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Iron-chromium-aluminum alloy with pink oxide film and its preparation method and annealing furnace

An iron-chromium-aluminum alloy, oxide film technology, applied in anodizing, furnaces, manufacturing tools, etc., can solve the problems of uneven color, bending and poor torsional performance, and achieve high annealing temperature, good performance and long service life. Effect

Active Publication Date: 2022-07-12
BEIJING SHOUGANG GITANE NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the blue oxide film formation process is: lye → HNO 3 Solution → lye → heat treatment → water cooling, that is, put the drawn Fe-Cr-Al alloy directly into the lye for 40-60 minutes, take it out and wash it with hot water, then put it in the nitric acid solution for 60 seconds, take it out with Clean it with hot water, put it in the lye after burning for 120s, take it out, and anneal it at an annealing temperature of 700-800°C for 3-3.5 hours. The surface of the Fe-Cr-Al alloy wire produced by this annealing process is It is blue, but the color is not uniform, and the bending and torsion performance is slightly poor

Method used

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  • Iron-chromium-aluminum alloy with pink oxide film and its preparation method and annealing furnace
  • Iron-chromium-aluminum alloy with pink oxide film and its preparation method and annealing furnace
  • Iron-chromium-aluminum alloy with pink oxide film and its preparation method and annealing furnace

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Embodiment approach

[0038] As an implementation of the embodiment of the present invention, the diameter of the drawn iron-chromium-aluminum alloy wire is 4-12 mm.

[0039] S2, placing the clean iron-chromium-aluminum alloy wire into a nitrate solution for passivation to obtain an iron-chromium-aluminum alloy wire with a passivation film;

[0040] This process has two functions: firstly, it has the function of neutralizing the residual alkali solution; secondly, it has the function of passivation, and its electrolyte has oxidizing properties, which can not only oxidize the metal ions and the replaced hydrogen atoms, but even the atomic state. Oxygen can oxidize on the surface of the alloy, and the chemical potential of atomic oxygen is high. At the same time as the oxidation of the electrolyte, atomic oxygen will chemically adsorb on the surface of the alloy. In chemical adsorption, O has electron-withdrawing properties and Metals have the property of losing electrons, so O can extract electrons ...

Embodiment 1

[0062] Embodiment 1 provides a kind of preparation method of the iron-chromium-aluminum alloy with pink oxide film, as follows:

[0063] 1. Put the drawn iron-chromium-aluminum alloy wire with a diameter of 10mm into the lye solution at a temperature of 95 ℃, keep it warm for 1.5h, clean the lubricant on the surface of the iron-chromium-aluminum alloy wire, and the solute in the lye solution and the solute. The mass concentrations are shown in Table 1.

[0064] 2. Put the iron-chromium-aluminum alloy wire after cleaning the lubricant in step 1 into boiling water at 100°C for ultrasonic cleaning for 10 minutes.

[0065] 3. Put the iron-chromium-aluminum alloy wire cleaned in step 2 into a sodium nitrate solution with a mass fraction of 55% sodium nitrate and a temperature of 15°C for electrolytic passivation for 25s, then take it out and put it into boiling water at 100°C for ultrasonic cleaning for 10 minutes.

[0066] 4. Put the iron-chromium-aluminum alloy wire treated in s...

Embodiment 2

[0071] Embodiment 2 provides a kind of preparation method of the iron-chromium-aluminum alloy with pink oxide film, is specifically as follows:

[0072] 1. Put the drawn iron-chromium-aluminum alloy wire with a diameter of 8mm into the lye solution at a temperature of 100 ℃, keep it warm for 1.8h, clean the lubricant on the surface of the iron-chromium-aluminum alloy wire, and the solute in the lye solution and the solute. The mass concentrations are shown in Table 1.

[0073] 2. Put the iron-chromium-aluminum alloy wire after cleaning the lubricant in step 1 into boiling water at 100°C for ultrasonic cleaning for 10 minutes.

[0074] 3. Put the iron-chromium-aluminum alloy wire cleaned in step 2 into a sodium nitrate solution with a mass fraction of 60% sodium nitrate and a sodium nitrate solution with a temperature of 35°C for 30s, then take it out and put it into boiling water at 100°C for ultrasonic cleaning for 10 minutes.

[0075] 4. Put the iron-chromium-aluminum alloy...

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Abstract

The invention provides an iron-chromium-aluminum alloy with a pink oxide film, a preparation method thereof, and an annealing furnace. The method comprises: placing a drawn iron-chromium-aluminum alloy wire in OH ‑ In the alkali solution with a mass concentration of 150-210g / L, the lubricant is cleaned to obtain a clean iron-chromium-aluminum alloy wire; the clean iron-chromium-aluminum alloy wire is placed in a nitrate solution for passivation treatment to obtain a passivation The iron-chromium-aluminum alloy wire of the film; the passivation iron-chromium-aluminum alloy wire is put into the alkali solution to corrode the passivation film, and the corroded iron-chromium-aluminum alloy wire is obtained; the corrosion iron-chromium-aluminum alloy wire is baked After drying, annealing treatment is carried out at a temperature of 850-900° C. for 2-2.5 hours, and after quenching, iron-chromium-aluminum alloy wires with pink oxide film are obtained. The iron-chromium-aluminum alloy wire with pink oxide film provided by the invention has a uniform oxide film, the bending times of the alloy wire can reach 30-36 times, the strength is 690-735MPa, the elongation is 26-30%, the performance is good, and the service life is 1 Years and a half, long service life.

Description

technical field [0001] The invention belongs to the technical field of alloy processing, and in particular relates to an iron-chromium-aluminum alloy surface treatment method and an annealing furnace. Background technique [0002] Iron-chromium-aluminum alloy (Fe-Cr-Al alloy) is based on iron and adds rare earth elements such as La, Ce, Y, etc., and has a high-performance electrothermal alloy. Its operating temperature reaches 1250-1350 ° C. The method and the heat treatment method can form a dense blue oxide film with good adhesion to the substrate on the surface of the Fe-Cr-Al alloy, so it has good anti-oxidation performance, so it is widely used in various fields. In addition, the resulting oxide film also has resistivity, high melting point, and good carburization resistance. [0003] At present, the blue oxide film formation process is: lye → HNO 3 Solution → lye → heat treatment → water cooling, that is, the drawn Fe-Cr-Al alloy is directly placed in the lye solutio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F17/00C23G1/19C25D11/34C21D1/26C21D1/18C21D9/52C23C8/10C21D9/54
CPCC23G1/19C25D11/34C21D1/26C21D1/18C21D9/525C23C8/10C23F17/00C21D9/54Y02P10/20
Inventor 胡静席林涛张德汉孙智聪李竞雄
Owner BEIJING SHOUGANG GITANE NEW MATERIALS