Photocuring composition and photocuring ink
A composition and light-curing technology, applied in inks, household appliances, applications, etc., can solve the problem of easy migration of photoinitiators, and achieve the effects of high molecular weight, low cost, and high sensitivity
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0040] The preparation method of the photocurable composition of the present invention comprises the following steps: under the conditions of constant temperature and humidity, sanitation and cleanliness, and avoiding ultraviolet radiation, it is completed through three links of pre-dispersion of ingredients, rolling and grinding, and modulation. Mix the polymerizable compound, initiator, colorant and additives at high speed to complete the pre-dispersion of ingredients; use a grinder—three-roller machine to disperse and grind the pre-dispersed materials online to the specified particle size; then add low viscosity according to the specified viscosity polymeric compound.
[0041] In another typical embodiment of the present application, a photocurable ink is provided, comprising a photocurable composition selected from any one of the above-mentioned photocurable compositions.
[0042] Because the compound having the above-mentioned structural formula I of the present invention...
preparation Embodiment 1
[0068]
[0069] Preparation of 13,13-bis(4-(2-hydroxy-2-methylpropanolyl)benzyl)-6H-indeno[1,2-b]anthracene-6,11(13H)-dione.
[0070] Step (1): Preparation of 2-(9H-fluorene-2-carbonyl)benzoic acid
[0071]
[0072] Add 400 grams of dichloromethane, 50 grams of fluorene and 44.1 grams of phthalic anhydride to a 500mL four-necked flask, stir, cool in an ice-water bath, reduce the temperature to 0 °C, and start adding 44 grams of aluminum trichloride in batches. The temperature of the process system was controlled below 10°C, and at the same time, dilute lye was used as the absorption tail gas, and aluminum trichloride was added in about 20 minutes, and the system continued to stir at room temperature for 1 hour to stop the reaction. The reaction solution was slowly poured into 400 grams of ice water, the solid was separated out, filtered under reduced pressure, the filter cake was slurried with methanol for 2 hours, and filtered to obtain a wet product of off-white powder...
preparation Embodiment 2
[0087]
[0088] of 13,13-bis(4-(2-morpholinyl-2-methylpropanolyl)benzyl)-6H-indeno[1,2-b]anthracene-6,11(13H)-dione preparation.
[0089] Into a 500mL four-necked flask was added 13,13-bis(4-(2-chloro-2-methylpropanolyl)benzyl)-6H-indeno[1,2-b]anthracene-6,11(13H )-dione 50g, morpholine 200g, heated to reflux at 100°C for 6h, the liquid phase detection reaction was complete, the reaction solution was poured into water and stirred, a yellow solid was precipitated, suction filtered, washed with water, and recrystallized from methanol to obtain 50g of compound 2 yellow solid, which was collected. The rate is 87.0%, and the purity is 98.57%.
[0090] The structure of the product was confirmed by H NMR and mass spectrometry. The specific characterization results are as follows: 1 H-NMR (CDCl 3 , 500MHz): δ8.39-8.28(m, 5H), 8.01-7.94(m, 2H), 7.54-7.28(m, 3H), 6.90-6.80(m, 8H), 3.66-3.50(t, 8H) , 3.15(m, 4H), 2.49-2.39(t, 8H), 1.40(s, 12H). MS(m / z): 787(M+1) + .
[0091] Wi...
PUM
| Property | Measurement | Unit |
|---|---|---|
| Thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More