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Preparation method of high-solid-content PAE resin paper wet strength agent

A technology of high solid content and wet strength agent, applied in paper, reinforcing agent addition, papermaking, etc., can solve the problems of high transportation cost of PAE resin, low solid content of PAE resin, reduce transportation cost, etc., and achieve excellent storage stability, Excellent wet reinforcement effect and reduced transportation cost

Inactive Publication Date: 2020-06-05
苏州派凯姆新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of this, in order to overcome the low solid content of PAE resin described in the prior art, the problem of high transportation cost of PAE resin, compared with the traditional low solid content of 12.5% ​​PAE resin paper wet strength agent, the new type of The solid content of the PAE resin paper wet strength agent is as high as 25%. The wet strength agent prepared according to the method of the invention has good fluidity and excellent storage stability, and has an excellent wet strengthening effect on paper. The invention discloses a The preparation method of high-solid content PAE resin paper wet strength agent breaks through a series of technical difficulties such as high-solid content PAE resin is very easy to produce gel during the preparation process, and the final wet strength agent product has high viscosity, poor fluidity, and short storage time. , successfully developed a new type of paper wet strength agent, reducing transportation costs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment example 1

[0019] Add 81 g of diethylenetriamine and 0.5 g of 98% sulfuric acid to a 1 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen inlet tube, feed nitrogen, slowly add 111 g of adipic acid, and control the temperature at Below 130°C, if the temperature exceeds 130°C, cooling and cooling treatment is required; after adding adipic acid, start to heat up, when the temperature reaches 170°C, keep warm for 4 hours, after the warming reaction is over, start cooling, when the temperature drops to 80°C, add 130g of deionized water, continue to cool down to 30°C, when the temperature is stable, add 90.3g of epichlorohydrin dropwise to the reaction kettle, the dropping time is controlled at 40 minutes, and the dropwise addition of mixed monomers is controlled Temperature to 40°C and keep warm for 6 hours, start cooling, when the temperature drops to 25°C, add 16g of 98% sulfuric acid and 350g of deionized water to the reaction kettle, adjust the ...

specific Embodiment example 2

[0021] Add 101 g of diethylenetriamine and 0.8 g of 98% sulfuric acid to a 1 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen inlet tube, feed nitrogen, slowly add 111 g of adipic acid, and control the temperature at Below 130°C, if the temperature exceeds 130°C, cooling and cooling treatment is required; after adding adipic acid, start to heat up, when the temperature reaches 170°C, keep warm for 4 hours, after the warming reaction is over, start cooling, when the temperature drops to 80°C, add 147g of deionized water, continue to cool down to 30°C, when the temperature is stable, add 70g of epichlorohydrin dropwise to the reaction kettle, the dropping time is controlled at 40 minutes, and the temperature is controlled after the addition of the mixed monomer is completed To 40 ℃ and keep warm for 6 hours, the reaction is over, start cooling, when the temperature drops to 25 ℃, add 21g of 98% sulfuric acid and 360g of deionized wat...

specific Embodiment example 3

[0023] Add 81 g of diethylenetriamine and 0.5 g of 98% sulfuric acid to a 1 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen inlet tube, feed nitrogen, slowly add 111 g of adipic acid, and control the temperature at Below 130°C, if the temperature exceeds 130°C, cooling and cooling treatment is required; after the addition of adipic acid, start to heat up, when the temperature reaches 170°C, keep warm for 4 hours, after the keep warm, start cooling, when the temperature drops to 80°C, add 130g of deionized water, continue to cool down to 30°C, when the temperature is stable, add 70g of epichlorohydrin dropwise to the reaction kettle, the dropping time is controlled at 40 minutes, and the temperature is controlled after the addition of the mixed monomer is completed To 40 ℃ and keep warm for 6 hours, the reaction is over, start cooling, when the temperature drops to 25 ℃, add 21g of 98% sulfuric acid and 300g of deionized water to t...

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PUM

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Abstract

The invention aims to manufacture a high-solid-content PAE resin paper wet strength agent. Compared with a traditional PAE resin wet strength agent with the low solid content of 12.5%, the PAE resin wet strength agent has the advantages that the solid content is low, wherein the solid content of the prepared novel PAE wet strength agent can reach up to 25%. The wet strength agent prepared according to the method achieves good flowability and excellent storage stability, wherein the wet strengthening effect on the paper is excellent. The invention discloses a preparation method of a high-solid-content PAE resin paper wet strength agent. A series of technical difficulties that gel is extremely easy to produce in the process of preparing the high-solid-content PAE resin paper wet strength agent, and a final product is high in viscosity, poor in flowability, short in storage time and the like are broken through, the novel paper PAE resin paper wet strength agent is successfully developed,and the transportation cost is reduced.

Description

technical field [0001] The invention relates to the field of papermaking chemicals, and more specifically, relates to a preparation method of a high-solid-content PAE resin paper wet strength agent. Background technique [0002] The wet strength of paper refers to the strength of the paper when it meets water or in a humid environment. Many paper products require high wet strength. The addition of wet strength agents can improve the wet strength of paper under wet conditions. [0003] At present, in the field of papermaking, the common chemicals that can improve the wet strength of paper are roughly as follows, the first category: urea-formaldehyde resin (UF); the second category: melamine-formaldehyde resin (MF); the third category: Polyamide polyamine epichlorohydrin resin (PAE); the fourth category: polyethyleneimine resin (PEI), among these types of wet strength agents, UF resin contains free formaldehyde, which will emit into the air Among them, being absorbed by the h...

Claims

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Application Information

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IPC IPC(8): C08G69/48C08G69/26D21H17/55D21H21/20
CPCC08G69/48C08G69/26D21H17/55D21H21/20
Inventor 张新东轩少云孙婷
Owner 苏州派凯姆新能源科技有限公司
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