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Preparation and application of an environmentally friendly and low-cost superhydrophobic powder material

A powder material, super-hydrophobic technology, applied in coatings and other directions, can solve the problems of inconvenient promotion and large-scale practical application, weak combination of micro-nano structure and substrate, and high cost of super-hydrophobic surface preparation, so as to reduce the preparation cost and shorten the Reaction time, the effect of increasing the binding force

Active Publication Date: 2021-12-14
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The commonly used superhydrophobic surface preparation methods at this stage include electrodeposition, hydrothermal method, chemical etching method, vapor deposition method, sol-gel method, electrospinning method, plasma treatment and laser engraving method, etc. Although these methods can Effectively prepare superhydrophobic surfaces, but often require higher experimental conditions or are only applicable to specific material substrates, and there are problems such as weak combination of micro-nano structures and substrates, long preparation time, and complicated processes, which are not convenient for other substrates. promotion and practical application on a large scale
In addition, in the process of reducing surface energy, fluoropolymers / compounds are usually used as low surface energy substances, and involve the use of a large amount of toxic organic solvents such as acetone, toluene, methylene chloride, etc., which not only makes the preparation of superhydrophobic surfaces The cost is high, and it may also cause environmental pollution, endanger human health and other problems. Therefore, there is a need for the preparation and application of an environmentally friendly and low-cost superhydrophobic powder material that can effectively solve the above problems.

Method used

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  • Preparation and application of an environmentally friendly and low-cost superhydrophobic powder material
  • Preparation and application of an environmentally friendly and low-cost superhydrophobic powder material
  • Preparation and application of an environmentally friendly and low-cost superhydrophobic powder material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Measure 70ml of absolute ethanol into a 150ml electrolytic cell, add 2.25g of micro-nano material KL, first magnetically stir for 1min, and then ultrasonic for 10min; the stirring time is to fully mix the micro-nano material KL and absolute ethanol, and the ultrasonic is to allow The micro-nano material KL is fully dispersed.

[0038] Add 2.5ml tetraethyl orthosilicate and 2.0ml long-chain silane 1 in sequence, and stir for 5 minutes;

[0039] Then add 30ml NaNO3 (0.67M) aqueous solution, adjust the pH with glacial acetic acid, and continue to stir for 30 minutes; the sodium nitrate aqueous solution mainly acts as an electrolyte, so potassium nitrate, potassium chloride, etc. can be used instead.

[0040] Use electrode 1 (1.5cm×1.5cm) as the anode, electrode 2 (4.5cm×2.25cm) as the cathode, and the distance between the electrodes is 4.5cm. Use a DC power supply (Huatai Power Supply HAP03-100) to react at a constant voltage of 30.0V for 90min with the assistance of stirr...

Embodiment 2

[0045] Measure 80ml of absolute ethanol into a 150ml electrolytic cell, add 2.25g of micro-nano material KL, first magnetically stir for 1min, then ultrasonic for 10min;

[0046] Add 2.5ml tetraethyl orthosilicate and 2.0ml long-chain silane 1 in sequence, and stir for 5 minutes;

[0047] Then add 30ml NaNO3 (0.67M) aqueous solution, use glacial acetic acid to adjust the pH, and continue to stir for 30min;

[0048] Use electrode 1 (1.5cm×1.5cm) as the anode, electrode 2 (4.5cm×2.25cm) as the cathode, and the distance between the electrodes is 4.5cm. Use a DC power supply (Huatai Power Supply HAP03-100) to react at a constant voltage of 40.0V for 90min with the assistance of stirring , sonicate for 5 minutes after the reaction;

[0049] Utilize centrifuge to separate 5min under 8000rpm, use absolute ethanol to wash three times;

[0050] The white matter was collected and dried at 60°C for 6h.

[0051] From the above experimental procedures, it can be seen that the difference...

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Abstract

The invention discloses the preparation and application of an environment-friendly and low-cost super-hydrophobic powder material. The micro-nano material KL is obtained by adding 50%-90% absolute ethanol into the micro-nano material KL, stirring for 1-5min, and ultrasonically dispersing for 5-15min. Dispersion liquid; adding long-chain silane and ethyl orthosilicate with a volume ratio of 1: (1-1.25) in sequence; adding sodium nitrate aqueous solution containing 1.9-2.1 molar mass to the micro-nano material KL mixture, and continuing to stir for 10- 30 minutes; the micro-nano material KL mixed solution was subjected to double-electrode electrolysis; after the reaction, the solution was ultrasonically washed and centrifuged, and dried to obtain a superhydrophobic powder. The invention increases the utilization rate of low surface energy substances, improves the yield of the super-hydrophobic material, reduces the preparation cost of the super-hydrophobic material, and adopts a two-electrode system for reaction, thereby shortening the reaction time.

Description

technical field [0001] The invention relates to the field of superhydrophobic materials, in particular to the preparation and application of an environmentally friendly and low-cost superhydrophobic powder material. Background technique [0002] According to wettability, materials can be divided into superhydrophobic materials, hydrophobic materials, hydrophilic materials, superhydrophilic materials and amphoteric materials. Usually superhydrophobic surface refers to a type of material surface where water droplets of a certain size have a water contact angle greater than 150° and a roll angle less than 10° on the material surface. For example, the surface of lotus leaves and butterfly wings is a typical superhydrophobic surface in nature. Due to the excellent functions such as self-cleaning, anti-icing, anti-corrosion, waterproof, and anti-fog, the surface of superhydrophobic materials has broad application prospects in the fields of aviation, automobiles, anti-corrosion, co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D7/62C09D7/20
CPCC09D183/04C09D7/62C09D7/20C08K2201/011C08K9/02C08K3/346
Inventor 袁绍军刘祥欧阳李科梁斌
Owner SICHUAN UNIV
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