Low-temperature-resistant medical PVC film and preparation method thereof
A PVC film, low temperature-resistant technology, used in pharmaceutical formulations, pharmaceutical science, rayon manufacturing, etc., can solve problems such as inability to exclude human sweat, affecting film transparency, and unfavorable doctor's observation, to promote wound hemostasis and healing, and achieve antibacterial. Performance, good effect of color and yellowing resistance
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Embodiment 1
[0039] (1) Preparation of base film:
[0040] Take sodium acetylene to react with 6-chloro-1-hexanol, take the product and add sodium amide for reaction, then react with m-hydroxybenzyl chloride again to obtain product A;
[0041] Take polyvinyl alcohol, add pure water to heat up and dissolve, add vinyl acetate and acetic acid and mix thoroughly to prepare mixed solution C;
[0042] Take polyvinyl chloride, add N,N-dimethylacetamide, α-methylstyrene, product A, and mixed solution C to mix thoroughly, add benzoyl peroxide, and place it at 70°C for 2 hours at a constant temperature , to obtain modified polyvinyl chloride;
[0043] Take modified polyvinyl chloride, add fatty acid sucrose polyester and calcium chloride and put it in the mixing chamber for melting and mixing, set the mixing temperature to 140°C, the rotation speed to 40r / min, the mixing time to 8min, take the product and add N, N-dimethylacetamide, polyethylene glycol, and methanol are fully mixed, then spun, soake...
Embodiment 2
[0052] (1) Preparation of base film:
[0053] Take sodium acetylene to react with 6-chloro-1-hexanol, take the product and add sodium amide for reaction, then react with m-hydroxybenzyl chloride again to obtain product A;
[0054] Take polyvinyl alcohol, add pure water to heat up and dissolve, add vinyl acetate and acetic acid and mix thoroughly to prepare mixed solution C;
[0055] Take polyvinyl chloride, add N,N-dimethylacetamide, α-methylstyrene, product A, and mixed solution C to mix thoroughly, add benzoyl peroxide, and place it at 80°C for 4 hours at a constant temperature , to obtain modified polyvinyl chloride;
[0056] Take modified polyvinyl chloride, add fatty acid sucrose polyester and calcium chloride and put it in the mixing room for melting and mixing. Set the mixing temperature to 145°C, the speed to 42r / min, and the mixing time to 10 minutes. Take the product and add N, N-dimethylacetamide, polyethylene glycol and methanol are fully mixed and then spun, soa...
Embodiment 3
[0065] (1) Preparation of base film:
[0066] Take sodium acetylene to react with 6-chloro-1-hexanol, take the product and add sodium amide for reaction, then react with m-hydroxybenzyl chloride again to obtain product A;
[0067] Take polyvinyl alcohol, add pure water to heat up and dissolve, add vinyl acetate and acetic acid and mix thoroughly to prepare mixed solution C;
[0068] Take polyvinyl chloride, add N,N-dimethylacetamide, α-methylstyrene, product A, and mixed solution C to mix thoroughly, add benzoyl peroxide, and place it at 90°C for constant temperature reaction for 6 hours , to obtain modified polyvinyl chloride;
[0069] Take modified polyvinyl chloride, add fatty acid sucrose polyester and calcium chloride, put it in the mixing room to melt and mix, set the mixing temperature to 150°C, the speed to 45r / min, and the mixing time to 13min, take the product and add N, N-dimethylacetamide, polyethylene glycol, and methanol are fully mixed and then spun, soaked in...
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