Anti-termite and anti-rat cable and preparation method thereof
A cable and termite prevention technology, applied in plastic/resin/wax insulators, organic insulators, electrical components, etc. High and low temperature performance, avoid circuit short circuit, improve the effect of flame retardant
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preparation example 1
[0028] Preparation Example 1 Preparation of porous silica / carboxylated polystyrene double-layer hollow spheres
[0029] The preparation method is as follows:
[0030]S1. After mixing 100g of water, 10g of methanol, and 22g of styrene, under the protection of nitrogen, the temperature of the system was raised to 70°C, and 1g of sodium persulfate was added, and the reaction was stopped after 2 hours of reaction to obtain polystyrene seed microspheres, which were centrifuged several times , Collect after washing for use;
[0031] S2. After mixing 70g water, 1g sodium lauryl sulfate, 10g methanol, and 100gDMSO evenly, heat to 60°C while stirring, add 12g polystyrene seed microspheres obtained in step S1 and dissolve 0.5g dihydrogen peroxide A mixed solution of diisopropyl carbonate, 27g of p-divinylbenzene and 22g of methacrylic acid was heated to 75°C for polymerization, and reacted for 1h, and the coated core-shell structure microspheres were swelled with anhydrous ether to rem...
preparation example 2
[0034] Preparation Example 2 Preparation of porous silica / carboxylated polystyrene double-layer hollow spheres
[0035] The preparation method is as follows:
[0036] S1. After mixing 100g of water, 30g of ethanol, and 37g of styrene, under the protection of nitrogen, the temperature of the system was raised to 80°C, and 1g of ammonium persulfate was added, and the reaction was stopped after 5 hours of reaction to obtain polystyrene seed microspheres, which were centrifuged several times , Collect after washing for use;
[0037] S2. After mixing 70g water, 1-3g sodium dodecylbenzenesulfonate, 30g ethanol, and 120gDMSO evenly, heat to 70°C while stirring, add 20g of polystyrene seed microspheres obtained in step S1 and dissolve 1.5 A mixed solution of tert-butyl peroxy tert-butyl valerate, 45g p-divinylbenzene and 30g methacrylic acid was heated to 80°C for polymerization, and reacted for 3h, and the coated core-shell microspheres were carried out with anhydrous ether. Swelli...
Embodiment 1
[0041] Including the cable core and the sheath wrapped in the cable core, the raw material composition (parts by weight) of the sheath: 10 parts of porous silica / carboxylated polystyrene double-layer hollow spheres prepared in Preparation Example 1, positive- 2 parts of nonanoic acid vanillyl amide, 100 parts of polyethylene, 2 parts of composite flame retardant, 1 part of toughening agent carboxyl liquid nitrile rubber, antioxidant quaternary [β-(3,5-tertiary butyl-4-hydroxy 0.5 part of phenyl) propionate] pentaerythritol ester, 0.1 part of zinc stearate as a dispersant, and 2 parts of microcrystalline cellulose. The composite flame retardant is a mixture of expanded graphite and chlorinated paraffin with a mass ratio of 2:1.
[0042] Include the following steps:
[0043] S1. Dissolve n-nonanoic acid vanillylamide in DMSO, add porous silica / carboxylated polystyrene double-layer hollow spheres, after ultrasonic dispersion, heat to 45°C for 1 hour, centrifuge, wash the solid w...
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