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Tungsten-copper alloy and preparation method thereof

A tungsten-copper alloy and tungsten-copper technology, applied in the field of tungsten-copper alloy and its preparation, can solve the problems of inability to meet the new tungsten-copper alloy, reduced efficiency, increased cost, etc., and achieves improved mechanical properties, extended service life, and excellent electrical conductivity. and thermal conductivity

Inactive Publication Date: 2020-04-21
TAIZHOU HUACHENG TUNGSTEN & MOLYBDENUM MFR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although repressing and refiring or subsequent thermal processing can increase the product density, the cost increases, the efficiency decreases, and the tungsten grains are further coarsened during sintering, which cannot meet the requirements of the new tungsten-copper alloy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A preparation method of tungsten copper alloy, comprising the following steps:

[0023] (1) Preparation of tungsten-copper composite oxide powder, taking by weighing 28.2% ammonium tungstate solution 320g, placing it in an electronic stirrer, dissolving copper nitrate (Cu(NO3) 2) with deionized water to form a solution, Under stirring conditions (speed: 1000rpm, stirring time: 60min), the mixture of Cu(NO3)2 solution and concentrated nitric acid (concentration 68%) (55g Cu(NO3)2 5H2O, 75g concentrated nitric acid) was added to ammonium tungstate The solution undergoes a chemical precipitation reaction, continuously stirred for 30-90 minutes, and then the precipitate is taken out, calcined at 150°C for 3 hours, ground and pulverized to obtain a tungsten-copper oxide composite powder.

[0024] (2) Reduction of tungsten-copper oxide composite powder, put the tungsten-copper oxide composite powder in a ventilated strong drainage tube furnace for hydrogen reduction to obtain...

Embodiment 2

[0028] (1) Take 320 g of ammonium tungstate solution with a concentration of 28.2%, place it in an electronic stirrer, mix Cu(NO3)2 solution and concentrated nitric acid (68% concentration) (55g Cu(NO3)2·5H2O, Add 75g of concentrated nitric acid into the ammonium tungstate solution under stirring conditions (rotating speed 1500rpm, stirring time 90min) for chemical precipitation reaction, then put the precipitate in a drying oven at 200°C for 2.3h, and then grind and crush it.

[0029] (2) The tungsten-copper oxide composite powder obtained in the above steps is reduced in the air-permeable strong drainage pipe furnace H2 atmosphere, the reduction temperature is 700°C, the reduction time is 1.3h, and the hydrogen flow rate is 40ml / min to obtain the nano-tungsten-copper mixed powder (average Grain ≤ 50nm).

[0030] (3) Put the mixed powder obtained in the above steps into a steel mold, and press it under a pressure of 180 MPa to make a green compact.

[0031] (4) Place the com...

Embodiment 3

[0033] (1) Weigh 320g of ammonium tungstate solution with a concentration of 28.2%, place it in an electronic stirrer, and mix Cu(NO3)2 solution and concentrated nitric acid (concentration 68%) mixture (55g Cu(NO3)2·5H2O, 75g concentrated nitric acid) was added to the above ammonium tungstate solution for chemical precipitation reaction, and then the precipitate was dried in a 300°C drying oven for 1.8h, and then ground and broken.

[0034] (2) The tungsten-copper oxide composite powder obtained in the above steps is reduced in the gas-permeable strong drainage pipe furnace H2 atmosphere, the reduction temperature is 750°C, the reduction time is 1h, and the hydrogen flow rate is 35ml / min to obtain nano-tungsten-copper mixed powder (average crystal Particles ≤ 50nm).

[0035] (3) Put the mixed powder into a steel mold and press under a pressure of 230MPa to make a green compact.

[0036] (4) Place the compact in a hydrogen furnace for sintering, the heating rate is 10°C / min, t...

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Abstract

The invention discloses a tungsten-copper alloy and a preparation method thereof. The preparation method comprises the steps of (1) preparing tungsten-copper composite oxide powder; (2) reducing the tungsten copper oxide composite powder; (3) pressing and forming; and (4) sintering the ultra-fine grain tungsten-copper alloy to obtain the ultra-fine grain tungsten-copper alloy. The content of copper in the tungsten-copper alloy is 20wt%, the relative density of the alloy is 98.0%-99.7%, the average size of tungsten grains in the alloy is 0.5-1.5[mu]m, the resistivity of the alloy is 0.035-0.041*10<-6>([omega].m), and the heat conductivity coefficient of the alloy is 200-223W / (m.K). The tungsten grains of the tungsten-copper alloy are fine and uniform, a continuous framework is formed, and the alloy is highly compact; and the copper phase is highly dispersed to form a compact network. Each particle in the ultra-fine dispersion tungsten-copper composite powder is composed of a copper phase and a tungsten phase, and the sintered alloy is approximately fully dense and has high thermal conductivity and electrical conductivity.

Description

technical field [0001] The invention relates to the technical field of powder metallurgy, in particular to a tungsten-copper alloy and a preparation method thereof. Background technique [0002] At present, the combination of two metals, tungsten (W) and copper (Cu), is generally obtained by impregnating porous tungsten blanks prepared by powder metallurgy, or liquid phase sintering after pressing blanks with mixed powder. For composite materials with high tungsten content, the latter method often leads to final porosity due to the insolubility of tungsten in liquid copper, and the highest relative density is only 92% to 95%, which leads to the conductivity of the composite material. , Low thermal conductivity, high air leakage rate. In order to increase the sintered density of tungsten-copper alloy, the method of adding sintering aid is usually used for activation sintering, but the addition of activator will greatly damage the thermal conductivity. [0003] The existing ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C27/04C22C1/04B22F9/22
CPCB22F9/22B22F2998/10C22C1/045C22C27/04B22F3/04B22F3/1007
Inventor 徐文进
Owner TAIZHOU HUACHENG TUNGSTEN & MOLYBDENUM MFR