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Method and device for synergistic treatment of organic fluorine and terpene residue by plasma cracking

A plasma cracking and co-processing technology, applied in the field of chemical waste treatment, can solve the problems of not creating economic value, easily producing dioxins, incomplete incineration, etc. Effect

Active Publication Date: 2022-07-08
ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the general method of treating terpene raffinate is incineration, but there are also disadvantages such as incomplete incineration, high energy consumption, secondary pollution, and easy generation of dioxins.
[0004] Moreover, the current treatment of organic fluorine residues and terpene residues is to treat them as wastes for harmless treatment, without creating economic value

Method used

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  • Method and device for synergistic treatment of organic fluorine and terpene residue by plasma cracking

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] See figure 1 As shown, it is a device for co-processing organic fluorine and terpene residues by plasma cracking provided in this embodiment. The device includes a cracking furnace 1, and the cracking furnace 1 has a furnace body in the shape of a vertical cylinder. A high temperature zone 2 in the upper section of the furnace body and a low temperature zone 3 arranged in the lower part of the high temperature zone; a plasma torch 4 is vertically arranged at the center of the upper end face of the furnace body, and the port of the plasma torch 4 is arranged in the high temperature zone 2 in the furnace body. Plasma uses the plasma torch or plasma beam generated between the electrodes to generate high temperature. The plasma torch or plasma beam can be generated by AC, DC, power frequency and high frequency methods. The arc core temperature is very high and can achieve high temperature instantly. The power is turned on, and the current starts arcing at the port of the pl...

Embodiment 2

[0038] The tetrafluoroethylene raffinate and the terpene raffinate are treated synergistically, as follows:

[0039] The collaborative treatment is carried out in the cracking furnace, and the negative pressure of the cracking furnace is controlled at -300Pa;

[0040] Turn on the power supply, and the current will strike the arc at the port of the plasma spray gun to form a high-temperature arc area. When the plasma arc is heated to above 2000 °C, the tetrafluoroethylene residue and terpene residue, tetrafluoroethylene residue, terpene residue, terpene residue and terpene residue are simultaneously introduced The mass ratio of the alkene residue is 30kg / h:13kg / h. The tetrafluoroethylene residual liquid is composed of: 80%-95% of octafluorocyclobutane, 5%-10% of perfluoroisobutene, about 5% of tetrafluoroethylene or its polymer, and a small amount of chlorodifluoromethane; The main component of the alkene residue is C 10 H 16 and its analogs, the content is about 80%, the ot...

Embodiment 3

[0046] The hexafluoropropylene raffinate and the terpene raffinate are treated synergistically, as follows:

[0047] The synergistic treatment is carried out in the cracking furnace, and the negative pressure of the furnace chamber is controlled at -900Pa;

[0048] Turn on the power supply, and the current will strike the arc at the port of the plasma spray gun to form a high-temperature arc area. When the temperature of the plasma arc is above 2000 °C, the hexafluoropropylene residue and terpene residue, hexafluoropropylene residue and terpene are simultaneously introduced. The mass ratio of the alkene residue is 40kg / h:17kg / h. Among them, the composition of the hexafluoropropylene residual liquid is: about 90% of perfluoroisobutene, about 10% of octafluorocyclobutane, and a small amount of hexafluoropropylene. The main component of terpene raffinate is C 10 H 16 and its analogs, the content is about 80%, the other is heavy components and a small amount of water, and the h...

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Abstract

The invention belongs to the technical field of chemical waste treatment, and specifically discloses a method for co-processing organic fluorine residual liquid and terpene residual liquid by plasma cracking, and also discloses a processing device. The method for synergistically treating organic fluorine and terpene residue by plasma cracking provided by the present invention, by mixing the organic fluorine residue and the terpene residue according to the proportion, cracking in an oxygen-free environment under the action of a plasma high-temperature arc, can The reaction yields carbon black and hydrogen fluoride gas. The method of the invention not only realizes the comprehensive synergistic treatment of organic fluorine and terpene residual liquid, but also prepares carbon black products with high purity, and also obtains hydrofluoric acid by-product, which has good economic and environmental benefits.

Description

technical field [0001] The invention relates to the technical field of chemical waste treatment, in particular to a method and a device for co-processing organic fluorine residual liquid and terpene residual liquid by plasma cracking. Background technique [0002] Organofluorine raffinate and terpene raffinate are the major wastes from the fluoropolymer industry. The waste liquid produced in the process of producing organic fluorine polymer is organic fluorine residue, and the common method for treating organic fluorine residue is incineration. The disadvantage of incineration treatment is incomplete incineration, high energy consumption, secondary pollution, and easy production of dioxins. Plasma cracking has been reported to treat organic fluorine waste. For example, the patent application with publication number CN109798531A discloses a method for treating organic fluorine residue by plasma cracking. The method is to mix and crack the organic fluorine residue with compr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/68C01B32/05C01B7/19C02F1/46C02F101/32C02F101/36C02F103/38
CPCC01B32/05C01B7/191C02F1/4608B01D53/68C02F2101/36C02F2101/32C02F2103/38C02F2201/46Y02C20/30
Inventor 李慧叶飞杨陈立义宋亦兰关永昕邓礼洪张光利
Owner ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD