Preparation method of carbon nanotube
A technology of carbon nanotubes and carbon sources, applied in the fields of carbon nanotubes, nanocarbons, chemical instruments and methods, etc.
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[0023] The embodiment of the present application provides a method for preparing carbon nanotubes, such as figure 1 Shown, this preparation method comprises the steps:
[0024] S01: Provide mesoporous silica molecular template;
[0025] S02: Depositing a carbon source on the mesoporous silica molecular template by atomic layer deposition, and then removing the mesoporous silica molecular template to obtain carbon nanotubes.
[0026] The preparation method of the carbon nanotubes of the present application uses the mesoporous silica molecular template as the deposition substrate, adopts atomic layer deposition technology, deposits the carbon source on the mesoporous silica molecular template, and then removes the mesoporous silica After molecular templates, pure carbon nanotubes with good three-dimensional shape retention can be obtained; during the above-mentioned carbon source deposition process, when the carbon source molecules reach the surface of the deposition substrate,...
Embodiment 1
[0045] A method for preparing carbon nanotubes, comprising the steps of:
[0046] (1) Preparation of mesoporous silica molecular template:
[0047] The molar ratio TEOS:HCl:P123:C 2 h 5 OH=(0.1-1):(0.1-0.5):(0.01:0.1):(5-30) The raw materials are mixed to obtain a mixed liquid; the above mixed liquid is rapidly dispersed at 30-60°C and 400-1200rpm 30-300min; after uniform dispersion, lower to room temperature (25°C), and stand for 2-10h; obtain mesoporous silica molecular template by spin deposition or dipping deposition.
[0048] In this example, by adjusting different contents of TEOS, mesoporous silica molecular templates with different pore capacities and pore diameters can be obtained, and the specific results are shown in Table 1 below. Subsequent preparation of carbon nanotubes is carried out using the molecular template as a matrix.
[0049] Table 1
[0050] TEOS content (%) Pore capacity (m 3 / g)
Aperture (nm) Mesoporous silica molecular tem...
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