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Lithium-supplementing negative electrode plate, preparation method thereof and lithium ion battery

A lithium-ion battery and negative electrode technology, which is applied in secondary batteries, battery electrodes, non-aqueous electrolyte storage batteries, etc., can solve the problems of complex process, difficult to ensure consistency of negative electrodes, cumbersome operation, etc., and achieve improved dispersion and uniformity performance, make up for irreversible loss, and improve the effect of the first Coulombic efficiency

Inactive Publication Date: 2021-11-19
HUBEI JINQUAN NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the invention needs to redesign the battery structure, and it is difficult to ensure the consistency of the negative electrode after lithium supplementation, the process is also very complicated, and the operation is cumbersome

Method used

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  • Lithium-supplementing negative electrode plate, preparation method thereof and lithium ion battery
  • Lithium-supplementing negative electrode plate, preparation method thereof and lithium ion battery
  • Lithium-supplementing negative electrode plate, preparation method thereof and lithium ion battery

Examples

Experimental program
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Effect test

Embodiment 1

[0052] This embodiment provides a lithium-supplementing negative electrode sheet and a preparation method thereof, the preparation method comprising the following steps:

[0053] (1) mixing graphite and silicon powder, and stirring at a speed of 600rpm for 60min to obtain the first negative electrode powder;

[0054] (2) mixing vapor-phase grown carbon fiber, lithium powder and the first negative electrode powder obtained in step (1), and stirring at a speed of 600 rpm for 60 min to obtain the second negative electrode powder;

[0055] (3) mixing polytetrafluoroethylene with the second negative electrode powder obtained in step (2), and stirring at a speed of 600 rpm for 30 min to obtain the third negative electrode powder;

[0056] (4) rolling the third negative electrode powder obtained in step (3) to obtain a lithium powder composite diaphragm;

[0057] (5) The lithium powder composite membrane obtained in step (4) and the double-sided carbon-coated copper foil are laminat...

Embodiment 2

[0061] This embodiment provides a lithium-supplementing negative electrode sheet and a preparation method thereof. In the preparation method, in addition to controlling the weight of lithium powder in the lithium powder composite diaphragm of the lithium-supplementing negative electrode sheet per unit volume, the weight of the positive electrode main material in the positive electrode sheet per unit volume is 1%, all the other conditions are the same as in Example 1, so they will not be repeated here.

Embodiment 3

[0063] This embodiment provides a lithium-supplementing negative electrode sheet and a preparation method thereof. In the preparation method, in addition to controlling the weight of lithium powder in the lithium powder composite diaphragm of the lithium-supplementing negative electrode sheet per unit volume, the weight of the positive electrode main material in the positive electrode sheet per unit volume is 2%, all the other conditions are the same as in Example 1, so they will not be repeated here.

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Abstract

The invention provides a lithium-supplementing negative electrode plate, a preparation method thereof and a lithium ion battery. The lithium-supplementing negative electrode plate comprises a lithium powder composite membrane and a negative electrode current collector; and the weight of the lithium powder in the lithium powder composite membrane of the lithium supplement negative plate per unit volume is 0.5-2% of the weight of the positive electrode main material in the positive plate per unit volume. The preparation method comprises the following steps: (1) mixing graphite and silicon powder to obtain first negative electrode powder; (2) mixing a conductive agent, lithium powder and the first negative electrode powder obtained in the step (1) to obtain second negative electrode powder; (3) mixing a binder with the second negative electrode powder obtained in the step (2) to obtain third negative electrode powder; (4) rolling the third negative electrode powder obtained in the step (3) to obtain a lithium powder composite membrane; and (5) mutually laminating the lithium powder composite diaphragm obtained in the step (4) and a negative electrode current collector, and rolling together to obtain the lithium-supplementing negative electrode plate. The lithium-supplementing negative plate makes up lithium consumed in the first lithium embedding process, and the lithium supplementing process is simplified.

Description

technical field [0001] The invention belongs to the technical field of lithium-ion batteries, and relates to a lithium-replenishing negative electrode sheet, in particular to a lithium-replenishing negative electrode sheet, a preparation method thereof, and a lithium-ion battery. Background technique [0002] The current worldwide energy crisis has led to an increasingly urgent need for and development of new energy vehicles. It is an inevitable trend for pure electric new energy vehicles to gradually replace traditional gasoline vehicles. However, new energy vehicles have higher requirements for power batteries. become more prominent. At present, in the application of lithium-ion batteries, graphite materials have 5%-10% irreversible lithium loss during the first charge and discharge process, while high-capacity silicon anode materials have 15%-35% irreversible lithium loss during the first charge and discharge process. Lithium supplementation technology is now usually use...

Claims

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Application Information

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IPC IPC(8): H01M4/134H01M4/38H01M4/139H01M10/058H01M10/0525H01M10/42
CPCH01M4/134H01M4/382H01M4/139H01M10/058H01M10/0525H01M10/4235Y02P70/50Y02E60/10
Inventor 谭立波高夜军阮祝华苑丁丁
Owner HUBEI JINQUAN NEW MATERIALS CO LTD