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High-strength anti-aging polyvinyl chloride composite material as well as preparation method and application thereof

A technology of polyvinyl chloride and composite materials, applied in mechanical equipment, pipes, pipes/pipe joints/fittings, etc., can solve the problems of reducing production stability, complex formula system, single function, etc., to improve compatibility, Extended service life, photoaging resistance and improved mechanical properties

Pending Publication Date: 2021-11-16
LIANSU TECH DEV WUHAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the current PVC plastic product industry, commonly used fillers are not compatible with PVC resin and have single functions, and the formula system is relatively complicated and easy to reduce production stability. The present invention provides a high-strength anti-aging polyvinyl chloride composite material , the use of activated lignin to replace traditional fillers and anti-light aging additives can not only simplify the overall formula, but also improve the compatibility between components in the material system, and realize the anti-light aging performance and mechanical properties of PVC-U pipes comprehensive improvement of

Method used

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  • High-strength anti-aging polyvinyl chloride composite material as well as preparation method and application thereof
  • High-strength anti-aging polyvinyl chloride composite material as well as preparation method and application thereof
  • High-strength anti-aging polyvinyl chloride composite material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5

[0044] A high-strength anti-aging polyvinyl chloride composite material, in parts by weight, including the raw materials described in Table 1 below.

[0045] The raw material composition of table 1 different embodiment

[0046]

[0047]

[0048] Wherein, activated lignin is lignin modified by titanate coupling agent.

[0049] The above-mentioned high-strength anti-light aging polyvinyl chloride composite material is used to prepare PVC-U drainage pipes, and the specific preparation method is as follows:

[0050] Mix the components uniformly at 110°C, cool to 52°C, and then extrude at a mold temperature of 160-175°C and a screw speed of 30 rpm. After cooling and cutting, high-strength anti-aging polyvinyl chloride can be obtained. drain pipe.

Embodiment 6

[0052] A high-strength anti-aging polyvinyl chloride composite material includes the same raw material composition as in Example 3 in parts by weight.

[0053] Wherein the lignin powder is a titanate coupling agent modified lignin, and the specific preparation method is as follows:

[0054] Dilute the titanate coupling agent TC-2 in deionized water at a ratio of 1:8, add 30wt% alkali lignin, and heat the reaction at 60°C for 2h, then place it in a vacuum at 85°C Treat in a drying oven until the solvent is completely evaporated to obtain activated lignin.

[0055] The above-mentioned high-strength anti-light aging polyvinyl chloride composite material is used to prepare PVC-U drainage pipes, and the specific preparation method is as follows:

[0056] Mix the components uniformly at 110°C, cool to 52°C, and then extrude at a mold temperature of 160-175°C and a screw speed of 30 rpm. After cooling and cutting, high-strength anti-aging polyvinyl chloride can be obtained. drain p...

Embodiment 7

[0058] A high-strength anti-aging polyvinyl chloride composite material includes the same raw materials as in Example 3 in parts by weight.

[0059] Wherein the activated lignin is a titanate coupling agent modified lignin, and the specific preparation method is as follows:

[0060] Dilute the titanate coupling agent TC-3 in deionized water at a ratio of 1:8, add 30wt% alkali lignin, and heat the reaction at 60°C for 2h, then place it in a vacuum at 85°C Treat in a drying oven until the solvent is completely evaporated to obtain activated lignin.

[0061] The above-mentioned high-strength anti-light aging polyvinyl chloride composite material is used to prepare PVC-U drainage pipes, and the specific preparation method is as follows:

[0062] Mix the components uniformly at 110°C, cool to 52°C, and then extrude at a mold temperature of 160-175°C and a screw speed of 30 rpm. After cooling and cutting, high-strength anti-aging polyvinyl chloride can be obtained. drain pipe.

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Abstract

The invention discloses a high-strength anti-aging polyvinyl chloride composite material as well as a preparation method and application thereof, and belongs to the technical field of anti-aging plastics. According to the high-strength anti-aging polyvinyl chloride composite material disclosed by the invention, lignin is activated by a titanate coupling agent to serve as a multifunctional additive, so that on one hand, the light aging resistance of a PVC-U drainage pipe material is effectively improved by utilizing a strong capturing effect of a hindered phenol structure of lignin on free radicals in a light aging process; on the other hand, the lignin which is hard and strong is used as the filler, so that the strength of the PVC-U drainage pipe material is effectively improved; a carbon branched chain structure is introduced into a lignin molecular structure through the titanate coupling agent, so that the compatibility of lignin molecules and a PVC matrix is improved, the light aging resistance and the strength modification effect of lignin are fully exerted, the comprehensive performance of the PVC-U drainage pipe is improved, the probability of pipe explosion accidents caused by aging or insufficient strength is reduced, and the service life of a pipe is effectively prolonged.

Description

technical field [0001] The invention relates to the technical field of anti-aging plastics, more specifically, to a high-strength anti-aging polyvinyl chloride composite material and its preparation method and application. Background technique [0002] Polyvinyl chloride (PVC) has always been popular for its relatively low price, good physical and mechanical properties, dielectric properties, solvent resistance and good flame retardancy, and is often used to prepare drainage pipes. However, the current industry needs to add specific additives for different defects of PVC pipes. For example, PVC resin is easy to degrade and age under the action of light, heat and oxygen, resulting in yellowing, brittleness and hardening of the pipe, and a sharp decline in physical properties. It is necessary to add light shielding agents, ultraviolet absorbers, Additives such as light stabilizers. In addition, as a PVC drainage pipe, it is necessary to add a large amount of calcium carbonat...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L97/00C08H7/00F16L9/12
CPCC08L27/06C08H6/00F16L9/12C08L2201/08C08L2203/18C08L97/005
Inventor 黄海亮宋科明李统一
Owner LIANSU TECH DEV WUHAN