Microbial-friendly biomass fertilizer coating agent and preparation method thereof
A kind of fertilizer coating and friendly technology, which is applied in the direction of organic fertilizers, fertilizer mixtures, layered/coated fertilizers, etc., can solve the problems of insufficient nutrients, high operating costs, and increased operating costs in the later stage, so as to reduce hydrophobicity and biological Toxicity, environmental and microbial friendliness, effect of improving fertilizer use efficiency
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Embodiment 1
[0034] A biomass-based fertilizer coating agent is prepared from the following raw materials in parts by weight: lignin 10, tackifier 5, and biomass pyrolysis-modified heavy oil 85.
[0035] Among them, the preparation method of biomass pyrolysis oil is as follows: dry and crush corn stalks to 50 mm, place them in a biomass pyrolysis device, and conduct pyrolysis in the absence of oxygen under the condition of a heating rate of 15 °C / s and a final temperature of 500 °C, and collect Volatile matter, the volatile matter is cooled to room temperature to form bio-oil. Add ethanol with a volume ratio of 100% to the bio-oil, stir and mix thoroughly, put it into a high-temperature, high-pressure reactor, raise the temperature to 110°C, and react for 40min at a stirring intensity of 150r / min. After the esterification reaction, add 150% dichloromethane by volume to the bio-oil cooled to room temperature, stir well and then stand for stratification, remove the polar liquid in the upper ...
Embodiment 2
[0040] A biomass-based fertilizer coating agent is prepared from the following raw materials in parts by weight: lignin 5, tackifier 10, biomass pyrolysis modified heavy oil 85.
[0041] Among them, the preparation method of biomass pyrolysis oil is as follows: dry and crush wheat straw to 50 mm, place it in a biomass pyrolysis device, and carry out pyrolysis in the absence of oxygen under the condition of a heating rate of 20 °C / s and a final temperature of 450 °C, and collect Volatile matter, the volatile matter is cooled to room temperature to form bio-oil. Add ethanol with a volume ratio of 100% to the bio-oil, stir and mix thoroughly, put it into a high-temperature, high-pressure reactor, raise the temperature to 100°C, and react for 60 minutes at a stirring intensity of 150r / min. After the esterification reaction, add 150% dichloromethane by volume to the bio-oil cooled to room temperature, stir well and then stand for stratification, remove the polar liquid in the upper...
Embodiment 3
[0046] A biomass-based fertilizer coating agent is prepared from the following raw materials in parts by weight: lignin 5, tackifier 5, and biomass pyrolysis-modified heavy oil 90.
[0047] Among them, the preparation method of biomass pyrolysis oil is as follows: dry and crush rice stalks to 50 mm, place them in a biomass pyrolysis device, and conduct pyrolysis in the absence of oxygen under the condition of a heating rate of 20 °C / s and a final temperature of 450 °C, and collect Volatile matter, the volatile matter is cooled to room temperature to form bio-oil. Add methanol with a volume ratio of 100% to the bio-oil, stir and mix thoroughly, put it into a high-temperature, high-pressure reactor, raise the temperature to 120°C, and react for 40min at a stirring intensity of 150r / min. After the esterification reaction, add 150% dichloromethane by volume to the bio-oil cooled to room temperature, stir well and then stand for stratification, remove the polar liquid in the upper ...
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