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Method for degrading VOCs in wood by utilizing ultrasonic activated persulfate

A technology for activating persulfate and persulfate, which is applied in wood treatment, wood impregnation, wood impregnation, etc., can solve the problems of difficult reagent recovery and treatment, large loss of three major elements of wood, and impact on wood quality, so as to reduce VOCs emissions , reduce generation and volatilization, and shorten the drying cycle

Active Publication Date: 2021-08-17
BEIJING FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Chemical methods such as acid and alkali treatment have high efficiency in removing extracts, but there are problems such as large loss of three major elements of wood, strong corrosion of equipment, and serious environmental pollution.
Solvent extraction is a common method for removing extracts in laboratories, but the operation is complicated, the cycle is long, and the toxicity is high. When this method is applied to industrial production, it has a certain effect, but it has high cost, low safety, and reagent recovery. Difficulties and high investment in equipment
Physical methods such as high-temperature drying and vacuum drying have problems such as poor treatment effect, long cycle, and high energy consumption.
[0004] The above-mentioned methods for removing extracts are complicated in treatment process, have certain harm to the human body and the environment, and also affect the quality of wood. There are also problems such as high treatment cost, long cycle, and large energy consumption.

Method used

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  • Method for degrading VOCs in wood by utilizing ultrasonic activated persulfate
  • Method for degrading VOCs in wood by utilizing ultrasonic activated persulfate
  • Method for degrading VOCs in wood by utilizing ultrasonic activated persulfate

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Embodiment 1

[0033] A method utilizing ultrasonically activated persulfate to degrade VOCs in wood, comprising:

[0034] Step 1: Pretreatment: The wood to be treated is the heartwood of Chinese fir plantation, the specification is 20 mesh wood powder, and the initial moisture content is about 70%. The wood powder to be treated is air-dried to make the moisture content reach 30%;

[0035] Step 2: Oxidation treatment: Take 20g of 20-mesh wood flour, put it into a test tube, and then add 200g of potassium persulfate solution with a concentration of 3mmol / L, the pH value is 4.2, shake the wood flour to completely soak in the potassium persulfate solution , put it into an ultrasonic cleaner for ultrasonic treatment, the ultrasonic power is 210W, the temperature is set at 50°C, and the ultrasonic time is 120min.

[0036] Step 3: Circular treatment: After the oxidation treatment, take out the treated wood, and then dry it at 30-40°C.

Embodiment 2

[0038] A method utilizing ultrasonically activated persulfate to degrade VOCs in wood, comprising:

[0039] Step 1: pretreatment: the wood to be treated is the heartwood of plantation Chinese fir, and the specification is 30×20×5mm (length×width×thick) wood block, and the initial moisture content is about 70%, and the wood block to be treated is carried out air-drying treatment, so that Its moisture content reaches 30%;

[0040] Step 2: Oxidation treatment: Take 15 pieces of wooden blocks with set specifications, put them into a beaker, and then add a potassium persulfate solution with a concentration of 3mmol / L and a pH value of 4.2, so that the solution just covers the wooden blocks by about 2cm and keeps The wooden block is under the liquid surface and soaked for 4 hours; put it into an ultrasonic cleaner for ultrasonic treatment, the ultrasonic power is 210W, the temperature is set at 50°C, and the ultrasonic time is 120min;

[0041] Step 3: Circular treatment: After the ...

Embodiment 3

[0043] A method utilizing ultrasonically activated persulfate to degrade VOCs in wood, comprising:

[0044] Step 1: Pretreatment: The wood to be treated is Xinjiang poplar, the specification is 30 × 20 × 5mm (length × width × thickness) wood block, the initial moisture content is about 50%, and the wood block to be treated is air-dried to make it contain water rate up to 30%;

[0045] Step 2: Oxidation treatment: Take 15 pieces of wooden blocks with set specifications, put them into a beaker, and then add a potassium persulfate solution with a concentration of 3mmol / L and a pH value of 4.2, so that the solution just covers the wooden blocks by about 2cm and keeps The wooden block is under the liquid surface and soaked for 4 hours; put it into an ultrasonic cleaner for ultrasonic treatment, the ultrasonic power is 210W, the temperature is set at 50°C, and the ultrasonic time is 120min;

[0046] Step 3: Circular treatment: After the oxidation treatment, take out the treated woo...

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Abstract

The invention relates to a method for degrading VOCs in wood by utilizing ultrasonic activated persulfate, and belongs to the technical field of wood modification. The method comprises the steps: pretreatment is conducted, specifically, air drying treatment is conducted on wood to be treated through temperature and humidity adjustment, so that the water content reaches about 25-30%; oxidation treatment is conducted, specifically, the air-dried wood is completely soaked in a persulfate solution for a period of time, and then ultrasonic treatment is conducted at the temperature of 45-55 DEG C; circulation treatment: after the oxidation treatment is finished, the treated wood is taken out, the step 2 is repeated for treatment, and the circulation frequency is 0-5 times; and then, drying is performed. According to the method, persulfate is activated through ultrasonic waves to generate sulfate free radicals to oxidize and degrade VOCs in wood, meanwhile, permeability of the wood is improved through ultrasonic oscillation and other behaviors, extract is promoted to be desorbed from cell walls and the inner wall of a guide pipe, and the oxidative decomposition effect of the free radicals on the extract is further improved through multiple effects of ultrasonic waves.

Description

technical field [0001] The invention relates to the technical field of wood modification, and specifically provides a method for degrading VOCs in wood by using ultrasonically activated persulfate. Background technique [0002] Wood is a renewable biomass material that plays a great supporting role in human life and is mostly used for structural materials, furniture manufacturing and interior decoration. However, the volatilization of the extracts (such as volatile oils and aromatic compounds) contained in the wood itself causes the wood to decompose during processing and utilization to release volatile organic compounds (VOCs) that are harmful to humans and unpleasant odors. , such as fir heartwood has a pungent taste, cedar has a spicy taste, basswood has a putty smell, etc. With the trend of material abundance and spiritual pursuit of diversification, human beings pay more and more attention to the environmental space they live in. In order to improve the relationship be...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B27K3/02B27K5/00B27K3/20
CPCB27K3/0214B27K3/02B27K5/0065B27K3/20B27K2240/10B27K2200/00B27K2200/15
Inventor 张世锋沈玉林
Owner BEIJING FORESTRY UNIVERSITY