Carbon matter-containing material production method, carbon matter-containing material, and soluble organic-inorganic composite
A manufacturing method and technology of carbon substances, which are applied in the fields of the manufacture of carbon-containing materials, carbon-containing materials, and soluble organic-inorganic composites, and can solve problems such as the difficulty in precisely controlling the structure and changes of carbon-containing materials
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Embodiment 1
[0457] [Example 1]: phloroglucinol+silica particles+250°C×1 hour
[0458] Phloroglucinol (manufactured by Tokyo Chemical Industry Co., Ltd., melting point: 220°C, condensation reaction temperature: 330°C, theoretical specific surface area: 750m 2 / g) with silica particles (manufactured by Fuji Silysia Chemical Ltd., product name: "Q-10HT60315", specific surface area: 259m 2 / g) Mix well so that the thickness of the phloroglucinol layer is 1.5 times greater than the thickness of the silica particle layer.
[0459] The resulting mixture was sealed in a quartz ampoule in vacuum, and then heated in an electric furnace preheated to 250° C. for 1 hour.
[0460] Thus, an organic-inorganic composite (1) including the carbon substance (1A) and the inorganic oxide (1B) was obtained.
[0461] The organic-inorganic composite (1) was dispersed in N-methylpyrrolidone (NMP), and the solubility of its carbon component was confirmed by the means described in the foregoing. As a result, this...
Embodiment 2
[0468] [Example 2]: phloroglucinol+alumina particles+250°C×1 hour
[0469] In addition to changing the silica particles to alumina particles (sample "JRC-ALO7" distributed free of charge by the general corporate juridical person "Japan Society of Catalysis", specific surface area: 180m 2 / g), an organic-inorganic composite (2) including a carbon substance (2A) and an inorganic oxide (2B) was obtained in the same manner as in Example 1.
[0470] The organic-inorganic composite (2) was dispersed in N-methylpyrrolidone (NMP), and the solubility of its carbon component was confirmed in the manner described in the foregoing. As a result, this component is soluble in the solvent.
[0471] The results of the C1s XPS analysis of the obtained organic-inorganic complex (2) are shown in image 3 (XPS Spectrum (C1s)) and Table 1. From Table 1, it was found that the organic-inorganic composite (2) was an organic-inorganic composite including carbon substances and inorganic oxides. The ...
Embodiment 3
[0476] [Example 3]: phloroglucinol+titanium dioxide particles+250°C×1 hour
[0477] In addition to changing the silica particles to titanium dioxide particles (sample "JRC-TIO-4(2)" distributed free of charge by the general corporate juridical person "Japan Society of Catalysis", specific surface area: 50m 2 / g), an organic-inorganic composite (3) including a carbon substance (3A) and an inorganic oxide (3B) was obtained in the same manner as in Example 1.
[0478] The organic-inorganic composite (3) was dispersed in N-methylpyrrolidone (NMP), and the solubility of its carbon component was confirmed by the means described in the foregoing. As a result, this component is soluble in the solvent.
[0479] The results of the C1s XPS analysis of the obtained organic-inorganic complex (3) are shown in image 3 (XPS Spectrum (C1s)) and Table 1. From Table 1, it was found that the organic-inorganic composite (3) was an organic-inorganic composite including carbon substances and ino...
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Abstract
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