Preparation method of self-adaptive optical gel based on boric acid ester reversible covalent bonds

An optical gel and self-adaptive technology, which is applied in the field of preparation of optical functional materials, can solve the problems of optical material color angle dependence, complex process, etc., to improve processability and service life, good molding effect, and good optical effect Effect

Pending Publication Date: 2020-08-18
剑桥大学南京科技创新中心有限公司
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AI-Extracted Technical Summary

Problems solved by technology

[0008] However, the disadvantage of the method in Document 2 is that the process is complicated, and it is necessary to form a template with structur...
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Abstract

The invention relates to a preparation method of optical gel with self-adaptive characteristics, and the optical gel is obtained by adding a comonomer, a small molecular functional monomer containingphenylboronic acid functional groups, complementary macromolecules and an initiator into a dispersion liquid of monodisperse microspheres under a specific pH condition, and then carrying out ultraviolet light or thermal polymerization, wherein the pH value is between 6 and 10. The monodisperse microspheres comprise inorganic microspheres, silicon dioxide microspheres, ferroferric oxide microspheres, titanium dioxide microspheres and the like; organic microspheres, polystyrene (PS) microspheres, polymethyl methacrylate (PMMA) microspheres and the like; the hybrid microspheres comprise core-shell structure microspheres and the like; and the particle size of the monodisperse microspheres ranges from 80nm to 3mu m. The particle size of the monodisperse microspheres determines the color presented by the optical gel, and the smaller the particle size is, the color moves towards the blue direction, otherwise, the color moves towards the red direction.

Technology Topic

Functional monomerBoronic acid +18

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  • Preparation method of self-adaptive optical gel based on boric acid ester reversible covalent bonds
  • Preparation method of self-adaptive optical gel based on boric acid ester reversible covalent bonds
  • Preparation method of self-adaptive optical gel based on boric acid ester reversible covalent bonds

Examples

  • Experimental program(12)

Example Embodiment

[0023] Example 1
[0024] Monodisperse silica microspheres with particle diameters of 100nm, 130nm and 200nm were used as the photonic crystal building unit, and dispersed in 1mL of dimethylacetamide (DMAc) solvent. The mass fraction of the microspheres in DMAc was controlled at 50%; continue to add 0.15g dimethylacrylamide (DMAm), 0.05g acrylamidophenylboronic acid (3-APBA), 50μL 5% polyvinyl alcohol (PVA) aqueous solution and 0.05g 2959 photoinitiator to the above mixture After mixing uniformly, use 1M NaOH aqueous solution to adjust the pH of the mixed solution to 7-8; carry out UV curing at room temperature for 30 minutes to obtain optical gels with blue, yellow and red colors ( figure 2 ).

Example Embodiment

[0025] Example 2
[0026] Use monodisperse silica microspheres with a particle size of 100nm as photonic crystal building units, and disperse them in 1mL of dimethylacetamide (DMAc) solvent. The mass fraction of the microspheres in DMAc is controlled at 35%; continue to Add 0.1g dimethylacrylamide (DMAm) and 0.05g isopropylacrylamide, 0.05g acrylamidophenylboronic acid (3-APBA), 50μL 5% polyvinyl alcohol (PVA) aqueous solution and 0.05g 2959 photoinitiator; after mixing uniformly, use 1M NaOH aqueous solution to adjust the pH of the mixture to 7-8; UV curing at room temperature for 30 minutes, the optical gel with structural color can be obtained.

Example Embodiment

[0027] Example 3
[0028] Use 400nm monodisperse silica microspheres as photonic crystal building units, and disperse them in 1mL dimethylacetamide (DMAc) solvent. The mass fraction of microspheres in DMAc is controlled at 65%; continue to Add 0.25g of dimethylacrylamide (DMAm), 0.05g of acrylamidophenylboronic acid (3-APBA), 0.05g of dextran and 0.05g of AIBN thermal initiator to the above mixture; after mixing uniformly, use 1M NaOH aqueous solution to adjust The pH of the mixed solution is 8-9; after curing at 80°C for 1 hour, an optical gel with structural color can be obtained.

PUM

PropertyMeasurementUnit
Particle size100.0 ~ 200.0nm
Particle size400.0nm
Particle size700.0nm

Description & Claims & Application Information

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