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Composition for electricity storage devices, slurry for electricity storage device electrodes, electricity storage device electrode, and electricity storage device

A technology of electric storage device and composition, which is applied to non-aqueous electrolyte battery electrodes, battery electrodes, hybrid capacitor electrodes, etc., can solve the problems of active material layer structure damage, volume change, deterioration of charge and discharge durability characteristics, etc. Effects of flexibility, improved battery performance, and good charge-discharge durability characteristics

Pending Publication Date: 2021-02-19
株式会社引能仕材料
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] However, the active material using such a material with a large lithium storage capacity is accompanied by a large volume change due to the storage and release of lithium.
Therefore, if the conventionally used electrode binder is applied to such a material with a large lithium storage capacity, the volume change accompanying charge and discharge will not be tolerated, the structure of the active material layer will be destroyed, and the charge and discharge durability characteristics will be significantly deteriorated.

Method used

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  • Composition for electricity storage devices, slurry for electricity storage device electrodes, electricity storage device electrode, and electricity storage device
  • Composition for electricity storage devices, slurry for electricity storage device electrodes, electricity storage device electrode, and electricity storage device
  • Composition for electricity storage devices, slurry for electricity storage device electrodes, electricity storage device electrode, and electricity storage device

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preparation example Construction

[0137] 2.2.3. Preparation method of slurry for storage device electrodes

[0138]The slurry for an electrical storage device electrode according to this embodiment may be a slurry for an electrical storage device electrode produced by any method as long as it contains the above-mentioned composition for an electrical storage device and an active material. Manufactured by the method described in et al.

[0139] 3. Electrode of electrical storage equipment

[0140] The electrical storage device electrode of the present embodiment includes a current collector and an active material layer formed by applying and drying the above-mentioned slurry for electrical storage device electrodes on the surface of the current collector. This electrical storage device electrode is produced by coating the above-mentioned slurry for electrical storage device electrodes on the surface of a current collector such as a metal foil to form a coating film, and then drying the coating film to form an ...

Embodiment 4

[0195] In the above "5.1.1. Preparation and evaluation of composition for electrical storage device (1) Preparation of composition for electrical storage device", the type and amount of each monomer are as described in Table 1 below, except , The composition for electrical storage devices containing 20 mass % of polymers (A4) was obtained similarly.

[0196] Next, 0.5 parts by mass (A4) of the polymer (A4) was charged into a twin-shaft planetary mixer (manufactured by Primex Co., Ltd., trade name "TK HIVIS MIX 2P-03") (solid content conversion value, as the pH 9.0 obtained above). Addition to the composition for electrical storage devices), water-based binder (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd., trade name "10CLPAH", cross-linked polyacrylic acid) 2.5 parts by mass (solid content conversion value, neutralized with sodium hydroxide , added as an aqueous solution with a pH of 9.0 and a concentration of 2% by mass), 90 parts by mass (solid content conver...

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Abstract

The present invention provides a composition for electricity storage devices, which is excellent in terms of flexibility, rubbing resistance and particle fall-off, and which is capable of producing anelectricity storage device electrode that exhibits good charge and discharge durability characteristics. A composition for electricity storage devices according to the present invention contains a polymer (A) and a liquid medium (B); and the polymer (A) contains 20-70 parts by mass of a repeating unit (a1) that is derived from a conjugated diene compound and 10-50 parts by mass of a repeating unit (a2) that is derived from an unsaturated carboxylic acid if the total of repeating units contained in the polymer (A) is taken as 100 parts by mass. With respect to the integral molecular weight distribution curve of the polymer (A) as determined by size exclusion chromatography (SEC) in accordance with JIS K7252, a copolymer fraction having a molecular weight of 1,000,000 or less is contained in an amount of 30% by mass or more relative to all copolymers.

Description

technical field [0001] The present invention relates to a composition for an electrical storage device, a slurry for an electrical storage device electrode containing the composition and an active material, an electrode for an electrical storage device formed by applying the slurry to a current collector and drying the electrode, and an electrode provided with the electrode power storage equipment. Background technique [0002] In recent years, power storage devices with high voltage and high energy density have been required as power sources for driving electronic devices. As such power storage devices, lithium ion batteries, lithium ion capacitors, and the like have been expected. [0003] An electrode used in such an electrical storage device is produced by applying a composition (slurry for electrode) containing an active material and a polymer functioning as a binder on the surface of a current collector and drying it. The properties required for polymers used as bind...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62C08F220/04C08F236/04C08L25/10C08L27/12C08L33/02C08L47/00H01G11/38H01M4/13H01M4/134
CPCH01M4/13H01M4/134H01M4/62C08F220/04C08F236/04C08L25/10C08L27/12C08L33/02C08L47/00H01G11/38Y02E60/10H01M4/622H01M4/131H01G11/50
Inventor 大桥泰良麻生圭吾助口大介浅井悠太
Owner 株式会社引能仕材料