A kind of imitation porcelain bottle and preparation method thereof
A technology of imitating porcelain and melamine, applied in the field of imitating porcelain materials, can solve the problems of easy cracking and poor toughness under stress
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Embodiment 1
[0019] An imitation porcelain bottle, its raw materials include by weight: 100 parts of filler, 10 parts of melamine formaldehyde resin, 40 parts of vegetable pectin, 30 parts of α-cellulose, 0.1 part of curing agent, 2 parts of zinc stearate, silane coupling 2 doses;
[0020] Wherein, the fillers are calcium carbonate, titanium dioxide and calcined kaolin, wherein the weight ratio of calcium carbonate, titanium dioxide and calcined kaolin is 3:1:6;
[0021] In the preparation process of melamine formaldehyde resin, γ-aminopropyltriethoxysilane modified montmorillonite was uniformly dispersed in melamine aqueous solution, stirred for 90 min with ultrasonic, then added polyethylene glycol 200 and mixed well, adjusted pH with phosphoric acid aqueous solution =6-6.5, react at 70°C for 3h, centrifuge, wash, and dry to obtain material 1, wherein the content of modified montmorillonite in material 1 is 3wt%, and the molar ratio of melamine and polyethylene glycol 200 is 1.1:1 ;
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Embodiment 2
[0025] An imitation porcelain bottle, its raw materials include by weight: 100 parts of filler, 15 parts of melamine formaldehyde resin, 30 parts of vegetable pectin, 20 parts of α-cellulose, 0.2 parts of curing agent, 1 part of zinc stearate, silane coupling 4 doses;
[0026] Wherein, the fillers are calcium carbonate, titanium dioxide and calcined kaolin, wherein the weight ratio of calcium carbonate, titanium dioxide and calcined kaolin is 2:1:7;
[0027] In the preparation process of melamine formaldehyde resin, γ-aminopropyltriethoxysilane modified montmorillonite was dispersed uniformly in the melamine aqueous solution, stirred for 60 min with ultrasonic, then added polyethylene glycol 200 and mixed well, and adjusted the pH with phosphoric acid aqueous solution =6-6.5, react at 90°C for 2.5h, centrifuge, wash, and dry to obtain material 1, wherein the content of modified montmorillonite in material 1 is 5wt%, and the molar ratio of melamine and polyethylene glycol 200 i...
Embodiment 3
[0031] An imitation porcelain bottle, its raw materials include by weight: 100 parts of filler, 12 parts of melamine formaldehyde resin, 35 parts of vegetable pectin, 25 parts of α-cellulose, 0.15 parts of curing agent, 1.5 parts of zinc stearate, silane coupling 3 doses;
[0032] Wherein, the fillers are calcium carbonate, titanium dioxide and calcined kaolin, wherein the weight ratio of calcium carbonate, titanium dioxide and calcined kaolin is 2.5:1:6.5;
[0033] In the preparation process of melamine formaldehyde resin, the γ-aminopropyltriethoxysilane modified montmorillonite was dispersed uniformly in the melamine aqueous solution, stirred for 80 min with ultrasound, then added polyethylene glycol 200 and mixed well, and the pH was adjusted with phosphoric acid aqueous solution =6-6.5, react at 80°C for 2.8h, centrifuge, wash, and dry to obtain material 1, wherein the content of modified montmorillonite in material 1 is 4wt%, and the molar ratio of melamine and polyethyl...
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