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Preparation method of porous composite carbonaceous reducing agent

A reducing agent and composite carbon technology, which is applied in the preparation/purification of carbon, chemical instruments and methods, silicon compounds, etc., can solve the problems of incompatibility between reactivity and pellet strength, so as to alleviate environmental ecological pressure and avoid resources Effect of waste and reduction of energy consumption

Pending Publication Date: 2020-09-04
KUNMING UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The present invention aims at the problem that the reactivity of the composite carbonaceous reductant and the strength of the pellets cannot be achieved at the same time, and provides a preparation method of the porous composite carbonaceous reductant. The present invention uses petroleum coke and coal as the main carbon source, and the sawdust To make pores, adopt pitch or coal tar as binder, dry and prepare porous composite carbonaceous reducing agent through burning sawdust; the present invention adjusts proportioning, optimizes process flow and condition parameters according to raw material characteristics; in industrial silicon In production, it can achieve the purpose of ensuring the gas permeability of the charge, ensuring the output and reducing the energy consumption of industrial silicon to reduce production costs, and providing a basis for the selection and use of industrial silicon-carbon reducing agents

Method used

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  • Preparation method of porous composite carbonaceous reducing agent

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The difference of embodiment 1 is:

[0034] The addition of sawdust is 5%, and the addition of binder is 2%;

[0035] Dry the reducing agent pellet precursor in step (4) under vacuum conditions, and then burn the sawdust in the reducing agent pellet precursor under vacuum at 200°C for 30 minutes. The sawdust is decomposed by burning to make the reducing agent pellets Pores are generated in the group precursor to obtain a porous composite carbonaceous reducing agent;

[0036] The specific resistance of the porous composite carbonaceous reducing agent in this example is 8000 μΩ·m, the fixed carbon content of the porous composite carbonaceous reducing agent pellet is 85%, the ash content is 3%, the reactivity is 92%, and the cold strength is 9000N.

Embodiment 2

[0037] The difference of embodiment 2 is:

[0038] The addition of sawdust is 30%, and the addition of binder is 20%;

[0039] Dry the reducing agent pellet precursor in step (4) under vacuum conditions, and then burn the sawdust in the reducing agent pellet precursor in vacuum at 600°C for 120 minutes. The sawdust is decomposed by burning to make the reducing agent pellets Pores are generated in the group precursor to obtain a porous composite carbonaceous reducing agent;

[0040] The specific resistance of the porous composite carbonaceous reducing agent in this example is 4000 μΩ·m, the fixed carbon content of the porous composite carbonaceous reducing agent pellet is 82%, the ash content is 5%, the reactivity is 90%, and the cold strength is 10000N.

Embodiment 3

[0041] The difference of embodiment 3 is:

[0042] The addition of sawdust is 15%, and the addition of binder is 10%;

[0043] Dry the reducing agent pellet precursor in the general step (4) under vacuum conditions, and then burn the sawdust in the reducing agent pellet precursor under vacuum at 400°C for 60 minutes. The sawdust is decomposed by burning to make the reducing agent Pores are generated in the pellet precursor to obtain a porous composite carbonaceous reducing agent;

[0044] The specific resistance of the porous composite carbonaceous reducing agent in this example is 6000 μΩ·m, the fixed carbon content of the porous composite carbonaceous reducing agent pellet is 86%, the ash content is 3%, the reactivity is 95%, and the cold strength is 8500N.

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Abstract

The invention relates to a preparation method of a porous composite carbonaceous reducing agent, and belongs to the technical field of industrial silicon smelting. The preparation method comprises thefollowing steps: respectively crushing petroleum coke and coal, screening sawdust, heating and melting a binder to a molten liquid state, uniformly mixing the petroleum coke with the coal, the sawdust and the molten liquid binder, and pelletizing to obtain a reducing agent pellet precursor; and drying the reducing agent pellet precursor, and firing sawdust in the reducing agent pellet precursor to generate a large number of pores in the reducing agent pellet precursor, thereby obtaining the porous composite carbonaceous reducing agent. The porous composite carbonaceous reducing agent has thecharacteristics of high mechanical strength, good reaction activity and the like, the reduction rate of silica can be increased, the consumption of the reducing agent is reduced by 5-10%, the ecological problem caused by a large amount of deforestation is relieved, and the production cost is reduced. The method has the advantages of being simple in equipment requirement, easy to operate, suitablefor large-scale industrial production and the like.

Description

technical field [0001] The invention relates to a preparation method of a porous composite carbonaceous reducing agent, which belongs to the technical field of industrial silicon smelting. Background technique [0002] The rapid development of the industrial silicon industry has caused a large amount of wood consumption to seriously damage the ecological environment. Therefore, finding an efficient and environmentally friendly alternative to charcoal as an industrial silicon-carbon reductant has become a bottleneck problem that researchers urgently need to solve. Because of its high fixed carbon content, low ash content, high mechanical strength, and stable composition, petroleum coke is one of the carbonaceous reducing agents commonly used by many industrial silicon production enterprises. In the high-temperature smelting process of industrial silicon, since petroleum coke is a carbon material with a graphite-like structure, the degree of graphitization is high at high tem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/05C01B33/025C01B33/021
CPCC01B32/05C01B33/025C01B33/021
Inventor 魏奎先马文会周世超陈正杰
Owner KUNMING UNIV OF SCI & TECH