Method and system for recycling alcohol and high-purity carbon dioxide by using alcohol tail gas as raw material
A carbon dioxide, high-purity technology, applied in chemical instruments and methods, preparation of organic compounds, separation/purification of hydroxyl compounds, etc., to achieve high recovery rate, improve economic benefits, save water and steam
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Embodiment 1
[0031] Embodiment 1: A kind of system that utilizes alcohol tail gas as raw material recovery alcohol and high-purity carbon dioxide, see Figure 1 to Figure 3 .
[0032] Including a washing tower T102, the washing tower T102 is provided with a feed gas inlet 101, a scrubbing gas outlet 1201 at the top, a condensate outlet at the bottom, and a water replenishment port 103 at the top, and the condensate outlet is connected to the condensate pump P401 , the outlet of the condensate pump P401 is divided into two paths, wherein the first path is connected to the water inlet to form a cycle, and the second path is the condensate discharge outlet 102, which also includes a washing liquid cooler E401, and the materials in the washing liquid cooler E401 The heat exchange tubes are connected in series on the first pipeline. The raw gas enters the washing tower through the raw gas inlet 101 and is absorbed by the water at the top of the tower.
[0033] It also includes a carbon dioxid...
Embodiment 2
[0041]Embodiment 2, a kind of method utilizing alcohol tail gas as raw material recovery alcohol and high-purity carbon dioxide, this method implements on the system described in embodiment 1, comprises the steps:
[0042] The gas source used in this project comes from the fermentation tail gas of corn alcohol production, and the CO in the raw gas 2 The purity is generally 92%~95%, and the rest are alcohols (methanol, ethanol), aldehydes (formaldehyde, acetaldehyde), N 2 , and O 2 Impurities, saturated with moisture content.
[0043] Table 1, Alcoholic fermentation gas impurity components
[0044] name unit content Remark carbon dioxide %v / v 92.9 ethanol ppmv / v 5098 total sulfur ppmv / v 15 Aldehydes ppmv / v 20 hydrogen sulfide ppmv / v 6.3 Others (calculated by ethanol) ppmv / v 82.16 oxygen %v / v 0.81 nitrogen %v / v 3.36 Moisture saturation
[0045] (1) Condensation and s...
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