Laminate for manufacturing flexible display, and flexible display manufacturing method using same
A flexible display and laminate technology, applied in chemical instruments and methods, lamination, application, etc., can solve the problems of complicated process, complicated manufacturing process, increased manufacturing cost, etc., and achieve the effect of promoting separation and minimizing problems
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preparation example 1
[0128] Polymerization of polyimide BPDA-pPDA (98.9:100)
[0129] After 100 g of NMP (N-methyl-2-pyrrolidone) was charged into the reactor with nitrogen flow, 6.243 g (57.726 mmol) of p-phenylenediamine (p -PDA) dissolves. At the same temperature, 16.797 g (57.091 mmol) of 3,3',4,4'-biphenyltetracarboxylic dianhydride (s-BPDA) and 56.96 g of NMP were added to the solution of p-PDA, and stirred for a predetermined time. time to polymerize the polyamic acid, thereby preparing a polyimide precursor.
[0130] An organic solvent was added in such an amount that the solid concentration of the polyimide precursor prepared by the reaction was 12.8% by weight to prepare a polyimide precursor solution.
preparation example 2
[0131] Polymerization of polyimide BPDA-PMDA-pPDA (88.9:10:100)
[0132] After 100 g of NMP (N-methyl-2-pyrrolidone) was charged into the reactor with nitrogen flow, 6.364 g (58.849 mmol) of p-phenylenediamine (p -PDA) dissolves. At the same temperature, 15.393g (52.316mmol) 3,3',4,4'-biphenyltetracarboxylic dianhydride (s-BPDA), 1.289g (5.885mmol) pyromellitic dianhydride (PMDA) and 56.96 g of NMP were added to the solution of p-PDA, and stirred for a predetermined time to polymerize polyamic acid, thereby preparing a polyimide precursor.
[0133] An organic solvent was added in such an amount that the solid concentration of the polyimide precursor prepared by the reaction was 12.8% by weight to prepare a polyimide precursor solution.
preparation example 3
[0134] Polymerization of polyimide BPDA-pPDA-TFMB (98.9:90:10)
[0135] After 100 g of NMP (N-methyl-2-pyrrolidone) was charged into the reactor with nitrogen flow, 5.335 g (49.332 mmol) of p-phenylenediamine (p -PDA) and 1.775 g (5.481 mmol) of bistrifluoromethylbenzidine (TFMB) were dissolved. At the same temperature, 15.950 g (54.221 mmol) of 3,3',4,4'-biphenyltetracarboxylic dianhydride (s-BPDA) and 56.96 g of NMP were added to the solution of p-PDA and TFMB, and The polyamic acid is polymerized by stirring for a predetermined time, thereby preparing a polyimide precursor.
[0136] An organic solvent was added in such an amount that the solid concentration of the polyimide precursor prepared by the reaction was 12.8% by weight to prepare a polyimide precursor solution.
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