%, heat up to 95°C, start the stirrer to stir at a speed of 75r / min, keep warm for 25min, filter and remove the filter residue to obtain a gel;

[0049] Wash the above-mentioned gel 4 times with deionized water, then put the washed gel into an oven, heat up to 105°C, and dry for 50 minutes to obtain a dry gel, then place the dry gel in a nano high-pressure pulse mill, After pulverizing for 12 minutes, nano gel powder is obtained, and the nano gel powder and chromium oxide are mixed at a mass ratio of 3:1 to obtain a sintering aid, which is set aside;

[0050] Preparation of alumina seed liquid:

[0051] Put 750mL of...

Embodiment 3

[0058] Preparation of sintering aids:

[0059] Take 500g of rice husk and ignite to get rice husk ash, put the rice husk ash into the glass tank, add 600mL of sodium hydroxide solution with a mass fraction of 30% to the glass tank to soak the rice husk ash, after soaking for 15min, then pour it into the glass tank Add 800mL of sulfuric acid solution with a mass fraction of 20%, heat up to 100°C, start the stirrer to stir at a speed of 80r / min, keep the reaction for 30min, filter and remove the filter residue to obtain a gel;

[0060] Wash the above gel 5 times with deionized water, then put the washed gel into an oven, heat up to 110°C, and dry for 55 minutes to obtain a dry gel, which is placed in a nano high-pressure pulse mill, After pulverizing for 15 minutes, nano gel powder is obtained, and the nano gel powder and chromium oxide are mixed at a mass ratio of 3:1 to obtain a sintering aid, which is set aside;

[0061] Preparation of alumina seed liquid:

[0062] Put 800m...

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Abstract

The invention discloses a preparation method for aluminum oxide ceramic, belonging to the technical field of ceramic preparation. According to the invention, when carbon dioxide is used for carbonation decomposition to prepare aluminum hydroxide, the causticity ratio of a solution is reduced; aluminum hydroxide seed crystal decomposition is inhibited; the particle size of aluminum hydroxide formedaround is reduced; aluminum oxide particles in ceramic are changed into nanometer aluminum oxide with high density; ceramic particles in a formed ceramic blank have high bonding strength; the toughness and bending strength of the aluminum oxide ceramic are improved; nitrogen in ammonia gas is fixed into fermentation filter residues through the micro-corrosion effect of microorganisms in fruit peels; toughened modified powder is subjected to hot pressed sintering to form a hexagonal boron nitride crystal; the wear resistance of the aluminum oxide ceramic is improved; the toughness and the bending strength of the aluminum oxide ceramic are improved; meanwhile, diamond is an atomic crystal; atoms are bonded through sp3 hybrid orbits; the interface energy of the diamond is high; the interfacebonding capacity of diamond particles and the ceramic is reinforced; the density of the aluminum oxide ceramic is increased while curing shrinkage is achieved; and the bending strength is improved.

Description

technical field [0001] The invention discloses a method for preparing alumina ceramics, which belongs to the technical field of ceramic preparation. Background technique [0002] Alumina ceramics are a kind of aluminum oxide (Al 2 o 3 ) as the main body of ceramic materials for thick film integrated circuits. Alumina ceramics have good conductivity, mechanical strength and high temperature resistance. It should be noted that ultrasonic cleaning is required. Alumina ceramics are a kind of ceramics with a wide range of uses. Because of its superior performance, it has been more and more widely used in modern society, meeting the needs of daily use and special performance. The technology of alumina ceramics is becoming more and more mature, but some indicators still need to be improved, which requires everyone's joint research. [0003] The molding methods of alumina ceramic products include dry pressing, grouting, extrusion, cold isostatic pressing, injection, casting, ho...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/10C04B35/64C04B35/634
CPCC04B35/10C04B35/63452C04B35/64C04B2235/3222C04B2235/3241C04B2235/3409C04B2235/3427C04B2235/427C04B2235/483C04B2235/77C04B2235/96
Inventor 赵金城
Owner 佛山市博特美陶瓷有限公司