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Decorative sheet and decorative plate

A decorative sheet and thermoplastic resin technology, which is applied in the direction of decorations, decorative arts, and techniques for producing decorative surface effects, etc., can solve the problem of decreased clarity of decorative sheet patterns, coloring, and damage to the transparency of the flame retardant layer, etc. problem, to achieve the effect of clear and visible pattern, high definition and excellent flame retardancy

Pending Publication Date: 2021-11-19
DAI NIPPON PRINTING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, when these flame retardants are used, the transparency of the layer containing the flame retardant is impaired, and it may be colored, and there is a problem that the clarity of the pattern of the decorative sheet is reduced.

Method used

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  • Decorative sheet and decorative plate
  • Decorative sheet and decorative plate
  • Decorative sheet and decorative plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0184] (manufacturing of decorative sheets)

[0185] As a substrate sheet, a 60 μm thick opaque colored polypropylene film was prepared. Next, after performing corona discharge treatment on both surfaces of the substrate sheet, a primer layer (thickness 2 μm) of two-liquid curing polyurethane resin was formed on the back surface of the substrate sheet, and the surface of the substrate sheet was coated by gravure printing. On the front side, a patterned layer is formed with curable printing ink containing acrylic urethane resin. Further, an adhesive of a two-component curing polyurethane resin was applied on the patterned layer to form a transparent adhesive layer. Then, on the adhesive layer, a transparent polypropylene resin containing a phosphinic acid metal salt flame retardant shown below is heated and melted and extruded using a T-die extruder to form a thermoplastic transparent resin layer (thickness 100 μm) ).

[0186] · Transparent polypropylene resin: 100 parts by ...

Embodiment 2

[0200] A decorative sheet and a decorative board were produced in the same manner as in Example 1 except that the content of the phosphinic acid metal salt-based flame retardant in the transparent resin layer was 5 parts by mass. The content of the phosphinic acid metal salt-based flame retardant was 3.0% by mass when the total of the mass of the transparent resin layer and the base sheet was 100% by mass.

Embodiment 3

[0202] A decorative sheet and a decorative board were produced in the same manner as in Example 1 except that the content of the phosphinic acid metal salt-based flame retardant in the transparent resin layer was 30 parts by mass. When the total mass of the transparent resin layer and the base material sheet was 100% by mass, the content of the phosphinic acid metal salt-based flame retardant was 14.4% by mass.

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Abstract

The present invention provides a decorative sheet that has exceptional flame retardance, has a vividly visible pattern, has suppressed discoloration, and has exceptional sharpness. The present invention provides a decorative sheet that has a transparent resin layer, a substrate sheet, and at least one thermoplastic resin layer selected from the group consisting of synthetic-resin backer layers, wherein the decorative sheet is characterized in that: (1) the at least one thermoplastic resin layer contains a phosphinic-acid-metal-salt-based flame retardant; and (2) the transparent resin layer and the substrate sheet contain at least one selected from the group consisting of polyolefin-based resins and polyester-based resins.

Description

technical field [0001] The present invention relates to decorative sheets and decorative panels. Background technique [0002] Currently, decorative sheets are laminated in order to impart design to the surface of various articles. For example, a decorative board used as a floor surface of a building can be used by laminating a decorative sheet on a base material. [0003] Since such a decorative board is laminated on the surface of a building, it may be necessary to satisfy the conditions for obtaining non-combustible certification that it is not easy to burn in the event of a fire. Among them, the above-mentioned conditions for obtaining the certification of non-combustibility are the results of the heat release test based on ISO5660-1 stipulated in Article 2, Clause 9 of the Japanese Building Standards Law on the total heat release, maximum heat release rate, cracks and voids. stipulated conditions. [0004] As a decorative sheet used for a decorative board satisfying ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/00B32B27/18B32B27/32B32B27/36E04B1/94
CPCB32B27/32B32B27/36B32B27/18B32B27/08B32B33/00B32B21/14B32B21/08B32B7/12E04F13/0866E04F13/18E04B1/94E04F15/18B32B2451/00B32B2307/3065B32B2419/04B32B2307/412E04F15/105E04F15/107E04F15/102E04F2290/046B32B27/16B32B2255/26B32B2264/307B32B2255/28B32B2255/10B32B2250/242B32B2264/1021B32B2307/41B32B2307/4026B32B9/042B32B9/045B32B2307/4023B32B3/30B32B27/20B32B9/02B44C1/10E04B1/942B32B2307/584B32B2307/75E04F15/02B32B2264/104B32B2307/732
Inventor 根津义昭风间圭佑阪口结香小林义弘
Owner DAI NIPPON PRINTING CO LTD