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Transparent conductive film

A transparent conductive film, transparent technology, applied in the field of conductive film, can solve the problems of affecting the conductivity, affecting the service life, and the silver nanowires are easy to fall off, so as to achieve the effect of improving the conductivity and improving the conductivity

Active Publication Date: 2021-11-09
浙江中科玖源新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Polyimide material has good high temperature resistance and mechanical properties, and can be used in flexible transparent conductive films, but the adhesion between polyimide and silver nanowires is poor, and flexible transparent conductive films will be damaged during use. Frequent bending will cause the silver nanowires to fall off easily, affecting the conductivity and thus affecting its service life

Method used

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  • Transparent conductive film

Examples

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Comparison scheme
Effect test

Embodiment 1

[0032] A transparent conductive film, comprising: a transparent polyimide base film and a conductive layer attached to the surface of the transparent polyimide base film;

[0033] Among them, in the preparation process of the transparent polyimide-based film, 2 mmol of triethylamine, 0.1 mmol of dendritic polyamide-amine whose end group is an amino group, 0.92 mmol of 2-(3-aminophenyl)-5- Aminobenzimidazole was dissolved in 400ml of water, nitrogen was introduced to remove the air, and then 1mmol of 4,4'-(4,4'-isopropyldiphenoxy)bis(phthalic anhydride) was slowly added to control the temperature. The polyamic acid solution was coated on the cleaned and dried glass carrier surface, then kept at 90 °C for 1 h, and then kept at 180 °C and 210 °C for 1.2 h to obtain a transparent polyamic acid solution. Imide-based film;

[0034] The transparent polyimide base film was washed with acetone, ethanol and water in turn and dried, and then the surface of the transparent polyimide base...

Embodiment 2

[0036] A transparent conductive film, comprising: a transparent polyimide base film and a conductive layer attached to the surface of the transparent polyimide base film;

[0037] Among them, in the preparation process of the transparent polyimide-based film, 2.5 mmol of triethylamine, 0.08 mmol of dendrimeric polyamide-amine whose end group is an amino group, and 0.94 mmol of 2-(4-aminophenyl)-5 - Aminobenzimidazole was dissolved in 400ml of water, and nitrogen was introduced to remove the air, and then 1mmol of 4,4'-oxydiphthalic anhydride was slowly added, the temperature was controlled at 10°C, and the reaction was kept for 5h to obtain a polyamic acid solution; The polyamic acid solution was coated on the surface of the cleaned and dried glass carrier, then kept at 80°C for 2h, and then kept at 190°C and 220°C for 0.8h respectively to obtain a transparent polyimide base film;

[0038] The transparent polyimide base film was washed with acetone, ethanol and water in turn a...

Embodiment 3

[0040] A transparent conductive film, comprising: a transparent polyimide base film and a conductive layer attached to the surface of the transparent polyimide base film;

[0041] Among them, in the preparation process of the transparent polyimide-based film, 2.3 mmol of triethylamine, 0.09 mmol of dendrimeric polyamide-amine whose end group is an amino group, and 0.93 mmol of 2-(3-aminophenyl)-5 - Dissolve aminobenzimidazole in 400ml of water, pass nitrogen to remove air, then slowly add 1mmol of 4,4'-(4,4'-isopropyldiphenoxy)bis(phthalic anhydride), control The temperature is 12 °C, and the reaction is kept for 4.5 hours to obtain a polyamic acid solution; the polyamic acid solution is coated on the surface of the cleaned and dried glass carrier, then kept at 85 °C for 1.5 hours, and then kept at 185 °C and 215 °C for 1 hour to obtain Transparent polyimide base film;

[0042] The transparent polyimide base film was washed with acetone, ethanol and water in turn and dried, a...

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Abstract

The invention discloses a transparent conductive film which comprises a transparent polyimide base film and a conductive layer attached to the surface of the transparent polyimide base film, wherein transparent polyimide is prepared by copolymerizing a dianhydride monomer, a diamine monomer and dendritic polyamide-amine with the end group being amino. The conductive film is good in transparency and good in conductivity, and the silver nanowires are not prone to falling off.

Description

technical field [0001] The present invention relates to the technical field of conductive films, in particular to a transparent conductive film. Background technique [0002] With the development of the times, the application of flexible electronic products is becoming more and more extensive. Flexible transparent conductive films are an important part of flexible electronic devices. Since indium tin oxide is not suitable for application in flexible electronic devices, the search for a new generation of materials has attracted extensive attention of researchers. Silver nanowires, as a new type of nanomaterials, have many novel properties on the nanometer scale, and their excellent electrical conductivity and good optical properties are considered to be the best materials to replace indium tin oxide. [0003] The polyimide material has good high temperature resistance and mechanical properties, and can be used in flexible transparent conductive films, but the adhesion betwee...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/044C08J5/18C08G73/10C09D175/04C09D5/24C09D163/00C08L79/08
CPCC08J7/044C08J7/0427C08J5/18C08G73/1085C08G73/101C09D175/04C09D5/24C09D163/00C08J2379/08C08J2475/04C08K2201/011C08J2463/00C08K7/06Y02E10/549
Inventor 阙新红徐哲金文斌
Owner 浙江中科玖源新材料有限公司