Preparation and application of an environmentally friendly and low-cost superhydrophobic powder material
A powder material, super-hydrophobic technology, applied in coatings and other directions, can solve the problems of inconvenient promotion and large-scale practical application, weak combination of micro-nano structure and substrate, and high cost of super-hydrophobic surface preparation, so as to reduce the preparation cost and shorten the Reaction time, the effect of increasing the binding force
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Embodiment 1
[0037] Measure 70ml of absolute ethanol into a 150ml electrolytic cell, add 2.25g of micro-nano material KL, first magnetically stir for 1min, and then ultrasonic for 10min; the stirring time is to fully mix the micro-nano material KL and absolute ethanol, and the ultrasonic is to allow The micro-nano material KL is fully dispersed.
[0038] Add 2.5ml tetraethyl orthosilicate and 2.0ml long-chain silane 1 in sequence, and stir for 5 minutes;
[0039] Then add 30ml NaNO3 (0.67M) aqueous solution, adjust the pH with glacial acetic acid, and continue to stir for 30 minutes; the sodium nitrate aqueous solution mainly acts as an electrolyte, so potassium nitrate, potassium chloride, etc. can be used instead.
[0040] Use electrode 1 (1.5cm×1.5cm) as the anode, electrode 2 (4.5cm×2.25cm) as the cathode, and the distance between the electrodes is 4.5cm. Use a DC power supply (Huatai Power Supply HAP03-100) to react at a constant voltage of 30.0V for 90min with the assistance of stirr...
Embodiment 2
[0045] Measure 80ml of absolute ethanol into a 150ml electrolytic cell, add 2.25g of micro-nano material KL, first magnetically stir for 1min, then ultrasonic for 10min;
[0046] Add 2.5ml tetraethyl orthosilicate and 2.0ml long-chain silane 1 in sequence, and stir for 5 minutes;
[0047] Then add 30ml NaNO3 (0.67M) aqueous solution, use glacial acetic acid to adjust the pH, and continue to stir for 30min;
[0048] Use electrode 1 (1.5cm×1.5cm) as the anode, electrode 2 (4.5cm×2.25cm) as the cathode, and the distance between the electrodes is 4.5cm. Use a DC power supply (Huatai Power Supply HAP03-100) to react at a constant voltage of 40.0V for 90min with the assistance of stirring , sonicate for 5 minutes after the reaction;
[0049] Utilize centrifuge to separate 5min under 8000rpm, use absolute ethanol to wash three times;
[0050] The white matter was collected and dried at 60°C for 6h.
[0051] From the above experimental procedures, it can be seen that the difference...
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