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Negative electrode material for nonaqueous secondary batteries, negative electrode for nonaqueous secondary batteries, and nonaqueous secondary battery

A non-aqueous secondary battery and negative electrode material technology, applied in the direction of secondary batteries, battery electrodes, negative electrodes, etc., can solve the problem of insufficient formation of conductive paths, insufficient Li ion diffusivity, low temperature input and output characteristics, and rapid charge and discharge Insufficient cycle characteristics and other problems, to achieve the effect of excellent cycle characteristics and excellent fast charge and discharge characteristics

Pending Publication Date: 2020-11-17
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The present inventors have found through research that in the negative electrode materials for non-aqueous secondary batteries described in the above-mentioned patent documents 1 and 2, there are insufficient diffusivity of Li ions in the electrodes due to the formation of the conductive path between the negative electrode material particles, Therefore, there are insufficient low-temperature input-output characteristics, rapid charge-discharge characteristics, and cycle characteristics.
In addition, it was found that in the negative electrode materials for non-aqueous secondary batteries described in the above-mentioned patent documents 3 to 5, although the diffusibility of Li ions in the electrode was improved by increasing the tap density, the formation of the conductive path was insufficient. However, there are insufficient low-temperature input-output characteristics, rapid charge-discharge characteristics, and cycle characteristics.

Method used

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  • Negative electrode material for nonaqueous secondary batteries, negative electrode for nonaqueous secondary batteries, and nonaqueous secondary battery
  • Negative electrode material for nonaqueous secondary batteries, negative electrode for nonaqueous secondary batteries, and nonaqueous secondary battery
  • Negative electrode material for nonaqueous secondary batteries, negative electrode for nonaqueous secondary batteries, and nonaqueous secondary battery

Examples

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Embodiment 1

[0180] (Preparation of Negative Electrode for Nonaqueous Electrolyte Secondary Battery)

[0181] d50 is 8.0μm, d90 is 12.5μm, d10 is 5.3μm, d90 / d10 is 2.4, BET specific surface area is 10.9m 2 / g, the tap density is 0.90g / cm 3 , roundness (1.5-40μm) is 0.95, roundness (10-40μm) is 0.91, powder density is 1.1g / cm 3 To graphite particles with a volume resistivity of 0.053Ω·cm, 2.0 mass% of graphite particles with a primary particle size of 24nm and a BET specific surface area (SA) of 115m were added. 2 / g, DBP oil absorption is the carbon black of 110mL / 100g, and utilize the crushing mechanism of the carbon black aggregate based on the shredder and the mixing and stirring mechanism of the powder based on the rotation of the shovel to use the rotary mixer with the shredder Mixing and stirring were performed for 5 minutes at a rotation speed of 3000 rpm. This mixed powder is mixed with petroleum-based heavy oil obtained when naphtha, which is a precursor of carbonaceous substan...

Embodiment 2

[0199] A sample was obtained by the same method as in Example 1 except that 100 parts by mass of graphite particles were coated with 3 parts by weight of amorphous carbon, and the same evaluation as in Example 1 was performed. The results are shown in Table 1 (Table 1A, Table 1B) and Table 2.

Embodiment 3

[0201] Using d50 of 8.3μm, d90 of 13.3μm, d10 of 4.5μm, d90 / d10 of 3.0, BET specific surface area of ​​11.0m 2 / g, tap density is 0.83g / cm 3 , roundness (1.5-40μm) is 0.94, roundness (10-40μm) is 0.90, powder density is 1.1g / cm 3 Except for graphite particles having a volume resistivity of 0.049Ω·cm, a sample was obtained by the same method as in Example 2, and the same evaluation as in Example 1 was performed. The results are shown in Table 1 (Table 1A, Table 1B) and Table 2.

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Abstract

The present invention is a negative electrode material for nonaqueous secondary batteries, which contains a graphite that has amorphous carbon in at least a part of the surface, and which has a density index (Dr-t) expressed by formula 1 of 0.080 g / cm<3> or less. Formula 1: Dr-t (g / cm<3>) = (powder density (g / cm<3>) at a volume resistivity of 0.05 Omega*cm) - (tap density (g / cm<3>)).

Description

technical field [0001] The present invention relates to a negative electrode material for a non-aqueous secondary battery excellent in low-temperature input-output characteristics, rapid charge-discharge characteristics and cycle characteristics. Moreover, this invention relates to the negative electrode for nonaqueous secondary batteries containing this negative electrode material for nonaqueous secondary batteries, and a nonaqueous secondary battery. Background technique [0002] In recent years, along with miniaturization of electronic equipment, the demand for high-capacity secondary batteries has been increasing. In particular, non-aqueous secondary batteries, especially lithium ion secondary batteries, which have higher energy density and better rapid charge and discharge characteristics than nickel-cadmium batteries and nickel-hydrogen batteries have attracted attention. In particular, a positive electrode and a negative electrode that can occlude and release lithium...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/587H01M4/36
CPCH01M4/587Y02E60/10H01M4/366H01M4/625H01M10/0525H01M4/133H01M2004/021H01M2004/027
Inventor 山田俊介石渡信亨佐藤智洋
Owner MITSUBISHI CHEM CORP